Synthesis of nanostructured materials in near and/or supercritical fluids : methods, fundamentals and modeling /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Erkey, Can, T�urk, Michael
Formato: Electrónico eBook
Idioma:Inglés
Publicado: [Place of publication not identified] : Elsevier, 2021.
Colección:Supercritical fluid science and technology ; 8
Temas:
Nanostructured materials > Synthesis.
Supercritical fluids.
Nanomat�eriaux > Synth�ese.
Fluides supercritiques.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Synthesis of Nanostructured Materials in Near and/or Supercritical Fluids: Methods, Fundamentals and Modeling
  • Copyright
  • Contents
  • Foreword
  • Preface
  • Chapter 1: Introduction
  • 1.1. Some conventions
  • 1.2. Motivation
  • 1.2.1. Metallic materials
  • 1.2.2. Metal oxide materials
  • 1.3. Scope of the book
  • References
  • Chapter 2: Compounds of interest
  • 2.1. Introduction
  • 2.2. Types of coordination compounds
  • 2.3. Structures and bonding in coordination compounds
  • 2.4. Reactions of organometallic compounds on surfaces
  • Chapter 3: Support materials
  • 3.1. Different support materials
  • 3.1.1. Silicas
  • 3.1.2. Mesoporous silicas
  • 3.1.3. Aluminas
  • 3.1.4. Zeolites
  • 3.1.5. Silica-aluminas
  • 3.1.6. Metal-organic frameworks
  • 3.1.7. Aerogels
  • 3.1.8. Silica aerogel
  • 3.1.9. Alumina aerogel
  • 3.1.10. Carbonaceous supports
  • 3.1.11. Carbon aerogels
  • 3.1.12. Graphene aerogels
  • 3.2. Characterization of porous materials
  • 3.2.1. Nitrogen physisorption
  • 3.2.2. X-ray diffraction
  • References
  • Chapter 4: Fundamental aspects of pure supercritical fluids
  • 4.1. Introduction
  • 4.2. Thermal and caloric properties
  • 4.3. Transport properties
  • 4.4. Applications of supercritical fluids
  • References
  • Chapter 5: Thermodynamics and transport properties of mixtures composed of metal complexes and supercritical fluids
  • 5.1. Introduction
  • 5.2. Phase behavior
  • 5.3. Solubility and binary diffusion coefficients of metal complexes in SCF
  • 5.4. Determination of high-pressure phase behavior data
  • 5.5. Experimental procedure
  • 5.6. Modeling solubility of metal complexes in SCFs
  • 5.7. Experimental determination and modeling of the solubility of salts in sub and supercritical H2O
  • References
  • Chapter 6: Thermodynamics and kinetics of adsorption of metal complexes on surfaces from supercritical solutions
  • 6.1. Adsorption
  • 6.1.1. Physisorption
  • 6.1.2. Chemisorption
  • 6.2. Adsorption isotherms
  • 6.2.1. Adsorption isotherm models
  • 6.2.1.1. The Langmuir model
  • 6.2.1.2. The Freundlich model
  • 6.3. Adsorption of supercritical fluids
  • 6.4. Adsorption of solutes from supercritical mixtures
  • 6.5. Adsorption of metal complexes on surfaces
  • 6.5.1. Experimental techniques for determination of adsorption isotherms
  • 6.5.1.1. Batch adsorption
  • 6.5.1.2. Frontal analysis chromatography
  • 6.5.2. Adsorption isotherms for metal complex-adsorbent-scCO2 systems
  • 6.5.3. Kinetics of adsorption of metal complexes on porous substrates from supercritical solutions
  • References
  • Chapter 7: Synthesis of nanostructured composites of metals by supercritical deposition (SCD)
  • 7.1. Supported nanoparticles on inorganic and carbon supports
  • 7.2. Polymer supported nanoparticles
  • 7.3. Supported bimetallic and multimetallic nanoparticles
  • 7.4. Metallic films
  • 7.5. Comparison with other methods
  • References

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