Cargando…
Electron paramagnetic resonance of d transition metal compounds /
Electron paramagnetic resonance (epr) spectroscopy is a sensitive and versatile method of studying paramagnets, which is finding increasing use in chemistry, biochemistry, earth and materials sciences. The technique is treated both qualitatively and quantitatively, with a progressive increase in sop...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; New York :
Elsevier,
1992.
|
| Colección: | Studies in inorganic chemistry ;
16. |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover; Electron Paramagnetic Resonance of d Transition Metal Compounds; Copyright Page; Table of Contents; Preface; Chapter 1.; 1.1 THE ELECTRON PARAMAGNETIC RESONANCE EXPERIMENT; 1.2 THE BASIC COMPONENTS OF AN E.P.R. SPECTROMETER AND THEIR FUNCTIONS; 1.3 THE EFFECTS OF INSTRUMENTAL SETTINGS ON E.P.R. SPECTRA; 1.4 SOME EFFECTS OF SAMPLE CHARACTERISTICS ON E.P.R. SPECTRA; 1.5 SOME EFFECTS OF MICROWAVE FREQUENCY; References; Chapter 2. SPIN DOUBLETS IN AN APPLIED MAGNETIC FIELD; A QUALITATIVE TREATMENT; 2.1 ENERGY LEVELS AND SPECTRA FOR A FREE ELECTRON
- 2.2 SPECTRA OF ISOLATED SINGLE PARAMAGNETS2.3 SPECTRA OF RANDOM COLLECTIONS OF PARAMAGNETS: POWDERS AND GLASSES; Chapter 3. THE QUANTITATIVE DESCRIPTION OF THE SPECTRA FROM SPIN DOUBLETS INTERACTING WITH AN APPLIED MAGNETIC FIELD ONLY; 3.1 THE INTERACTION OF THE ELECTRON WITH A MAGNETIC FIELD; 3.2 THE ESSENTIALS OF PERTURBATION THEORY; 3.3 THE APPLICATION OF PERTURBATION THEORY TO SPIN DOUBLETS; 3.4 THE DETERMINATION OF THE PRINCIPAL g TENSOR ELEMENTS FROM SINGLE CRYSTAL SPECTRA; References; Chapter 4. THE SPECTRA FROM SPIN DOUBLETS INTERACTING WITH A NUCLEAR SPIN: A QUALITATIVE TREATMENT
- 4.1 INTRODUCTION4.2 ISOTROPIC PARAMAGNETS; 4.3 ANISOTROPY IN METAL HYPERFINE INTERACTIONS; 4.4 ANISOTROPY IN LIGAND HYPERFINE INTERACTION; References; Chapter 5. SPECTRA OF SPIN DOUBLETS INTERACTING WITH A NUCLEAR SPIN: A QUANTITATIVE TREATMENT; 5.1 INTERACTION WITH A METAL NUCLEAR SPIN; 5.2 THE DETERMINATION OF THE g AND A TENSORS FROM SINGLE CRYSTAL STUDIES; 5.3 SPIN DOUBLETS INTERACTING WITH A LIGAND NUCLEAR SPIN ONLY; 5.4 INTERACTION WITH BOTH A METAL NUCLEAR SPIN AND LIGAND NUCLEAR SPINS; References; Chapter 6. NUCLEAR QUADRUPOLE AND NUCLEAR ZEEMAN EFFECTS IN SPIN DOUBLETS
- 6.1 QUALITATIVE ASPECTS OF METAL NUCLEAR ZEEMAN AND NUCLEAR QUADRUPOLE INTERACTIONS6.2 QUALITATIVE ASPECTS OF LIGAND NUCLEAR QUADRUPOLE AND NUCLEAR ZEEMAN INTERACTIONS; 6.3 QUANTITATIVE ASPECTS OF THE METAL NUCLEAR ZEEMAN INTERACTION; 6.4 QUANTITATIVE ASPECTS OF THE METAL NUCLEAR QUADRUPOLE INTERACTION; 6.5 OTHER METHODS FOR MEASURING QUADRUPOLE INTERACTIONS; References; Chapter 7. SPECTRUM SIMULATION FOR SPIN DOUBLETS; 7.1 PURPOSE OF SIMULATING E.P.R. SPECTRA; 7.2 THE ESSENTIAL STEPS IN SPECTRUM SIMULATION; 7.3 LINESHAPES AND LINEWIDTHS; 7.4 THE CONSTRUCTION AND PRESENTATION OF A SPECTRUM
- 7.5 THE EFFECTS OF g STRAIN AND A STRAIN7.6 ADDITIONAL SIMULATION DEVICES; 7.7 DETAILED TREATMENTS OF SOME SIMULATION SOFTWARE; 7.8 SIMULATION SOFTWARE; References; Chapter 8. METAL IONS IN CUBIC AND AXIAL LIGAND FIELDS; 8.1 INTRODUCTION; 8.2 TERM ENERGIES AND WA VEFUNCTIONS IN CUBIC CRYSTAL FIELDS; 8.3 TERM SPLITTINGS AND WA VEFUNCTIONS IN AXIAL DISTORTIONS FROM CUBIC SYMMETRIES; References; Chapter 9. THE RELATIONSHIP BETWEEN THE SPIN-HAMILTONIAN PARAMETERS AND THE ELECTRONIC STRUCTURES OF SPIN DOUBLET PARAMAGNETS; 9.1 SPIN-ORBIT COUPLING