Green sustainable process for chemical and environmental engineering and science. Microwaves in organic synthesis /

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Microwaves in Organic Synthesis provides an in-depth overview in the area of organic and pharmaceutical chemistry of the microwave technology in separation, purification and extraction of medicinal, biological, and organic compounds. This book methodically explores the application of microwaves in a...

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Bibliographic Details
Call Number:Libro Electrónico
Other Authors: Inamuddin, 1980-, Boddula, Rajender, Asiri, Abdullah M.
Format: Electronic eBook
Language:Inglés
Published: Amsterdam, Netherlands : Elsevier, [2021]
Subjects:
Organic compounds > Synthesis.
Compos�es organiques > Synth�ese.
Organic compounds > Synthesis
Online Access:Texto completo
Table of Contents:
  • Intro
  • Green Sustainable Process for Chemical and Environmental Engineering and Science: Organic Synthesis in Water and Supercriti...
  • Copyright
  • Contents
  • Contributors
  • Chapter 1: Polymer synthesis in water and supercritical water
  • 1. Introduction
  • 1.1. Water in industries
  • 1.2. Supercritical fluids
  • 1.3. Properties of water and supercritical water
  • 2. Polymerization in water medium
  • 2.1. Emulsion polymerization
  • 2.2. Photoactivated polymerization
  • 2.3. Dispersion polymerization
  • 2.4. Controlled/``living�� radical polymerization
  • 2.5. Radical polymerization
  • 5. Se-nucleophile
  • 6. H-nucleophiles
  • References
  • Chapter 3: Cycloaddition reactions in water
  • 1. Introduction
  • 2. ``In-water�� cycloaddition reactions
  • 2.1. [4+2] Cycloaddition (Diels-Alder) reactions
  • 2.2. Hydrophobicity effect on rate enhancement in water
  • 2.2.1. Structure facilitated hydrophobic effect
  • 2.3. Hydrogen-bonding effect on rate enhancement
  • 2.4. Endo- vs exo-selectivity in intermolecular D-A reactions
  • 2.5. Inverse electron demand D-A reactions in water
  • 2.6. Asymmetric Diels-Alder reactions in water
  • 2.7. Application to the total synthesis of natural products
  • 2.8. Intramolecular Diels-Alder reactions in water
  • 2.9. Aqueous intramolecular D-A reaction in the total synthesis
  • 2.10. [3+2] Cycloaddition reactions in water
  • 2.11. [4+3] Cycloaddition reaction
  • 2.12. [2+2+2] Cycloadditions
  • 2.13. [5+2] Cycloadditions
  • 3. Cycloaddition reactions ``on-water��
  • 4. Concluding remarks
  • Acknowledgments
  • References
  • Chapter 4: Hydrogenation reactions in water
  • 1. Introduction
  • 2. Types of hydrogenation
  • 2.1. Catalytic hydrogenation
  • 2.2. Transfer hydrogenation
  • 2.3. Asymmetric hydrogenation
  • 2.4. Asymmetric transfer hydrogenation
  • 2.5. Electrocatalytic hydrogenation
  • 2.6. Selective hydrogenation
  • 2.6.1. Chemoselective hydrogenation
  • 2.6.2. Diastereoselective hydrogenation
  • 2.6.3. Regioselective hydrogenation
  • 2.7. Other hydrogenation
  • 3. Water as hydrogen donor
  • 3.1. Synthesis of aliphatic compounds
  • 3.2. Synthesis of aromatic compounds
  • 3.3. Synthesis of carbonyl compounds
  • 3.4. Synthesis of alcohols, ethers, sugars, nitro and nitril compounds
  • 3.5. Synthesis of bio-oils, fossil fuel, and cellulose
  • 4. Water as solvent

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