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Ions in solution and their solvation /

The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made through...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Marcus, Y. (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken, New Jersey : John Wiley & Sons, Inc., ©2015.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Marcus, Y.,  |e author. 
245 1 0 |a Ions in solution and their solvation /  |c Yizhak Marcus. 
264 1 |a Hoboken, New Jersey :  |b John Wiley & Sons, Inc.,  |c ©2015. 
300 |a 1 online resource 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
347 |a text file 
347 |b PDF 
504 |a Includes bibliographical references and index. 
505 0 |a Title Page; Copyright Page; Contents; Preface; Chapter 1 Introduction; 1.1 THE SIGNIFICANCE AND PHENOMENOLOGY OF IONS IN SOLUTION; 1.2 LIST OF SYMBOLS AND ABBREVIATIONS; PRINCIPAL LATIN CHARACTERS; PRINCIPAL GREEK CHARACTERS; PRINCIPAL SUBSCRIPTS; PRINCIPAL SUPERSCRIPTS; Chapter 2 Ions and Their Properties; 2.1 IONS AS ISOLATED PARTICLES; 2.1.1 Bare Ions; 2.1.2 Ions in Clusters; 2.2 SIZES OF IONS; 2.3 IONS IN SOLUTION; 2.3.1 Thermodynamics of Ions in Aqueous Solutions; 2.3.1.1 Heat Capacities of Aqueous Ions; 2.3.1.2 Entropies of Aqueous Ions; 2.3.1.3 Enthalpies of Formation of Aqueous Ions. 
505 8 |a 2.3.1.4 Gibbs Energies of Formation of Aqueous Ions2.3.1.5 Ionic Molar Volumes in Aqueous Solutions; 2.3.2 Other Properties of Aqueous Ions; 2.3.2.1 Ionic Conductivities in Aqueous Solutions; 2.3.2.2 Ionic Self-Diffusion in Aqueous Solutions; 2.3.2.3 Ionic Effects on the Viscosity; 2.3.2.4 Ionic Effects on the Relaxation of NMR Signals; 2.3.2.5 Ionic Dielectric Decrements; 2.3.2.6 Ionic Effects on the Surface Tension; REFERENCES; Chapter 3 Solvents for Ions; 3.1 SOLVENT PROPERTIES THAT SUIT ION DISSOLUTION; 3.2 PHYSICAL PROPERTIES OF SOLVENTS; 3.2.1 Volumetric Properties. 
505 8 |a 3.2.2 Thermodynamic Properties3.2.3 Electrical, Optical, and Magnetic Properties; 3.2.4 Transport Properties; 3.3 CHEMICAL PROPERTIES OF SOLVENTS; 3.3.1 Structuredness; 3.3.2 Solvent Properties Related to Their Ion Solvating Ability; 3.3.2.1 Polarity; 3.3.2.2 Electron Pair Donicity and Ability to Accept a Hydrogen Bond; 3.3.2.3 Hydrogen Bond Donicity and Electron Pair Acceptance; 3.3.2.4 Softness; 3.3.3 Solvents as Acids and Bases; 3.3.4 Miscibility with and Solubility in Water; 3.3.5 Spectroscopic and Electrochemical Windows; 3.4 PROPERTIES OF BINARY AQUEOUS COSOLVENT MIXTURES. 
505 8 |a 3.4.1 Physical Properties of Binary Aqueous Mixtures with Cosolvents3.4.1.1 Thermodynamic Properties of the Mixtures; 3.4.1.2 Some Electrical, Optical, and Transport Properties of the Mixtures; 3.4.2 Chemical Properties of Binary Aqueous Mixtures with Cosolvents; 3.4.2.1 Structuredness; 3.4.2.2 Properties Related to the Ion Solvating Ability; REFERENCES; Chapter 4 Ion Solvation in Neat Solvents; 4.1 THE SOLVATION PROCESS; 4.2 THERMODYNAMICS OF ION HYDRATION; 4.2.1 Gibbs Energies of Ion Hydration; 4.2.1.1 Accommodation of the Ion in a Cavity; 4.2.1.2 Electrostatic Interactions. 
505 8 |a 4.2.2 Entropies of Ion Hydration4.2.3 Enthalpies of Ion Hydration; 4.3 TRANSFER THERMODYNAMICS INTO NONAQUEOUS SOLVENTS; 4.3.1 Selection of an Extra-Thermodynamic Assumption; 4.3.2 Thermodynamics of Transfer of Ions into Nonaqueous Solvents; 4.3.2.1 Gibbs Energies of Transfer; 4.3.2.2 Enthalpies of Transfer; 4.3.2.3 Entropies of Transfer; 4.3.2.4 Ionic Heat Capacities in Nonaqueous Solvents; 4.3.2.5 Ionic Volumes in Nonaqueous Solvents; 4.4 THE STRUCTURE OF SOLVATED IONS; 4.4.1 Hydration Numbers from Diffraction Studies; 4.4.2 Hydration Numbers from Computer Simulations. 
520 |a The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the s. 
588 0 |a Online resource; title from digital title page (viewed on February 08, 2016). 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Ionic solutions. 
650 0 |a Ions. 
650 0 |a Solution (Chemistry) 
650 0 |a Solvation. 
650 6 |a Solutions ioniques. 
650 6 |a Ions. 
650 6 |a Solutions (Chimie) 
650 6 |a Solvatation. 
650 7 |a solution.  |2 aat 
650 7 |a SCIENCE  |x Chemistry  |x Physical & Theoretical.  |2 bisacsh 
650 7 |a Ionic solutions  |2 fast 
650 7 |a Ions  |2 fast 
650 7 |a Solution (Chemistry)  |2 fast 
650 7 |a Solvation  |2 fast 
758 |i has work:  |a Ions in solution and their solvation (Text)  |1 https://id.oclc.org/worldcat/entity/E39PCFVgmPWfrFBcQMtRmqhgDq  |4 https://id.oclc.org/worldcat/ontology/hasWork 
776 0 8 |i Print version:  |a Marcus, Y.  |t Ions in solution and their solvation.  |d Hoboken, New Jersey : John Wiley & Sons, Inc., ©2016  |z 9781118889145  |w (DLC) 2015020563 
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