Group theory for chemists : fundamental theory and applications /

Mostrar otras versiones (2)

The basics of group theory and its applications to themes such as the analysis of vibrational spectra and molecular orbital theory are essential knowledge for the undergraduate student of inorganic chemistry. The second edition of Group Theory for Chemists uses diagrams and problem-solving to help s...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Molloy, Kieran C. (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Oxford : WP, Woodhead Publishing, 2011.
Edición:Second edition.
Colección:Woodhead Publishing in materials.
Temas:
Group theory.
Chemistry > Inorganic.
Group theory > Problems, exercises, etc.
Chemistry, Inorganic > Problems, exercises, etc.
Chemistry, Inorganic
Th�eorie des groupes.
Chimie inorganique.
Th�eorie des groupes > Probl�emes et exercices.
Chimie inorganique > Probl�emes et exercices.
inorganic chemistry.
SCIENCE > Chemistry > Physical & Theoretical.
Chemistry, Inorganic.
Problems and Exercises
exercise books.
Problems and exercises.
Probl�emes et exercices.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Group Theory for Chemists: Fundamental Theory and Applications
  • Copyright
  • Table of Contents
  • Preface
  • PART I SYMMETRY AND GROUPS
  • 1 Symmetry
  • 1.1 SYMMETRY
  • 1.2 POINT GROUPS
  • 1.3 CHIRALITY AND POLARITY
  • 1.4 SUMMARY
  • PROBLEMS
  • 2 Groups and Representations
  • 2.1 GROUPS
  • 2.2 TRANSFORMATION MATRICES
  • 2.3 REPRESENTATIONS OF GROUPS
  • 2.4 CHARACTER TABLES
  • 2.5 SYMMETRY LABELS
  • 2.6 SUMMARY
  • PROBLEMS
  • PART II APPLICATION OF GROUP THEORY TO VIBRATIONAL SPECTROSCOPY
  • 3 Reducible Representations
  • 3.1 REDUCIBLE REPRESENTATIONS
  • 3.2 THE REDUCTION FORMULA.
  • 3.3 THE VIBRATIONAL SPECTRUM OF SO2
  • 3.4 CHI PER UNSHIFTED ATOM
  • 3.5 SUMMARY
  • PROBLEMS
  • 4 Techniques of Vibrational Spectroscopy
  • 4.1 GENERAL CONSIDERATIONS
  • 4.2 INFRARED SPECTROSCOPY
  • 4.3 RAMAN SPECTROSCOPY
  • 4.4 RULE OF MUTUAL EXCLUSION
  • 4.5 SUMMARY
  • PROBLEMS
  • 5 The Vibrational Spectrum of Xe(O)F4
  • 5.1 STRETCHING AND BENDING MODES
  • 5.2 THE VIBRATIONAL SPECTRUM OF Xe(O)F 4
  • 5.3 GROUP FREQUENCIES
  • PROBLEMS
  • PART III APPLICATION OF GROUP THEORY TO STRUCTURE AND BONDING
  • 6 FUNDAMENTALS OF MOLECULAR ORBITAL THEORY
  • 6.1 BONDING IN H2
  • 6.2 BONDING IN LINEAR H3.
  • 6.3 LIMITATIONS IN A QUALITATIVE APPROACH
  • 6.4 SUMMARY
  • PROBLEMS
  • 7 H2O
  • LINEAR OR ANGULAR?
  • 7.1 SYMMETRY-ADAPTED LINEAR COMBINATIONS
  • 7.2 CENTRAL ATOM ORBITAL SYMMETRIES
  • 7.3 A MOLECULAR ORBITAL DIAGRAM FOR H2O
  • 7.4 A C2v / Dh MO CORRELATION DIAGRAM
  • 7.5 SUMMARY
  • PROBLEMS
  • 8 NH3
  • PLANAR OR PYRAMIDAL?
  • 8.1 LINEAR OR TRIANGULAR H3?
  • 8.2 A MOLECULAR ORBITAL DIAGRAM FOR BH3
  • 8.3 OTHER CYCLIC ARRAYS
  • 8.4 SUMMARY
  • PROBLEMS
  • 9 OCTAHEDRAL COMPLEXES
  • 9.1 SALCS FOR OCTAHEDRAL COMPLEXES
  • 9.2 d-ORBITAL SYMMETRY LABELS
  • 9.3 OCTAHEDRAL P-BLOCK COMPLEXES.
  • 9.4 OCTAHEDRAL TRANSITION METAL COMPLEXES
  • 9.5 (Ss (B-BONDING AND THE SPECTROCHEMICAL SERIES
  • 9.6 SUMMARY
  • PROBLEMS
  • 10 FERROCENE
  • 10.1 CENTRAL ATOM ORBITAL SYMMETRIES
  • 10.2 SALCS FOR CYCLOPENTADIENYL ANION
  • 10.3 MOLECULAR ORBITALS FOR FERROCENE
  • PROBLEMS
  • PART IV APPLICATION OF GROUP THEORY TO ELECTRONIC SPECTROSCOPY
  • 11 SYMMETRY AND SELECTION RULES
  • 11.1 SYMMETRY OF ELECTRONIC STATES
  • 11.2 SELECTION RULES
  • 11.3 THE IMPORTANCE OF SPIN
  • 11.4 DEGENERATE SYSTEMS
  • 11.5 EPILOGUE
  • SELECTION RULES FOR VIBRATIONAL SPECTROSCOPY
  • 11.6 SUMMARY
  • PROBLEMS.
  • 12 TERMS AND CONFIGURATIONS
  • 12.1 TERM SYMBOLS
  • 12.2 THE EFFECT OF A LIGAND FIELD
  • ORBITALS
  • 12.3 SYMMETRY LABELS FOR dn CONFIGURATIONS
  • AN OPENING
  • 12.4 WEAK LIGAND FIELDS, TERMS AND CORRELATION DIAGRAMS
  • 12.5 SYMMETRY LABELS FOR dn CONFIGURATIONS
  • CONCLUSION
  • 12.6 SUMMARY
  • PROBLEMS
  • 13 d-d SPECTRA
  • 13.1 THE BEER-LAMBERT LAW
  • 13.2 SELECTION RULES AND VIBRONIC COUPLING
  • 13.3 THE SPIN SELECTION RULE
  • 13.4 d-d SPECTRA
  • HIGH-SPIN OCTAHEDRAL COMPLEXES
  • 13.5 d-d SPECTRA
  • TETRAHEDRAL COMPLEXES
  • 13.6 d-d SPECTRA
  • LOW-SPIN COMPLEXES
  • 13.7 DESCENDING SYMMETRY.

Ejemplares similares