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Solution thermodynamics and its application to aqueous solutions : a differential approach /

As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves withou...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Koga, Yoshikata
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; Oxford ; Boston [Mass.] : Elsevier, 2007.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Chapter 0. Introduction
  • PART A: A Differential Approach to Solution Thermodynamics
  • Chapter I. Basics of thermodynamics Derivatives of Gibbs energy, G
  • Chapter II. Solution thermodynamics Use of the second and the third derivatives
  • of G
  • Chapter III. Determination of the partial molar quantities
  • Chapter IV. Fluctuations and partial molar fluctuations Understanding H2O
  • PART B: Studies of Aqueous Solutions using the Second and the Third Derivatives of G
  • Chapter V. Mixing schemes in binary aqueous mono-ols
  • Chapter VI. Mixing schemes in aqueous solutions of non-electrolytes
  • Chapter VII. Effects of non-electrolytes on the molecular organization of H2O: 1-Propanol (1P) probing methodology
  • Chapter VIII. Effects of ions on the molecular organization of H2O: 1-Propanol (1P) probing methodology
  • Chapter IX. Interactions in ternary aqueous solutions General treatment
  • Chapter X. In closing Executive summary on the effect of solute on H2O
  • Appendix A. B-spline vs. manual graphical differentiation
  • Appendix B. Gibbs-Konovalov correction
  • Appendix C. Heat capacity anomalies associated with phase transition Two level
  • approximation
  • Appendix D. Freezing point depression
  • Appendix E. Titration calorimetry with dilute titrant.