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Molecular photophysics and spectroscopy /
This new, expanded edition provides a fresh, photon-based description of modern molecular spectroscopy and photophysics, with applications that are drawn from across the breadth of chemistry, biology, physics, and materials science, including recent developments. The focus is on the mechanisms that...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Bristol [England] (Temple Circus, Temple Way, Bristol BS1 6HG, UK) :
IOP Publishing,
[2021]
|
| Edición: | Second edition. |
| Colección: | IOP (Series). Release 21.
IOP ebooks. 2021 collection. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- 1. Introduction to molecular spectroscopy and photophysics
- 1.1. The distinctiveness of molecular interactions with light
- 1.2. Properties of molecules and their spectra
- 1.3. The electromagnetic spectrum
- 1.4. Photon properties : polarisation and spin
- 2. Atoms and molecules : developing principles of electronic structure
- 2.1. Review of atomic orbitals, angular momentum and electron spin
- 2.2. Multielectron atoms
- 2.3. Diatomic molecules
- 2.4. Orbitals and bonding in molecules
- 3. Polyatomic molecules : orbitals, symmetry and group theory
- 3.1. Symmetry elements
- 3.2. Point groups and operations : Schoenflies notation
- 3.3. Matrix representations and character tables
- 4. Electronic and nuclear energy levels in molecules
- 4.1. The separation of electronic and nuclear motions
- 4.2. Types of nuclear motions and degrees of freedom
- 4.3. How far do the atoms move?
- 5. Small molecule rotational energy levels and spectra
- 5.1. Diatomic and linear polyatomic molecules
- 5.2. Nuclear spin effects
- 5.3. Interpreting rotational spectra
- 5.4. Centrifugal distortion
- 5.5. Non-linear polyatomic molecules
- 6. Diatomics and triatomics : vibrational energy levels and spectra
- 6.1. Diatomic molecules : harmonic motion
- 6.2. Anharmonicity and dissociation
- 6.3. Vibration-rotation spectra of diatomic molecules
- 6.4. The vibrations of triatomic molecules
- 7. Large molecule infrared absorption spectroscopy
- 7.1. Group frequencies and skeletal modes
- 7.2. Infrared spectroscopy in the condensed phase
- 7.3. Near-infrared spectroscopy
- 8. Raman scattering and spectral interpretation
- 8.1. Rayleigh scattering
- 8.2. Vibrational Raman scattering
- 8.3. Depolarisation ratio
- 8.4. Resonance Raman spectroscopy
- 9. Electronic and vibrational states in large molecules
- 9.1. Electronic states, transitions, and molecular structure
- 9.2. Vibronic structure in electronic absorption spectra
- 9.3. Vibronic structure in electronic emission spectra
- 9.4. Transition metal complexes : vibronic coupling in electronic transitions
- 10. Electronic transitions, colours, and detection
- 10.1. The origins of colour
- 10.2. Photometry and Beer's law
- 10.3. Organic molecules : conjugation and colour
- 11. After light is absorbed : photophysics in an excited electronic state
- 11.1. Interplay of excitation and decay
- 11.2. States accessible to photoexcitation
- 11.3. Decay channels
- 12. Molecular fluorescence
- 12.1. Quantum yields and fluorescence measurements
- 12.2. Transition dipole orientations
- 12.3. Photoselection and fluorescence anisotropy
- 12.4. Fluorophores and laser-induced fluorescence imaging
- 12.5. Quantum dots
- 13. Fluorescence resonance energy transfer
- 13.1. Mechanism for intermolecular energy transfer
- 13.2. Spectroscopic shift
- 13.3. Distance measurements
- 14. Chiral phenomena and optical activity
- 14.1. Criteria for chirality in matter and in light
- 14.2. Circular dichroism
- 14.3. Optical rotation
- 15. Multiphoton absorption in molecules
- 15.1. Two-photon absorption
- 15.2. Non-resonant two-photon absorption
- 15.3. Resonant two-photon absorption
- 15.4. Two-photon spectroscopy
- 15.5. Higher order processes
- 15.6. Multiphoton imaging and processing.