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Kinetics of chemical processes /
Kinetics of Chemical Processes details the concepts associated with the kinetic study of the chemical processes. The book is comprised of 10 chapters that present information relevant to applied research.
| Call Number: | Libro Electrónico |
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| Main Author: | |
| Format: | Electronic eBook |
| Language: | Inglés |
| Published: |
Boston :
Butterworth-Heinemann,
[1991]
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| Series: | Butterworth-Heinemann series in chemical engineering.
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| Subjects: | |
| Online Access: | Texto completo |
Table of Contents:
- Front Cover; Kinetics of Chemical Processes; Copyright Page; Table of Contents; PREFACE AND ERRATUM; PREFACE TO THE ORIGINAL PRINTING; Chapter 1. INTRODUCTION; 1.1 The Scope of Chemical Kinetics; 1.2 The Extent of Reaction; 1.3 The Rate of Reaction; 1.4 General Properties of the Rate Function for a Single Reaction; 1.5 Ideal Reactors; 1.6 Stirred-Flow Reactors; 1.7 Ideal Tubular Reactors; 1.8 Measurement of Reaction Rates; BIBLIOGRAPHY; Chapter 2. CHEMICAL KINETICS OF ELEMENTARY STEPS; 2.1 Definition of an Elementary Step; 2.2 Transition-State Theory; 2.3 The Rate of an Elementary Step.
- 2.4 Thermodynamic Formulation of Rates; 2.5 The Collision Theory and the Equation of Arrhenius; 2.6 Rates and Equilibrium; 2.7 Rates in Solutions and in Thermodynamically Nonideal Systems; 2.8 Summary; BIBLIOGRAPHY; Chapter 3. THE STEADY-STATE APPROXIMATION: CATALYSIS; 3.1 Single Reactions: Open and Closed Sequences; 3.2 The Steady-State Approximation; 3.3 Kinetic Treatment of Catalytic Sequences; 3.4 Kinetic Treatment of Chain Reactions; 3.5 Principle of Microscopic Reversibility; 3.6 Kinetics of Polymerization; BIBLIOGRAPHY; Chapter 4. SIMPLIFIED KINETICS OF SEQUENCES AT THE STEADY STATE.
- 4.1 The Rate-determining Step; 4.2 The Stoichiometric Number of the Rate-determining Step; 4.3 Shift in Rate-determining Step; 4.4 Rate-determining Active Centers; 4.5 Ambiguity of Simplified Kinetics; BIBLIOGRAPHY; Chapter 5. COUPLED SEQUENCES IN REACTION NETWORKS; 5.1 Catalytic Reactions in Parallel; 5.2 Catalytic Reactions in Series; 5.3 Chain Reactions in Parallel; 5.4 Chain Reactions in Series; BIBLIOGRAPHY; Chapter 6. AUTOCATALYSIS AND INHIBITION; 6.1 Acceleration of the Rate; 6.2 Branched Chains; 6.3 Degenerate Branching; 6.4 Reactions Involving Solids; 6.5 Inhibition; BIBLIOGRAPHY.
- Chapter 7. IRREDUCIBLE TRANSPORT PHENOMENA IN CHEMICAL KINETICS; 7.1 The Gel and Cage Effects; 7.2 The Wall Effect; 7.3 The Penetration Effect; 7.4 Thermal Explosions, Ignition, Stability; BIBLIOGRAPHY; Chapter 8. CORRELATIONS IN HOMOGENEOUS KINETICS; 8.1 The Polanyi Relation; 8.2 The Br�onsted Relation; 8.3 The Hammett Relation: Linear Free-energy Relationships; 8.4 The Compensation Effect; 8.5 The Acidity Function in Acid-Base Catalysis; BIBLIOGRAPHY; Chapter 9. CORRELATIONS IN HETEROGENEOUS CATALYSIS; 9.1 Catalysis on a Nonuniform Surface; 9.2 Activity and Selectivity.
- 9.3 The Principle of Sabatier; 9.4 A Kinetic Comparison Between Homogeneous and Heterogeneous Catalysis; BIBLIOGRAPHY; Chapter 10. ANALYSIS OF REACTION NETWORKS; 10.1 The Kinetic Tracer Technique of Neiman; 10.2 Kinetic Behavior of a Network of First-order Reversible Reactions: The Method of Wei and Prater; 10.3 Determination of Straight-line Reaction Paths; 10.4 Calculation of Rate Constants; 10.5 Illustration: Isomerization of Butenes on Alumina; 10.6 Kinetic Response of Reaction Networks; BIBLIOGRAPHY; APPENDIX; INDEX.