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Spectra of atoms and molecules /

"This book is designed as a textbook to introduce advanced undergraduates and, particularly, new graduate students to the vast field of spectroscopy. It presumes that the student is familiar with the material in an undergraduate course in quantum mechanics. I have taken great care to review the...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Bernath, Peter F. (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York, NY : Oxford University Press, 2020.
Edición:Fourth edition.
Temas:
Acceso en línea:Texto completo

MARC

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049 |a UAMI 
100 1 |a Bernath, Peter F.,  |e author. 
245 1 0 |a Spectra of atoms and molecules /  |c Peter F. Bernath. 
250 |a Fourth edition. 
264 1 |a New York, NY :  |b Oxford University Press,  |c 2020. 
264 4 |c ©2020 
300 |a 1 online resource (xvi, 525 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
504 |a Includes bibliographical references and index. 
520 |a "This book is designed as a textbook to introduce advanced undergraduates and, particularly, new graduate students to the vast field of spectroscopy. It presumes that the student is familiar with the material in an undergraduate course in quantum mechanics. I have taken great care to review the relevant mathematics and quantum mechanics as needed throughout the book. Considerable detail is provided on the origin of spectroscopic principles. My goal is to demystify spectroscopy by showing the necessary steps in a derivation, as appropriate in a textbook. The digital computer has permeated all of science including spectroscopy. The application of simple analytical formulas and the nonstatistical graphical treatment of data are long dead. Modern spectroscopy is based on the matrix approach to quantum mechanics. Real spectroscopic problems can be solved on the computer more easily if they are formulated in terms of matrix operations rather than differential equations. I have tried to convey the spirit of modern spectroscopy, through the extensive use of the language of matrices"--  |c Provided by publisher. 
588 |a Description based on online resource; title from digital title page (ProQuest Ebook Central, viewed April 15, 2021). 
505 0 |a Introduction. Waves, particles, and units ; The electromagnetic spectrum ; Interaction of radiation with matter -- Molecular symmetry. Symmetry operations ; Groups ; Notation for point groups -- Matrix representation of groups. Vectors and matrices ; Symmetry operations and position vector basis ; Symmetry operators and atomic basis vectors ; Symmetry operators and basis functions ; Equivalent, reducible, and irreducible representations ; Great orthogonality theorem ; Character tables -- Quantum mechanics and group theory. Matrix representation and the Schrödinger equation ; Born-Oppenheimer approximation ; Symmetry of the Hamiltonian operator ; Projection operators ; Direct product representations ; Integrals and selection rules -- Atomic spectroscopy. Background ; Angular momentum ; The hydrogen atom and one-electron spectra ; Many-electron atoms ; Selection rules ; Atomic spectra ; Intensity of atomic lines ; Zeeman effect ; Stark effect -- Rotational spectroscopy. Rotation of rigid bodies ; Diatomic and linear molecules ; Rotational line intensities for diatomic and linear molecules ; Symmetric tops ; Asymmetric tops ; Structure determination -- Vibrational spectroscopy. Diatomic molecules ; Vibrational motion of polyatomic molecules ; Selection rules for vibrational transitions ; Vibrational spectra of polyatomic linear molecules ; Vibrational spectra of symmetric tops ; Vibrational spectra of spherical tops ; Vibrational spectra of asymmetric tops ; Vibration-rotation line intensities ; Fermi and Coriolis perturbations ; Inversion doubling and fluxional behavior -- Light scattering and the Raman effect. Background ; Rotational Raman effect ; Vibration-rotation Raman spectroscopy ; Rayleigh and Raman intensities -- Electronic spectroscopy of diatomics. Orbitals and states ; Vibrational structure ; Rotational structure of diatomic molecules ; The symmetry of diatomic energy levels : parity ; Rotational line intensities ; Dissociation, Photodissociation, and Predissociation -- Electronic spectroscopy of polyatomics. Orbitals and states ; Vibrational structure of electronic transitions ; Vibronic coupling : the Herzberg-Teller effect ; Jahn-Teller effect and conical intersections ; Renner-Teller effect ; Nonradiative transitions : Jablonski diagram ; Photoelectron spectroscopy ; Rotational structure : H₂CO and HCN ; Intensity of transitions -- Atmospheric spectroscopy. Introduction ; Atmospheric spectra ; Radiative transfer ; Forward and inverse models -- Astronomical spectroscopy. Introduction ; Interstellar clouds ; Stars and brown dwarfs ; Planets, exoplanets, and moons. 
590 |a Knovel  |b ACADEMIC - Chemistry & Chemical Engineering 
590 |a Knovel  |b ACADEMIC - General Engineering & Project Administration 
650 0 |a Atomic spectroscopy  |v Textbooks. 
650 0 |a Molecular spectroscopy  |v Textbooks. 
650 0 |a Spectrum analysis  |v Textbooks. 
650 7 |a Atomic spectroscopy  |2 fast 
650 7 |a Molecular spectroscopy  |2 fast 
650 7 |a Spectrum analysis  |2 fast 
655 7 |a Textbooks  |2 fast 
776 0 8 |i Print version:  |a Bernath, Peter F.  |t Spectra of atoms and molecules.  |b Fourth edition.  |d New York, NY : Oxford University Press, 2020  |z 9780190095406  |w (DLC) 2020001412  |w (OCoLC)1137752236 
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