Catalysis by metals and alloys /
Catalysis by Metals and Alloys.
Clasificación: | Libro Electrónico |
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Autor principal: | |
Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Amsterdam ; New York :
Elsevier,
1995.
|
Colección: | Studies in surface science and catalysis ;
95. |
Temas: | |
Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Cover
- Copyright Page
- Contents
- PROLOGUE
- CHAPTER 1. STRUCTURE AND PROPERTIES OF METALS AND ALLOYS
- 1.1 A microscopic theory of solids
- 1.2 Some results of the theory of chemisorption on metals and alloys
- 1.3 Adsorption of molecules and radicals which are intermediates in catalytic reactions
- 1.4 Macroscopic thermodynamic theory of alloys
- CHAPTER 2. EXPERIMENTAL TECHNIQUES OF SOLID STATE PHYSICS, RELEVANT TO RESEARCH ON ALLOYS
- 2.1 Photoelectron Spectroscopy (PES)
- 2.2 Auger spectroscopy
- 2.3 Other methods
- CHAPTER 3. THE ELECTRONIC STRUCTURE OF ALLOYS.
- EXPERIMENTAL RESULTS
- 3.1 Magnetic measurements
- 3.2 The M�ossbauer effect
- 3.3 Photoemission Spectroscopy (PES)
- 3.4 Soft X-ray emission and absorption
- 3.5 Conclusions
- CHAPTER 4. SURFACE COMPOSITION OF ALLOYS
- 4.1 General remarks on surfaces of metals
- 4.2 Binary systems with surface segregation
- 4.3 Surface segregation in catalytically interesting alloys
- CHAPTER 5. PHYSICAL PROPERTIES AND STRUCTURES OF SMALL METAL AND ALLOY PARTICLES
- 5.1 The electronic structure of small free metal particles
- 5.2 Equilibrium shape and thermal properties of small metal particles.
- 5.3 Adsorption sites on small metal particles
- 5.4 Reactivity of small metal particles
- 5.5 Polarization and charging of small metal particles by a support
- CHAPTER 6. THE CATALYTIC CYCLE
- 6.1 Prelude
- 6.2 The role of reaction mechanism in catalytic research
- 6.3 Methods of investigating catalysed reactions
- 6.4 Kinetics of heterogeneously catalysed reactions
- 6.5 Structure sensitivity and particle size effects
- 6.6 Catalytic consequence of metal-support interactions
- CHAPTER 7. PREPARATION AND CHARACTERIZATION OF METAL AND ALLOY CATALYSTS
- 7.1 Macroscopic materials.
- 7.2 Small unsupported metal particles
- 7.3 Supported metal catalysts
- 7.4 Characterization of alloy catalysts
- CHAPTER 8. ADSORPTION ON ALLOYS
- 8.1 Ensemble size and composition effects
- 8.2 Ensemble statistics and the extent of adsorption
- 8.3 Adsorption as a probe of active sites on alloys
- 8.4 Adsorption of simple gases on alloys
- CHAPTER 9. CATALYSIS BY ALLOYS
- GENERAL FEATURES
- 9.1 Basic problems
- 9.2 Investigation of electronic structure effects by means of catalytic reactions
- 9.3 Important side effects of alloying.
- CHAPTER 10. REACTIONS OF HYDROGEN AND ALKANE-DEUTERIUM EXCHANGE
- 10.1 Reactions involving only hydrogen and its analogues
- 10.2 The equilibrium of hydrogen + deuterium and para- hydrogen conversion
- 10.3 Exchange of alkanes with deuterium
- CHAPTER 11. CATALYTIC HYDROGENATION AND DEHYDROGENATION
- 11.1 Hydrogenation of alkenes
- 11.2 Hydrogenation of alkynes and alkadienes
- 11.3 Hydrogenation of aromatic compounds
- 11.4 Hydrogenation of other unsaturated groups
- 11.5 Dehydrogenation
- 11.6 Hydrogenation of diatomic molecules: oxygen and nitrogen
- CHAPTER 12. OXIDATION REACTIONS.
- 12.1 Fundamentals
- chemisorption of the reactants.