Basics of Analytical Chemistry and Chemical Equilibria
Autor principal: | |
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Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Newark :
John Wiley & Sons, Incorporated,
2013.
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Colección: | New York Academy of Sciences Ser.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Intro
- Title Page
- Copyright
- Preface
- Part I: Quantitative Analysis Using Reactions that go to "Completion"
- Chapter 1: Making Measurements
- 1.1 Introduction
- 1.2 GLP and A FEW Other Important Acronyms
- 1.3 Precision and Random Error
- 1.4 Discarding a Suspected Outlier
- 1.5 Calibration
- 1.6 Maintaining Accurate Results
- Practice Exercises
- Chapter 2: Sample Preparation, Extractions, and Chromatography
- 2.1 Sampling and Control Samples
- 2.2 Sample Preparation
- 2.3 Solvents and Solutions
- 2.4 Introduction to Solubility
- 2.5 Extraction
- 2.6 Stationary Phases
- 2.7 Solid-Phase Extraction (SPE)
- 2.8 Introduction to Chromatography
- 2.9 Immunoassays
- Practice Exercises
- Chapter 3: Classical Methods
- 3.1 Introduction
- 3.2 Review of Chemical Reactions
- 3.3 Reactions in Aqueous Solution
- 3.4 Gravimetry
- 3.5 Titration
- 3.6 Titration Curves
- 3.7 Coulometry
- Practice Exercises
- Chapter 4: Molecular Spectroscopy
- 4.1 Introduction
- 4.2 Properties Of EM Radiation
- 4.3 Electromagnetic Spectrum
- 4.4 Spectroscopic Transitions
- 4.5 UV/VIS Absorption Spectroscopy
- 4.6 UV/VIS Instrumentation
- 4.7 Beer-Lambert Law
- 4.8 Molecular Fluorescence
- Practice Exercises
- Part II: Reactions That Do Not Go to "completion." Equilibria in Aqueous Solutions
- Chapter 5: Acid-Base Equilibria and Activity
- 5.1 Acids and Bases
- 5.2 Weak Acids and Weak Bases
- 5.3 Water and
- 5.4 Acid Strength
- 5.5 The Concept of Activity
- 5.6 Acid-Base Equilibrium Calculations
- Practice Exercises
- Chapter 6: Buffer Solutions and Polyprotic Acids
- 6.1 Buffer Solutions
- 6.2 Alpha Fraction Plots
- 6.3 Weak Acid Titration Curve
- 6.4 Polyprotic Acids
- Practice Exercises
- Chapter 7: Complexation and Precipitation Equilibria
- 7.1 Complex Terminology
- 7.2 Complex Equilibria
- 7.3 Competing Equilibria
- 7.4 Stepwise Complexation
- 7.5 Precipitate Equilibrium
- 7.6 Molar Solubility
- 7.7 Precipitation and Competing Equilibria
- Practice Exercises
- Part III: Instrumental Methods and Analytical Separations
- Chapter 8: Electroanalytical Chemistry
- 8.1 Introduction
- 8.2 Standard Reduction Potentials
- 8.3 Using Half Reactions
- 8.4 Background on Spontaneous Reactions and Equilibrium
- 8.5 Reaction Energies, Voltages, and the Nernst Equation
- 8.6 Electrochemical Cells
- 8.7 Potentiometry
- 8.8 ION-Selective Electrodes (ISE)
- 8.9 Voltammetry
- Practice Exercises
- Chapter 9: Atomic Spectrometry
- 9.1 Atomization
- 9.2 Atomic Absorption Spectrometry (AAS)
- 9.3 Atomic Emission Spectrometry (AES)
- 9.4 Introduction to Mass Spectrometry (MS)
- 9.5 ICP-MS Measurements
- 9.6 Summary
- Practice Exercises
- Chapter 10: Analytical Separations
- 10.1 Thin-Layer Chromatography
- 10.2 Chromatogram Terminology
- 10.3 Column Selection
- 10.4 High Performance Liquid Chromatography
- 10.5 Gas Chromatography