Material concepts in surface reactivity and catalysis /
On the last quarter century's advances on the processes occurring on solid surfaces during catalysis, corrosion, adhesion, field deposition, and related phenomena. The physical and chemical properties of the surface in a reacting system are the main topics of this book. Annotation copyright Boo...
Clasificación: | Libro Electrónico |
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Autor principal: | |
Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
San Diego :
Academic Press,
�1990.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover
- Material Concepts in Surface Reactivity and Catalysis
- Copyright Page
- Table of Contents
- Preface
- Chapter 1. Structural Aspects
- A. Symmetry Properties
- B. Crystal Planes
- C. Packing Fractions
- D. Surface Overlayers
- E. Catalyst Supports
- F. Bulk and Surface Imperfections
- References
- Chapter 2. Crystallite Morphology
- A. Surface Energy and Crystal Shape
- B. Metal-Support Interactions
- C. Surface Energy and Crystal Orientation
- D. Surface Energy of Multicomponent Systems
- References
- Chapter 3. Interface EquilibriaA. Adsorption Isotherms and Isosteres
- B. Model Isotherms
- References
- Chapter 4. Adsorption and Desorption Kinetics
- A. Lennard-Jones Potential Curves
- B. Adsorption Kinetics
- C. Desorption Kinetics
- References
- Chapter 5. Binding States and Adsorbate Structures
- A. Low-Energy Electron Diffraction (LEED)
- B. Photoemission Spectroscopy
- C. Adsorbate-Induced Surface Reconstruction
- References
- Chapter 6. Interface Reactions between Metals and Support Materials
- A. Metal-Support Reactions
- B. Intermetallic CompoundsReferences
- Chapter 7. Electronic Properties of Nonmetal Catalysts
- A. Defect Structure
- B. Point Defects
- C. Defect Thermodynamics
- D. Surface States
- E. Catalytic Applications
- References
- Chapter 8. Disorder in Multicomponent Metal Oxides
- A. Metal Oxides
- B. Spinels
- C. Perovskites
- D. Scheelites
- E. Defect Metal Oxides with Crystallographic Shear Structures
- References
- Chapter 9. Metal Oxide Catalysis
- A. Spinels
- B. Perovskites
- C. Scheelites
- References
- Chapter 10. Surface Properties of Grain BoundariesA. Grain Boundary Structure
- B. Grain Boundary Energetics
- C. Component Segregation at Grain Boundaries
- D. Model Isotherms
- E. Selective Segregation in Multicomponent Systems
- F. Influence of Grain Boundary Structure on Segregation
- References
- Chapter 11. Oxide Layer Formation on Metal Surfaces
- A. General Considerations
- B. Nucleation and Growth of Oxide Layer
- C. Diffusion-Controlled Metal Oxidation
- D. Metal Oxidation Controlled by Interfacial Reaction
- E. Formation of Volatile SpeciesF. Formation of Epitaxial Oxide Layers
- G. Stress Effects
- H. Oxidation of Alloys
- References
- Chapter 12. Metal-Electrolyte Interfaces
- A. General Considerations
- B. Equilibrium at Metal-Electrolyte Interfaces
- C. Adsorption at Metal-Electrolyte Interfaces
- D. Kinetics of Metal Deposition
- References
- Index