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Oxygen chemistry /

This book places oxygen on the center stage of chemistry in a manner that parallels the focus on carbon by 19th century chemists. One measure of the significance of oxygen chemistry is the greater diversity of oxygen-containing molecules than of carbon-containing molecules. One of the most important...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Sawyer, Donald T. (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York : Oxford University Press, 1991.
Colección:International series of monographs on chemistry ; 26.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • 1. Introduction: Why oxygen chemistry?; 2. Redox thermodynamics for oxygen species (O[sub(3)], O[sub(2)], HOO·, O[sub(2)][sup(
  • )]·, HOOH, HOO[sup(
  • )], O, O[sup(
  • )]·, and HO[sup(
  • )]); effects of media and pH; 3. Nature of chemical bonds for oxygen in its compounds; 4. Reactivity of Hydrogen Peroxide, Alkyl Hydroperoxides, and Peracids; 5. Reactivity of oxygen radicals [HO·, RO·, HOO·, ROO·, and RC(O)O·]; 6. Reactivity of dioxygen and its activation for selective dioxygenation, mono-oxygenation, dehydrogenation, and auto-oxidation of organic substrates and metals (corrosion).