Pincer-metal complexes : applications in catalytic dehydrogenation chemistry /

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and d...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Kumar, Akshai (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam, The Netherlands ; Cambridge, MA : Elsevier, [2022]
Temas:
Dehydrogenation.
Transition metal compounds > Industrial applications.
D�eshydrog�enation.
M�etaux de transition > Compos�es > Applications industrielles.
Dehydrogenation
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover
  • Pincer-Metal Complexes
  • Copyright Page
  • Contents
  • List of contributors
  • Foreword
  • Preface
  • 1 Application of pincer metal complexes in catalytic transformations
  • 1.1 Introduction
  • 1.2 Dehydrogenation of ammonia borane and its derivatives
  • 1.3 Dinitrogen activation using pincer ligands
  • 1.3.1 Catalytic dinitrogen activation using Mo pincer catalyst
  • 1.3.2 Catalytic dinitrogen activation using 3d metal pincer catalyst
  • 1.3.3 Catalytic dinitrogen fixation using earlier transition metals (V, Ti, Zr)
  • 1.3.4 N-X bond formation with metal nitride in pincer complexes
  • 1.3.5 Catalytic silylation of dinitrogen using transition metal pincer complexes
  • 1.4 Pincer complexes as hydrogenation catalyst
  • 1.4.1 Ester hydrogenation
  • 1.4.2 Amide hydrogenation
  • 1.4.3 Hydrogenation of urea, carbamate, carbonate, and imides derivatives
  • 1.4.4 Nitrile hydrogenation
  • 1.4.5 Hydrogenation of alkynes
  • 1.5 Coupling reaction: C-C bond formation reaction
  • 1.5.1 Mizoroki-Heck reaction
  • 1.5.2 Suzuki-Miyaura reaction
  • 1.5.3 Sonogashira, Negishi, Kumada-Corriu, Stille cross-coupling
  • 1.6 Redox-Active Pincer Complexes
  • 1.7 Conclusion
  • References
  • 2 Pincer-group(8) and pincer-group(9) metal complexes for catalytic alkane dehydrogenation reactions
  • 2.1 Introduction
  • 2.1.1 Alkane dehydrogenation
  • 2.2 Dehydrogenation reactions of alkane using pincer-Ir complexes
  • 2.2.1 Initial reports based on pincer-Ir catalysts
  • 2.2.2 Alkane dehydrogenation by PC(sp2)P-Ir systems
  • 2.2.3 Alkane dehydrogenation by PYC(sp2)ZP-Ir (Y=O, S, CH2) systems
  • 2.2.4 Mechanism of pincer-Ir-catalyzed alkane dehydrogenation
  • 2.2.5 Solid/gas-phase alkane dehydrogenation
  • 2.2.6 Continuous-flow gas-phase alkane dehydrogenation
  • 2.2.7 Alkane dehydrogenation by PC(sp3)P-Ir complexes
  • 2.2.8 Alkane dehydrogenation by POCN-Ir, PBP-Ir, PNP-Ir, and PAlP complexes
  • 2.2.9 Alkane dehydrogenation by PXC(sp2)NP-Ir-HCl (X=O, S) complexes
  • 2.2.10 Alkane dehydrogenation by non-phosphine-based iridium pincer complexes
  • 2.3 Dehydrogenation of alkanes by pincer-metal complexes other than iridium
  • 2.3.1 Ruthenium pincer complexes for alkane dehydrogenation
  • 2.3.2 Osmium pincer complexes for alkane dehydrogenation
  • 2.3.3 Rhodium pincer complexes for alkane dehydrogenation
  • 2.4 Applications of alkane dehydrogenation
  • 2.4.1 Alkane metathesis
  • 2.4.2 Alkane coupling
  • 2.4.3 Synthesis of aromatics
  • 2.4.3.1 Dehydroaromatization
  • 2.4.3.2 Cyclodimerization
  • 2.4.3.3 Alkyl group cross metathesis
  • 2.4.3.4 Alkyl-aryl coupling
  • 2.4.4 Functionalization of alkanes
  • 2.4.4.1 Silylation and borylation
  • 2.4.4.2 Formylation and aminomethylation
  • 2.5 Summary and outlook
  • References
  • 3 Transition metal-catalyzed dehydrogenation of methanol and related transformations
  • 3.1 Introduction

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