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Non-aqueous solutions-- 5 : plenary and section lectures presented at the fifth International Conference on Non-aqueous Solutions, Leeds, England, 5-9 July 1976 /
Non-Aqueous Solutions - 5 is a collection of lectures presented at the Fifth International Conference on Non-Aqueous Solutions held in Leeds, England, on July 5-9, 1976. The papers explore reactions in non-aqueous solutions as well as the thermodynamic and kinetic properties of non-aqueous solutions...
| Clasificación: | Libro Electrónico |
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| Autores Corporativos: | , , |
| Otros Autores: | |
| Formato: | Electrónico Congresos, conferencias eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford ; New York :
Pergamon Press,
1977.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Non-Aqueous Solutions-5; Copyright Page; Table of Contents; PREFACE; CHAPTER 1. CATION-ELECTRON INTERACTIONS IN METAL SOLUTIONS
- FROM SOLVATED ELECTRONS TO ALKALI METAL ANIONS; INTRODUCTION; SOLVATED ELECTRONS; SPECIES OF STOICHIOMETRY M; DIAMAGNETIC ELECTRON-CATION CLUSTERS; ALKALI METAL ANIONS; EFFECT OF SOLVENT AND METAL ON THE STABILITY OF VARIOUS SPECIES; REFERENCES; CHAPTER 2. APPLICATION OF E.S.R. SPECTROSCOPY TO THE STUDY OF SOLVATION; INTRODUCTION; ION-PAIRS AND CLUSTERS; SOLVATION OF NEUTRAL RADICALS; INFORMATION FROM RADIATION STUDIES; CONCLUDING COMMENT; REFERENCES.
- Chapter 3. influence of solvent properties on ligand substitution mechanisms of labile complexesintroduction; solvent properties and solvent-exchange parameters of nickel(ii) ion; solvent effects on substitution kinetics of bipyridine and similar ligands; abnormally slow reactions in dimethylsulfoxide and other strong-donor solvents; abnormally fast reactions in acetonitrile and other weak-donor solvents; summary; references; chapter 4. colored sulfur species in epd-solvents; introduction; the nature of the blue and red sulfur species in epd-solvents; references.
- Chapter 5. chemical reactions in molten salts : importance of acidityintroduction; acidity in molten chloroaluminates; acidity in molten nitrates; acidity in molten potassium disulfate; acidity in molten hydrogenosulfate; conclusion; acknowledgment; references; chapter 6. non-aqueous solvents for preparation and reactions of nitrogen halogen compounds; introduction; 1. the solvent takes part in the reaction; 2. the solvent doesn't take part in the reaction; conclusion; references; chapter 7. ion-solvent and ion-ion interactions: alkali metal tetraalkylaluminates in nonaqueous solutions.
- INTRODUCTIONALKALI METAL TETRAALKYLALUMINATES; ION PAIR TYPE; SOLVATION NUMBER; ION AGGREGATION; CONCLUSION; REFERENCES; CHAPTER 8. RECENT DEVELOPMENTS IN THE CHEMISTRY OF SOLUTIONS OF SALTS IN LIQUID ALKALI METALS; METAL-NONMETAL PHASE EQUILIBRIA; SOLUBILITIES; SOLUTE SPECIES; REACTIONS IN METALS; REFERENCES; CHAPTER 9. PREFERENTIAL SOLVATION IN KINETICS; INTRODUCTION; SOLVENT EFFECTS ON KE ; SOLVENT EFFECTS ON k; REFERENCES; CHAPTER 10. RAMAN SPECTROSCOPIC STUDIES OF NON-AQUEOUS SOLUTIONS; INTRODUCTION; RESULTS; ACKNOWLEDGEMENT; REFERENCES.
- CHAPTER 11. ARE REACTIONS IN SUPERACID MEDIA DUE TO PROTONS OR TO POWERFUL OXIDISING SPECIES SUCH AS SO3 OR SbF5?INTRODUCTION; REFERENCES; CHAPTER 12. SPECTROSCOPIC STUDIES ON COORDINATION COMPOUNDS FORMED IN MOLTEN SALTS; INTRODUCTION; REFERENCES.