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Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones An Approach through Asymmetric Organocatalysis /
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic α,β-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She descr...
| Cote: | Libro Electrónico |
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| Auteur principal: | |
| Collectivité auteur: | |
| Format: | Électronique eBook |
| Langue: | Inglés |
| Publié: |
Berlin, Heidelberg :
Springer Berlin Heidelberg : Imprint: Springer,
2012.
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| Édition: | 1st ed. 2012. |
| Collection: | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Sujets: | |
| Accès en ligne: | Texto Completo |
Table des matières:
- Background
- Asymmetric Organocatalysis
- Catalytic Asymmetric Epoxidation of Electron-Deficient Olefins
- Synthesis and Relevance of 3-Hydroxy-1,2-dioxolanes and 1,2-Dioxolanes
- Objectives of this Ph.D. Work
- Results and Discussion
- Catalytic Asymmetric Epoxidation of Cyclic Enones
- Catalytic Asymmetric Epoxidation and Hydroperoxidation of Acyclic Enones
- Synthetic Transformations of Optically Active a,ß-Epoxy Ketones and 3-Hydroxy-1,2-dioxolanes
- Summary and Conclusions
- Mechanistic Considerations
- Preparation of Starting Materials
- Catalyst Synthesis
- Summary
- Outlook
- Experimental Part
- General Experimental Conditions
- Catalytic Asymmetric Epoxidation of Cyclic Enones
- Catalytic Asymmetric Hydroperoxidation and Epoxidation of Acyclic Enones
- Synthetic Transformations of Optically Active Products
- Preparation of Starting Materials
- Catalyst Synthesis.