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Sulphones in organic synthesis /
Over the last twenty years the use of sulphones in organic synthesis has increased dramatically, the synthetic repertoire of sulphones having been developed to such an extent as to rival the carbonyl functionality for versatility. Not only have sulphones been employed in a great many synthetic metho...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford [England] ; New York :
Pergamon,
1993.
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| Edición: | 1st ed. |
| Colección: | Tetrahedron organic chemistry series ;
v. 10. |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover; Sulphones in Organic Synthesis; Copyright Page; Preface; Table of Contents; CHAPTER 1. Introduction to Sulphone Chemistry; References; CHAPTER 2. The Preparation of Sulphones; 2.1 Simple Alkyl Aryl and Dialkyl Sulphones; 2.2 Vinyl Sulphones; 2.3 Allylic, Allenic, Alkynyl and Aryl Sulphones; 2.4 Functionalised Sulphones; CHAPTER 3. Sulphonyl Carbanions; 3.1 Introduction to Sulphonyl Carbanions; 3.2 Reactions of Simple Sulphonyl Carbanions; 3.3 Reactions of Additionally Stabilised Sulphonyl Carbanions; 3.4 Sulphonyl Polyanions; CHAPTER 4. Additions to Unsaturated Sulphones.
- 4.1 Heteroatom Nucleophiles4.2 Non-stabilised Organometallics; 4.3 Enolates, Related Anions and Miscellaneous Carbon Nucleophiles; 4.4 Cyclopropanations; 4.5 Radical Additions; CHAPTER 5. Rearrangements of Sulphones; 5.1 Ring Expansions and Fragmentations; 5.2 Sulphinate to Sulphone Rearrangements; 5.3 1,3-Rearrangements of Allylic Sulphones; 5.4 The Truce-Smiles Rearrangement; 5.5 Miscellaneous Rearrangements; CHAPTER 6. Cycloaddition Chemistry of Unsaturated Sulphones; 6.1 [2+2] Cycloadditions; 6.2 [3+2] Cycloadditions; 6.3 [4+2] Cycloadditions.
- CHAPTER 7. Carbon-Carbon Double-Bond Formation by Sulphone Elimination7.1 The Julia Olefination Reaction; 7.2 Alternative �-Eliminations of Sulphones; 7.3 The Ramberg-B�acklund Reaction; CHAPTER 8. Chemistry of Cyclic Sulphones; 8.1 Three-membered Ring Sulphones; 8.2 Four-membered Ring Sulphones; 8.3 Five-membered Ring Sulphones; 8.4 Functionalised Normal-sized Rings; 8.5 Larger Ring Sulphones; CHAPTER 9. Desulphonylation; 9.1 Simple Alkyl Aryl and Dialkyl Sulphones; 9.2 Allylic Sulphones; 9.3 Vinyl Sulphones; 9.4 Functionalised Sulphones; 9.5 Sulphone Reduction; INDEX.