Instrumental methods in electrochemistry /

Using 372 references and 211 illustrations, this book underlines the fundamentals of electrochemistry essential to the understanding of laboratory experiments. It treats not only the fundamental concepts of electrode reactions, but also covers the methodology and practical application of the many ve...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor Corporativo: Southampton Electrochemistry Group
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge [England] : Woodhead Publishing, 2011.
Colección:Chemical Science Series
Temas:
Electrochemical analysis.
Analyse �electrochimique.
SCIENCE > Chemistry > Physical & Theoretical.
Science.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Instrumental Methods in Electrochemistry; Instrumental Methods in Electrochemistry; Copyright Page; Table of Contents; Preface; List of symbols; Chapter 1. Introduction to the fundamental concepts of electrochemistry; 1.1 ELECTRODE REACTIONS AND CELL CHEMISTRY; 1.2 THE NATURE OF ELECTRODE REACTIONS; 1.3 ELECTRON TRANSFER; 1.4 MASS TRANSPORT; 1.5 THE INTERACTION OF ELECTRON TRANSFER AND MASS TRANSPORT; 1.6 COUPLED CHEMICAL REACTIONS; 1.7 ADSORPTION; 1.8 PHASE FORMATION; REFERENCES; Chapter 2. Steady state and potential step techniques; 2.1 STEADY STATE TECHNIQUES
  • 2.2 CONTROLLED POTENTIAL BULK ELECTROLYSIS2.3 TECHNIQUES FOR THE INVESTIGATION OF FAST ELECTRODE REACTIONS; 2.4 POTENTIAL STEP TECHNIQUES; 2.5 PULSE VOLTAMMETRY; 2.6 CHRONOPOTENTIOMETRY; REFERENCES; Chapter 3. Electron transfer; 3.1 AN EMPIRICAL DESCRIPTION OF ELECTRON TRANSFER; 3.2 MORE FUNDAMENTAL MODELS OF ELECTRON TRANSFER; 3.3 COMPARISON BETWEEN HETEROGENEOUS AND HOMOGENEOUS ELECTRON TRANSFER; 3.4 COMPARISON OF ELECTRON TRANSFER AT METAL AND SEMICONDUCTOR ELECTRODES; 3.5 MULTISTEP ELECTRODE REACTIONS; REFERENCES
  • Chapter 4. Convective diffusion systems
  • the rotating disc and ring-disc electrodes4.1 HYDRODYNAMICS OF CONVECTIVE DIFFUSION SYSTEMS; 4.2 THE ROTATING DISC ELECTRODE; 4.3 THE ROTATING RING-DISC ELECTRODE; REFERENCES; Chapter 5. The electrical double layer; 5.1 THE THERMODYNAMICS OF CHARGED INTERFACES; 5.2 THE STRUCTURE OF THE ELECTRICAL DOUBLE LAYER; 5.3 THE ADSORPTION ISOTHERM; 5.4 THE EFFECT OF DOUBLE LAYER STRUCTURE ON ELECTRODE KINETICS; 5.5 EXPERIMENTAL METHODS; REFERENCES; Chapter 6. Potential sweep techniques and cyclic voltammetry; 6.1 REVERSIBLE REACTIONS; 6.2 IRREVERSIBLE SYSTEMS
  • 6.3 COUPLED HOMOGENEOUS REACTIONS6.4 ILLUSTRATIONS OF THE USE OF CYCLIC VOLTAMMETRY FOR THE STUDY OF COUPLED CHEMICAL REACTIONS; 6.5 SURFACE PROCESSES; 6.6 MORE RECENT DEVELOPMENTS; 6.7 EXPERIMENTAL PROBLEMS ASSOCIATED WITH LINEAR SWEEP AND CYCLIC VOLTAMMETRY; REFERENCES; Chapter 7. Electrocatalysis; 7.1 ELECTRODE REACTIONS INVOLVING ADSORBED INTERMEDIATES; 7.2 THE HYDROGEN EVOLUTION REACTION; 7.3 THE OXYGEN EVOLUTION AND REDUCTION REACTIONS; 7.4 FUEL CELL ANODE REACTIONS; 7.5 THE DESIGN OF ELECTROCATALYSTS; REFERENCES; Chapter 8. A.C. techniques; 8.1 A.C. THEORY
  • 8.2 MEASURING THE IMPEDANCE OF AN ELECTROCHEMICAL CELL8.3 APPLICATIONS OF IMPEDANCE ANALYSIS; 8.4 GRAPHICAL REPRESENTATION OF RESULTS; REFERENCES; Chapter 9. Electrocrystallisation; 9.1 PHASE FORMATION FROM THE VAPOUR PHASE; 9.2 ELECTROCHEMICAL PHASE FORMATION; 9.3 NUCLEATION AND GROWTH OF MONOLAYERS; 9.4 NUCLEATION AND GROWTH OF THREE-DIMENSIONAL CENTRES; 9.5 CRYSTAL ORIENTATION AND MORPHOLOGY OF POLYCRYSTALLINE DEPOSITS; 9.6 ELECTROCRYSTALLISATION OF ANODIC FILMS; 9.7 ELECTROCRYSTALLISATION PROCESSES IN OTHER ELECTROCHEMICAL SYSTEMS; REFERENCES; Chapter 10. Spectroelectrochemistry

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