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Handbook of carbon-based nanomaterials /

Handbook of Carbon-Based Nanomaterials provides a comprehensive overview of carbon-based nanomaterials and recent advances in these specialized materials. This book opens with a brief introduction to carbon, including the different forms of carbon and their range of uses. Each chapter systematically...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Thomas, Sabu (Editor ), Sarathchandran, C., 1978- (Editor ), Ilangovan, S. A. (Editor ), Moreno-Pirajan, Juan Carlos (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; Cambridge, MA : Elsevier, [2021]
Colección:Micro & nano technologies.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Handbook of Carbon-Based Nanomaterials
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Chapter 1: Introduction to carbon
  • 1. Introduction
  • 2. Different allotropes of carbon
  • 2.1. Diamond
  • 2.2. Graphite
  • 2.3. Carbynes
  • 2.4. Fullerenes
  • 2.5. Carbon nanotubes
  • 2.6. Amorphous carbon
  • 3. Carbide derived carbon
  • 4. Carbon-carbon composites
  • 5. Characterization techniques
  • 6. Advanced applications of carbon based materials
  • 7. Conclusion
  • References
  • Chapter 2: Fullerenes and their applications
  • 1. Introduction to fullerenes
  • 2. Synthesis of fullerenes
  • 2.1. Synthesis of empty fullerenes
  • 2.1.1. Laser vaporization
  • 2.1.2. Arc discharge
  • 2.1.3. Combustion
  • 2.1.4. High-frequency furnace
  • 2.1.5. Solar generation
  • 2.1.6. Pyrolysis of PAHs
  • 2.1.7. Plasma method
  • 2.1.8. Chemical synthesis
  • 2.1.9. High-temperature halogenation
  • 2.2. Synthesis of endohedral fullerenes
  • 2.2.1. Laser vaporization
  • 2.2.2. Arc discharge
  • 2.2.2.1. N2
  • 2.2.2.2. NH3
  • 2.2.2.3. CH4 and H2
  • 2.2.2.4. O2 and CO2
  • 2.2.2.5. SO2
  • 2.2.2.6. Inorganic compounds
  • 2.2.2.7. Organic molecules
  • 2.2.3. High-pressure methods
  • 2.2.4. Ion implantation
  • 2.2.5. Hot-atom incorporation
  • 2.2.6.�� Molecular surgery��
  • 3. Structure of fullerenes
  • 3.1. Isolated pentagon rule
  • 3.2. Fullerenes in Euler geometry
  • 3.3. Spiral algorithm
  • 3.4.�� Stone-Wales�� transformations
  • 3.5. Structures of fullerenes
  • 3.5.1. Empty fullerenes
  • 3.5.1.1. C20 and C36
  • 3.5.1.2. C50-C58
  • 3.5.1.3. C60-C68
  • 3.5.1.4. C70-C78
  • 3.5.1.5. C80-C88
  • 3.5.1.6. C90-C98
  • 3.5.1.7. C100-C108
  • 3.5.2. Endohedral fullerenes
  • 3.5.2.1. C60-C68
  • 3.5.2.2. C70-C78
  • 3.5.2.3. C80-C88
  • 3.5.2.4. C90-C98
  • 3.5.2.5. C100-C108
  • 4. Fullerene functionalization
  • 4.1. Nucleophilic addition
  • 4.1.1. Addition of carbon nucleophiles
  • 4.1.1.1. Cyclopropanation
  • 4.1.1.2. Hydroalkylation and hydroarylation
  • 4.1.1.3. Cyanide addition
  • 4.1.2. Addition of hydroxides and alkoxides
  • 4.1.3. Addition of amines
  • 4.1.4. Addition of phosphorous nucleophiles
  • 4.1.5. Addition of silicon and germanium nucleophiles
  • 4.2. Tether-directed multifunctionalization
  • 4.3. Hydrogenation reactions
  • 4.3.1. Metal/acid system methods
  • 4.3.2. Birch reduction
  • 4.3.3. Hydroboration
  • 4.3.4. Hydrozirconation
  • 4.3.5. Metal-catalyzed reactions
  • 4.3.6. Solid-phase reaction
  • 4.4. Halogenation reactions
  • 4.4.1. Fluorination
  • 4.4.1.1. Direct fluorination with F2
  • 4.4.1.2. Fluorination with noble gas fluorides and halogen fluorides
  • 4.4.1.3. Reaction with metal fluorides
  • 4.4.2. Chlorination
  • 4.4.3. Bromination
  • 4.4.4. Reaction with iodine
  • 4.4.5. Halogenation of higher fullerenes
  • 4.5. Reactions with electrophiles and oxidation
  • 4.5.1. Oxygenation reactions
  • 4.5.2. Osmylation reactions
  • 4.5.3. Reactions with strong acids and oxidizing agents
  • 4.5.4. Reactions with Lewis acids