1,1'-Binaphthyl-Based Chiral Materials : Our Journey.

Chiral materials have been studied in the Department of Chemistry at the University of Virginia for applications in areas like asymmetric catalysis, enantioselective fluorescent sensing, and optical/electrical materials. Optically active 1,1'-binaphthyl molecules are used to build novel chiral...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Lin, Pu
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Singapore : World Scientific Publishing Company, 2009.
Temas:
Chirality.
Asymmetric synthesis.
Molecular theory.
Chiralité.
Synthèse asymétrique.
Théorie moléculaire.
Asymmetric synthesis
Chirality
Molecular theory
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers.
  • 2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers.
  • 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction.
  • 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc.

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