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150525s2015 nju ob 001 0 eng d |
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|a (OCoLC)937447219
|z (OCoLC)957125344
|z (OCoLC)981888662
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|a QD561
|b .M3365 2015
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|a SCI
|x 013050
|2 bisacsh
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|a 541/.372
|2 23
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|a UAMI
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|a Marcus, Y.,
|e author.
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|a Ions in solution and their solvation /
|c Yizhak Marcus.
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|a Hoboken, New Jersey :
|b John Wiley & Sons, Inc.,
|c ©2015.
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300 |
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|a 1 online resource
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336 |
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a text file
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|b PDF
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|a Includes bibliographical references and index.
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|a Title Page; Copyright Page; Contents; Preface; Chapter 1 Introduction; 1.1 THE SIGNIFICANCE AND PHENOMENOLOGY OF IONS IN SOLUTION; 1.2 LIST OF SYMBOLS AND ABBREVIATIONS; PRINCIPAL LATIN CHARACTERS; PRINCIPAL GREEK CHARACTERS; PRINCIPAL SUBSCRIPTS; PRINCIPAL SUPERSCRIPTS; Chapter 2 Ions and Their Properties; 2.1 IONS AS ISOLATED PARTICLES; 2.1.1 Bare Ions; 2.1.2 Ions in Clusters; 2.2 SIZES OF IONS; 2.3 IONS IN SOLUTION; 2.3.1 Thermodynamics of Ions in Aqueous Solutions; 2.3.1.1 Heat Capacities of Aqueous Ions; 2.3.1.2 Entropies of Aqueous Ions; 2.3.1.3 Enthalpies of Formation of Aqueous Ions.
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|a 2.3.1.4 Gibbs Energies of Formation of Aqueous Ions2.3.1.5 Ionic Molar Volumes in Aqueous Solutions; 2.3.2 Other Properties of Aqueous Ions; 2.3.2.1 Ionic Conductivities in Aqueous Solutions; 2.3.2.2 Ionic Self-Diffusion in Aqueous Solutions; 2.3.2.3 Ionic Effects on the Viscosity; 2.3.2.4 Ionic Effects on the Relaxation of NMR Signals; 2.3.2.5 Ionic Dielectric Decrements; 2.3.2.6 Ionic Effects on the Surface Tension; REFERENCES; Chapter 3 Solvents for Ions; 3.1 SOLVENT PROPERTIES THAT SUIT ION DISSOLUTION; 3.2 PHYSICAL PROPERTIES OF SOLVENTS; 3.2.1 Volumetric Properties.
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|a 3.2.2 Thermodynamic Properties3.2.3 Electrical, Optical, and Magnetic Properties; 3.2.4 Transport Properties; 3.3 CHEMICAL PROPERTIES OF SOLVENTS; 3.3.1 Structuredness; 3.3.2 Solvent Properties Related to Their Ion Solvating Ability; 3.3.2.1 Polarity; 3.3.2.2 Electron Pair Donicity and Ability to Accept a Hydrogen Bond; 3.3.2.3 Hydrogen Bond Donicity and Electron Pair Acceptance; 3.3.2.4 Softness; 3.3.3 Solvents as Acids and Bases; 3.3.4 Miscibility with and Solubility in Water; 3.3.5 Spectroscopic and Electrochemical Windows; 3.4 PROPERTIES OF BINARY AQUEOUS COSOLVENT MIXTURES.
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|a 3.4.1 Physical Properties of Binary Aqueous Mixtures with Cosolvents3.4.1.1 Thermodynamic Properties of the Mixtures; 3.4.1.2 Some Electrical, Optical, and Transport Properties of the Mixtures; 3.4.2 Chemical Properties of Binary Aqueous Mixtures with Cosolvents; 3.4.2.1 Structuredness; 3.4.2.2 Properties Related to the Ion Solvating Ability; REFERENCES; Chapter 4 Ion Solvation in Neat Solvents; 4.1 THE SOLVATION PROCESS; 4.2 THERMODYNAMICS OF ION HYDRATION; 4.2.1 Gibbs Energies of Ion Hydration; 4.2.1.1 Accommodation of the Ion in a Cavity; 4.2.1.2 Electrostatic Interactions.
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|a 4.2.2 Entropies of Ion Hydration4.2.3 Enthalpies of Ion Hydration; 4.3 TRANSFER THERMODYNAMICS INTO NONAQUEOUS SOLVENTS; 4.3.1 Selection of an Extra-Thermodynamic Assumption; 4.3.2 Thermodynamics of Transfer of Ions into Nonaqueous Solvents; 4.3.2.1 Gibbs Energies of Transfer; 4.3.2.2 Enthalpies of Transfer; 4.3.2.3 Entropies of Transfer; 4.3.2.4 Ionic Heat Capacities in Nonaqueous Solvents; 4.3.2.5 Ionic Volumes in Nonaqueous Solvents; 4.4 THE STRUCTURE OF SOLVATED IONS; 4.4.1 Hydration Numbers from Diffraction Studies; 4.4.2 Hydration Numbers from Computer Simulations.
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|a The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the s.
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|a Online resource; title from digital title page (viewed on February 08, 2016).
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|a ProQuest Ebook Central
|b Ebook Central Academic Complete
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650 |
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|a Ionic solutions.
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|a Ions.
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|a Solution (Chemistry)
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|a Solvation.
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|a Solutions ioniques.
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|a Ions.
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|a Solutions (Chimie)
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|a Solvatation.
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|a solution.
|2 aat
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|a SCIENCE
|x Chemistry
|x Physical & Theoretical.
|2 bisacsh
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|a Ionic solutions
|2 fast
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|a Ions
|2 fast
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|a Solution (Chemistry)
|2 fast
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|a Solvation
|2 fast
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|i has work:
|a Ions in solution and their solvation (Text)
|1 https://id.oclc.org/worldcat/entity/E39PCFVgmPWfrFBcQMtRmqhgDq
|4 https://id.oclc.org/worldcat/ontology/hasWork
|
776 |
0 |
8 |
|i Print version:
|a Marcus, Y.
|t Ions in solution and their solvation.
|d Hoboken, New Jersey : John Wiley & Sons, Inc., ©2016
|z 9781118889145
|w (DLC) 2015020563
|
856 |
4 |
0 |
|u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=4039588
|z Texto completo
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|b IZTAP
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