Organofluorine chemistry : synthesis and applications /

Organofluorine Chemistry: Synthesis and Applications gives a comprehensive outlook on modern synthetic methodologies for organofluorine compounds. It illustrates chemical, biochemical, and materials applications of fluorine-containing compounds, including synthesis and applications of small molecule...

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Bibliographic Details
Call Number:Libro Electrónico
Main Author: Reddy, Prakash
Format: Electronic eBook
Language:Inglés
Published: Amsterdam : Elsevier, 2020.
Subjects:
Organofluorine compounds.
Compos�es organiques fluor�es.
Online Access:Texto completo
Table of Contents:
  • Front Cover
  • Organofluorine Chemistry
  • Copyright Page
  • Contents
  • Preface
  • 1 Nucleophilic reactions in the synthesis of organofluorine compounds
  • 1.1 Introduction
  • 1.2 Reagents for nucleophilic fluorinations
  • 1.3 Nucleophilic deoxyfluorination
  • 1.4 Nucleophilic fluorination of pyridines and diazines
  • 1.5 Nucleophilic gem-difluorination of carbonyl compounds
  • 1.6 Nucleophilic fluoroalkylations
  • 1.6.1 Nucleophilic difluoromethylation of aldehydes
  • 1.6.2 Ruppert-Prakash reagent (CF3SiMe3) for trifluoromethylation
  • 1.6.2.1 Enantioselective trifluoromethylation
  • 1.6.2.2 Synthesis of trifluoromethyl ketones
  • 1.6.2.3 Trifluoromethylation of imines
  • 1.6.3 Fluoroacetone hydrates for the nucleophilic fluoroalkylations
  • 1.6.4 Trifuoromethylations using fluoroform (CHF3)
  • 1.6.5 Borazine-mediated trifluoromethylation and difluoroalkylation
  • 1.6.6 N-Trifluoromethylation of amines
  • 1.6.7 Tetrakis(dimethylamino)ethylene-mediated fluoroalkylations
  • 1.6.7.1 Trifluoromethylation of acyl chlorides
  • 1.6.7.2 Synthesis of gem-(difluoromethyl)thioethers
  • 1.7 Nucleophilic trifluoromethylthiolation
  • 1.8 Trifluoromethoxylations

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