Handbook of Organic Name Reactions : Reagents, Mechanism and Applications.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Verma, Dakeshwar Kumar
Otros Autores: Dewangan, Yeestdev, Verma, Chandrabhan
Formato: Electrónico eBook
Idioma:Inglés
Publicado: San Diego : Elsevier, 2023.
Temas:
Chemical reactions.
Chemistry, Organic.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover
  • Handbook of Organic Name Reactions
  • Copyright Page
  • Contents
  • Foreword
  • Preface
  • 1 Organic reaction mechanism
  • 1.1 Basics of organic chemistry
  • 1.1.1 Inductive Effect
  • 1.1.2 Electromeric Effect
  • 1.1.3 Mesomeric effect/Resonating effect /Conjugation effect
  • 1.1.4 Resonance
  • 1.1.5 Hyperconjugation or no-bond resonance
  • 1.2 Reaction intermediates: carbocation, carbanion, free radical, carbene, nitrene, and benzyne
  • 1.2.1 Carbocation
  • 1.2.2 Carbanion
  • 1.2.3 Carbon-free radical
  • 1.2.4 Carbene
  • 1.2.5 Nitrene
  • 1.2.6 Benzyne/aryne
  • 1.3 Nucleophilic addition to carbon-heteroatoms multiple bonds
  • 1.4 Electrophilic addition to carbon-carbon multiple bonds
  • 1.4.1 Addition of bromine to alkenes
  • 1.4.2 Regioselectivity of electrophilic addition to unsymmetrical alkenes
  • 1.4.3 Formation of epoxide from alkene
  • 1.4.4 Reaction of NBS to alkene
  • 1.4.5 Iodo-and Bromo-lactonization
  • 1.4.6 Addition of water molecule to alkene and alkynes
  • 1.4.7 Dihydroxylation of alkenes
  • 1.4.8 Ozonolysis
  • 1.4.9 Hydroboration
  • 1.5 Nucleophilic aliphatic substitution and neighboring group participation
  • 1.6 Unimolecular nucleophilic substitution (SN1)reaction
  • 1.7 Bimolecular nucleophilic substitution (SN2)reaction
  • 1.8 Neighbouring group participation (NGP)
  • 1.9 Substitution nucleophilic internal (SNi) Mechanism
  • 1.10 Nucleophilic aromatic substitution
  • 1.10.1 Addition-elimination mechanism (An activatedcomplex mechanism)
  • 1.10.2 Elimination-addition mechanism (Benzyne mechanism)
  • 1.11 Electrophilic aliphatic, alkenyl, and alkynyl substitution reaction
  • 1.11.1 Unimolecular electrophilic aliphatic substitution (SE1) reaction
  • 1.11.2 Bimolecular aliphatic electrophilic substitution reaction (SE1 and SEi)
  • 1.11.3 Electrophilic substitution reaction at the allylic group
  • 1.12 Electrophilic aromatic substitution reaction
  • 1.13 Elimination reaction
  • 1.13.1 Unimolecular elimination (E1) reaction
  • 1.13.2 Bimolecular elimination E2 reaction
  • 1.13.3 Unimolecular conjugated base (E1cB) Elimination reaction
  • References
  • 2 Reactions of aldehydes and ketones
  • 2.1 Aldol condensation reaction
  • 2.1.1 Cross-aldol condensation reaction
  • 2.1.1.1 Reactivity of carbonyl compounds with nucleophilic agents
  • 2.1.2 Henry nitroaldol condensation
  • 2.1.3 Intramolecular aldol condensation
  • 2.1.4 Barbas-list asymmetric aldol reaction
  • 2.1.5 Mukaiyama aldol reaction
  • 2.2 Baeyer-Villiger oxidation
  • 2.3 Bamford-Stevens reaction
  • 2.3.1 Selectivity in Bamford-Stevens reaction
  • 2.4 Barton decarboxylation reaction
  • 2.5 Barbier reaction
  • 2.6 Barbier in situ Grignard reaction
  • 2.7 Baer-Fischer amino sugar synthesis
  • 2.8 Baylis-Hillman reaction
  • 2.8.1 Intramolecular Baylis-Hillman reaction
  • 2.9 Benzoin condensation
  • 2.10 Bischler-Napieralski reaction

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