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Handbook of transition metal polymerization catalysts /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, NJ :
John Wiley & Sons,
2018.
|
| Edición: | Second edition. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- 2.3 Influence of Silica Gel Properties and Polymerization Conditions on Catalyst Performance2.4 Conclusions; References; 3 Activator Supports for Metallocene and Related Catalysts; 3.1 Introduction; 3.2 Activator Support Studies; 3.3 Activator Support Patents; 3.4 Conclusion; References; 4 Computational Modeling of Polymerization Catalysts; 4.1 Introduction; 4.2 Computational Modeling of Chemical Reactions; 4.3 Modeling the Catalyst Properties and the Polymerization Processes; 4.4 Concluding Remarks; Acknowledgment; References; 5 Computational Studies of Chromium/Silica Catalysts.
- 5.1 Introduction5.2 Mechanistic Proposals for Phillips Catalyst; 5.3 Theoretical Study on Phillips Catalyst; 5.4 The Limitation of the Current Computations and a Prospect for the Future; References; 6 Laboratory Reactors and Procedures for Catalyst Evaluation; 6.1 Introduction; 6.2 Setup in the Fume Hood; 6.3 Autoclave Reactors and Safety Relief Devices; 6.4 Purification Methods; 6.5 Modular Reactor System; 6.6 Catalyst Addition; 6.7 Temperature Control; 6.8 Autoclave Reactor Setup; 6.9 Copolymerization; 6.10 Gas-Phase Laboratory Reactors; References.
- 7 Scale-Up of Catalyst Recipes to Commercial Production7.1 Introduction; 7.2 Fundamental of Process Scale-Up; 7.3 Considerations in Scaling Up a Laboratory Recipe; 7.4 A Modern Polymerization Catalyst Production Facility; 7.5 Other Scale-Up Considerations; References; 8 Supported Titanium/Magnesium Ziegler Catalysts for the Production of Polyethylene; 8.1 Introduction; 8.2 Particle-Form Technology; 8.3 General Architecture and Preparation of Supported Catalysts; 8.4 Nonuniformity of Active Centers in Supported Ziegler Catalysts.
- Intro; Title Page; Table of Contents; Notes on Contributors; Preface; Acknowledgments; 1 Industrial Metal Alkyls and Their Use in Polyolefin Catalysts; 1.1 Introduction; 1.2 Metal Alkyls in Ziegler-Natta Catalysts; 1.3 Aluminum Alkyls; 1.4 Manufacturers of Aluminum Alkyls; 1.5 Pricing and Selection Criteria for Aluminum Alkyls; 1.6 Methylaluminoxanes; 1.7 Magnesium Alkyls; 1.8 Organoboron Compounds; 1.9 Organozinc Compounds; References; 2 Porous Silica in Transition Metal Polymerization Catalysts; 2.1 Introduction; 2.2 Production of Silica Gel Catalysts.