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Catalysis by metals and alloys /

Catalysis by Metals and Alloys.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Ponec, Vladim�ir
Otros Autores: Bond, G. C. (Geoffrey Colin)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; New York : Elsevier, 1995.
Colección:Studies in surface science and catalysis ; 95.
Temas:
Acceso en línea:Texto completo
Texto completo
Tabla de Contenidos:
  • Cover
  • Copyright Page
  • Contents
  • PROLOGUE
  • CHAPTER 1. STRUCTURE AND PROPERTIES OF METALS AND ALLOYS
  • 1.1 A microscopic theory of solids
  • 1.2 Some results of the theory of chemisorption on metals and alloys
  • 1.3 Adsorption of molecules and radicals which are intermediates in catalytic reactions
  • 1.4 Macroscopic thermodynamic theory of alloys
  • CHAPTER 2. EXPERIMENTAL TECHNIQUES OF SOLID STATE PHYSICS, RELEVANT TO RESEARCH ON ALLOYS
  • 2.1 Photoelectron Spectroscopy (PES)
  • 2.2 Auger spectroscopy
  • 2.3 Other methods
  • CHAPTER 3. THE ELECTRONIC STRUCTURE OF ALLOYS.
  • EXPERIMENTAL RESULTS
  • 3.1 Magnetic measurements
  • 3.2 The M�ossbauer effect
  • 3.3 Photoemission Spectroscopy (PES)
  • 3.4 Soft X-ray emission and absorption
  • 3.5 Conclusions
  • CHAPTER 4. SURFACE COMPOSITION OF ALLOYS
  • 4.1 General remarks on surfaces of metals
  • 4.2 Binary systems with surface segregation
  • 4.3 Surface segregation in catalytically interesting alloys
  • CHAPTER 5. PHYSICAL PROPERTIES AND STRUCTURES OF SMALL METAL AND ALLOY PARTICLES
  • 5.1 The electronic structure of small free metal particles
  • 5.2 Equilibrium shape and thermal properties of small metal particles.
  • 5.3 Adsorption sites on small metal particles
  • 5.4 Reactivity of small metal particles
  • 5.5 Polarization and charging of small metal particles by a support
  • CHAPTER 6. THE CATALYTIC CYCLE
  • 6.1 Prelude
  • 6.2 The role of reaction mechanism in catalytic research
  • 6.3 Methods of investigating catalysed reactions
  • 6.4 Kinetics of heterogeneously catalysed reactions
  • 6.5 Structure sensitivity and particle size effects
  • 6.6 Catalytic consequence of metal-support interactions
  • CHAPTER 7. PREPARATION AND CHARACTERIZATION OF METAL AND ALLOY CATALYSTS
  • 7.1 Macroscopic materials.
  • 7.2 Small unsupported metal particles
  • 7.3 Supported metal catalysts
  • 7.4 Characterization of alloy catalysts
  • CHAPTER 8. ADSORPTION ON ALLOYS
  • 8.1 Ensemble size and composition effects
  • 8.2 Ensemble statistics and the extent of adsorption
  • 8.3 Adsorption as a probe of active sites on alloys
  • 8.4 Adsorption of simple gases on alloys
  • CHAPTER 9. CATALYSIS BY ALLOYS
  • GENERAL FEATURES
  • 9.1 Basic problems
  • 9.2 Investigation of electronic structure effects by means of catalytic reactions
  • 9.3 Important side effects of alloying.
  • CHAPTER 10. REACTIONS OF HYDROGEN AND ALKANE-DEUTERIUM EXCHANGE
  • 10.1 Reactions involving only hydrogen and its analogues
  • 10.2 The equilibrium of hydrogen + deuterium and para- hydrogen conversion
  • 10.3 Exchange of alkanes with deuterium
  • CHAPTER 11. CATALYTIC HYDROGENATION AND DEHYDROGENATION
  • 11.1 Hydrogenation of alkenes
  • 11.2 Hydrogenation of alkynes and alkadienes
  • 11.3 Hydrogenation of aromatic compounds
  • 11.4 Hydrogenation of other unsaturated groups
  • 11.5 Dehydrogenation
  • 11.6 Hydrogenation of diatomic molecules: oxygen and nitrogen
  • CHAPTER 12. OXIDATION REACTIONS.
  • 12.1 Fundamentals
  • chemisorption of the reactants.