Advances in polymer reaction engineering /

"Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Chapters in this new release include Polymer reaction engineering and composition control in free radical copolymers,...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Moscatelli, Davide (Editor ), Sponchioni, Mattia (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam, The Netherlands : Elsevier Academic Press, 2020.
Edición:First edition.
Colección:Advances in chemical engineering ; v. 56.
Temas:
Polymer engineering.
Polymerization.
G�enie des polym�eres.
Polym�erisation.
polymer science.
polymerization.
Polymer engineering
Polymerization
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Advances in Polymer Reaction Engineering
  • Copyright
  • Contents
  • Contributors
  • Chapter One: Perspectives, pillars, and examples of polymer reaction engineering in the 21st century
  • 1. The evolution of polymer reaction engineering
  • 2. The question and request for perspectives
  • 3. Excerpts from the responses
  • 4. Kinetic rate coefficients as a core element of PRE
  • 5. Why are the propagation rate coefficients for the homologous series of methacrylates different?
  • 6. Pulsed-laser polymerization (PLP) and coupled with size exclusion chromatography (PLP-SEC)
  • 7. An approach to rate parameter estimation for reactive sites on sidechains pendent to the primary chain backbone
  • 8. Concluding remarks
  • References
  • Chapter Two: On-line monitoring and control of emulsion polymerization reactors
  • 1. Introduction
  • 2. On-line monitoring and estimation of polymer latex characteristics
  • 2.1. Free monomer concentration/copolymer composition/polymerization rate
  • 2.1.1. Direct measurement of the free monomer concentration
  • 2.1.2. Estimation of the free monomer concentration from other measurements
  • 2.1.3. Comparison between spectroscopy and calorimetry
  • 2.2. Particle size average and distribution
  • 2.3. Molar mass
  • 2.4. Radical concentration
  • 2.5. ACOMP (automatic continuous on-line monitoring of polymerization reaction)
  • 2.6. Remaining challenges
  • 3. On-line control of polymer characteristics in emulsion polymerization
  • 3.1. Copolymer composition
  • 3.2. Molar mass distribution (MMD)
  • 3.3. Particle size distribution
  • 3.4. Remaining challenges
  • 4. Conclusions and outlook
  • References
  • Chapter Three: Exploiting the pulsed laser polymerization-size exclusion chromatography technique to retrieve kinetic par ...
  • 1. Introduction
  • 2. One mode propagation reactivities from PLP inflection point data
  • 2.1. Factors affecting the accuracy of the PLP-SEC technique
  • 2.1.1. Termination rate limit: Use of inflection point or peak maximum data?
  • 2.1.2. Stability of the inflection point toward other chemical reactions
  • 2.1.3. Isothermicity or not?
  • 2.1.4. Selection of photo-initiator
  • 2.1.5. SEC calibration and column broadening
  • 2.2. Trends and family type behavior

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