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Immobilized enzymes for industrial reactors /

Immobilized Enzymes For Industrial Reactors.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Messing, Ralph A.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Oxford : Elsevier Science, 1975.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Immobilized Enzymes for Industrial Reactors; Copyright Page; Table of Contents; Contributors; Preface; Immobilized Enzymes for Industrial Reactors; CHAPTER 1. INTRODUCTION AND GENERAL HISTORY OF IMMOBILIZED ENZYMES; I. HISTORY OF ENZYMES; II. HISTORY OF IMMOBILIZED ENZYMES; III. THE PROLIFERATION OF THE TECHNOLOGY; IV. REASONS FOR IMMOBILIZING ENZYMES; V. IMMOBILIZATION TECHNIQUES; VI. PROLIFERATION OF CARRIERS; VII. REACTORS; VIII. SCOPE OF THE TECHNOLOGY; IX. ECONOMIC CONSIDERATIONS AND PRECAUTIONS; X. ENZYME PURITY; REFERENCES; CHAPTER 2. BASIC ENZYMOLOGY.
  • I. enzymes as proteinsii. enzymes as catalysts; references; chapter 3. controlled-pore glasses for enzyme immobilization; i. introduction; ii. preparation of controlled-pore glasses; iii. surface area of controlled-pore glass; iv. surface properties of porous glass; v. some surface reactions of porous glass; vi. chemical durability of controlled-pore glasses; vii. physical and mechanical characteristics; viii. summary; references; chapter 4. carriers; i. carrier morphology and configuration; ii. microbial considerations; iii. selecting a carrier; iv. carrier regeneration.
  • V. optimizing the carrierreferences; chapter 5. immobilization by adsorption and inorganic bridge formation; i. definition; ii. promising applications; iii. theory, mechanisms and application considerations; iv. an example of immobilization by adsorption; references; chapter 6. immobilization by covalent attachment and by entrapment; i. methods for the covalent attachment of enzymes to water-insoluble carriers; ii. methods for covalent attachment of proteins to inorganic supports; iii. copolymerization of proteins; iv. proteins immobilized by intermolecular cross linking.
  • V. entrapment of proteins within polymermatricesvi. microencapsulation (47-51); vii. ultrafiltration and hollow-fiber devices (52-54); references; chapter 7. characteristics of free vs. immobilized enzymes; 1
  • enzyme concentration; 2
  • temperature; 3
  • ph; 4
  • ionic strength; 5
  • product concentration; 6
  • maximum velocity; 7
  • michaelis constant; 8
  • substrate concentration; 9
  • inhibitor concentration; 10
  • other factors; references; chapter 8. immobilized coenzymes; enzyme reactions; stoichiometric and catalytic coenzymes.
  • Coenzyme retention strategies for immobilizedenzymes requiring stoichiometric coenzymesmechanisms of coenzyme requiring enzymes; immobilized coenzymes with enzymatic activity; references; chapter 9. design and operation of immobilized enzyme reactors; i. introduction; ii. reactor types; iii. immobilized enzyme reactor performance; iv. mass transfer; v. electrostatic effects; vi. backmixing; vii. temperature; viii. ime activity loss; ix. heat transfer; x. pressure drop; xi. ime reactor operating strategy; xii. general design considerations for ime systems; xiii. ime system cost estimate.