Molecularly Imprinted Polymers (MIPs) Commercialization Prospects.
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
San Diego :
Elsevier,
2023.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover
- Molecularly Imprinted Polymers (MIPs)
- Molecularly Imprinted Polymers (MIPs): Commercialization Prospects
- Copyright
- Contents
- Contributors
- Preface
- 1
- An introduction to molecularly imprinted polymers
- 1. Introduction
- 2. Concept
- 3. Components required for synthesis of MIP
- 3.1 Functional monomers
- 3.1.1 1,3-Diaryl urea
- 3.1.2 1-Vinyl imidazole
- 3.1.3 2,6-Bisacrylamide pyridine
- 3.1.4 2-Acrylamido-2-methyl-1-[propanesulfonic acid]
- 3.1.5 2-Hydroxy ethyl methacrylate
- 3.1.6 2-Vinyl pyridine and 4-vinyl pyridine
- 3.1.7 4-Vinylbenzoic acid
- 3.1.8 4-Vinyl aniline or 4-amino styrene
- 3.1.9 2-Aminoethyl methacrylate
- 3.1.10 3-Methacrylamidopropyl trimethylammonium chloride (MAPTAC)
- 3.1.11 Acrolein
- 3.1.12 Acrylamide (AAm)
- 3.1.13 Acrylic acid
- 3.1.14 Acrylonitrile
- 3.1.15 Allylamine
- 3.1.16 o-aminophenol
- 3.1.17 3-Aminophenyl boronic acid
- 3.1.18 3-Aminopropyl methacrylamide
- 3.1.19 Aniline
- 3.1.20 2-(Dimethylamino)ethyl methacrylate (2-DEMA)
- 3.1.21 (Diethylamino)ethyl methacrylic acid (DEAEM)
- 3.1.22 Dopamine
- 3.1.23 Ethylene glycol dimethacrylate (EDMA)
- 3.1.24 Itaconic acid (IA)
- 3.1.25 Methacrylic acid (MAA)
- 3.1.26 p-Divinyl benzene
- 3.1.27 Phenol
- 3.1.28 Phenylene diamine
- 3.1.29 Pyrrole
- 3.1.30 Styrene
- 3.1.31 Thiophene
- 3.1.32 Urocanic acid
- 3.1.33 Vinyl benzene
- 3.2 Cross-linker
- 3.2.1 Ethylene glycol dimethacrylate (EGDMA)
- 3.2.2 Epichlorohydrin
- 3.2.3 N, N'-methylenebisacrylamide
- 3.2.4 Trimethylolpropane trimethacrylate (TRIM)
- 3.2.5 Trimethylpropane trimethacrylate (TMPTMA))
- 3.3 Initiator
- 3.3.1 Azobisisobutyronitrile (AIBN)
- 3.3.2 Potassium persulfate
- 3.3.3 Ammonium persulfate (NH4)2S2O8
- 3.3.4 Potassium peroxodisulfate
- 3.3.5 Benzoyl peroxide
- 4. Polymerization methods
- 4.1 Free radical polymerization
- 4.2 Living/controlled radical polymerization
- 4.3 Atom transfer radical polymerization
- 4.4 Reversible addition-fragmentation transfer polymerization
- 4.5 Iniferter polymerization
- 4.6 Nitroxide-mediated polymerization
- 5. Polymeric format for molecular imprinting
- 5.1 Bulk/conventional polymerization
- 5.2 Surface imprinting
- 5.3 Nanoscale imprinting
- 6. Thermodynamic and kinetic aspects
- 6.1 Thermodynamic parameters
- 6.2 Kinetic models/theories
- 6.3 Adsorption models/theories
- 7. Conclusion
- References
- 2
- Computer-aided modeling for rational design of molecularly imprinted polymers
- 1. Introduction
- 2. Computational techniques
- 2.1 Molecular mechanics
- 2.2 Molecular dynamics
- 2.3 Quantum mechanics
- 2.4 ab initio computational methods
- 2.5 Density functional theory
- 3. Drawbacks and improvements
- 4. Conclusion
- References
- 3
- Inefficient removal of templates as a limitation for molecular imprinting of polymers
- Abbreviations
- 1. Introduction
- 2. Factors leading to efficient removal of templates as limitations to molecular imprinting