Handbook of carbon-based nanomaterials /
Handbook of Carbon-Based Nanomaterials provides a comprehensive overview of carbon-based nanomaterials and recent advances in these specialized materials. This book opens with a brief introduction to carbon, including the different forms of carbon and their range of uses. Each chapter systematically...
Clasificación: | Libro Electrónico |
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Otros Autores: | , , , |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Amsterdam ; Cambridge, MA :
Elsevier,
[2021]
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Colección: | Micro & nano technologies.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Intro
- Handbook of Carbon-Based Nanomaterials
- Copyright
- Contents
- Contributors
- Preface
- Chapter 1: Introduction to carbon
- 1. Introduction
- 2. Different allotropes of carbon
- 2.1. Diamond
- 2.2. Graphite
- 2.3. Carbynes
- 2.4. Fullerenes
- 2.5. Carbon nanotubes
- 2.6. Amorphous carbon
- 3. Carbide derived carbon
- 4. Carbon-carbon composites
- 5. Characterization techniques
- 6. Advanced applications of carbon based materials
- 7. Conclusion
- References
- Chapter 2: Fullerenes and their applications
- 1. Introduction to fullerenes
- 2. Synthesis of fullerenes
- 2.1. Synthesis of empty fullerenes
- 2.1.1. Laser vaporization
- 2.1.2. Arc discharge
- 2.1.3. Combustion
- 2.1.4. High-frequency furnace
- 2.1.5. Solar generation
- 2.1.6. Pyrolysis of PAHs
- 2.1.7. Plasma method
- 2.1.8. Chemical synthesis
- 2.1.9. High-temperature halogenation
- 2.2. Synthesis of endohedral fullerenes
- 2.2.1. Laser vaporization
- 2.2.2. Arc discharge
- 2.2.2.1. N2
- 2.2.2.2. NH3
- 2.2.2.3. CH4 and H2
- 2.2.2.4. O2 and CO2
- 2.2.2.5. SO2
- 2.2.2.6. Inorganic compounds
- 2.2.2.7. Organic molecules
- 2.2.3. High-pressure methods
- 2.2.4. Ion implantation
- 2.2.5. Hot-atom incorporation
- 2.2.6.�� Molecular surgery��
- 3. Structure of fullerenes
- 3.1. Isolated pentagon rule
- 3.2. Fullerenes in Euler geometry
- 3.3. Spiral algorithm
- 3.4.�� Stone-Wales�� transformations
- 3.5. Structures of fullerenes
- 3.5.1. Empty fullerenes
- 3.5.1.1. C20 and C36
- 3.5.1.2. C50-C58
- 3.5.1.3. C60-C68
- 3.5.1.4. C70-C78
- 3.5.1.5. C80-C88
- 3.5.1.6. C90-C98
- 3.5.1.7. C100-C108
- 3.5.2. Endohedral fullerenes
- 3.5.2.1. C60-C68
- 3.5.2.2. C70-C78
- 3.5.2.3. C80-C88
- 3.5.2.4. C90-C98
- 3.5.2.5. C100-C108
- 4. Fullerene functionalization
- 4.1. Nucleophilic addition
- 4.1.1. Addition of carbon nucleophiles
- 4.1.1.1. Cyclopropanation
- 4.1.1.2. Hydroalkylation and hydroarylation
- 4.1.1.3. Cyanide addition
- 4.1.2. Addition of hydroxides and alkoxides
- 4.1.3. Addition of amines
- 4.1.4. Addition of phosphorous nucleophiles
- 4.1.5. Addition of silicon and germanium nucleophiles
- 4.2. Tether-directed multifunctionalization
- 4.3. Hydrogenation reactions
- 4.3.1. Metal/acid system methods
- 4.3.2. Birch reduction
- 4.3.3. Hydroboration
- 4.3.4. Hydrozirconation
- 4.3.5. Metal-catalyzed reactions
- 4.3.6. Solid-phase reaction
- 4.4. Halogenation reactions
- 4.4.1. Fluorination
- 4.4.1.1. Direct fluorination with F2
- 4.4.1.2. Fluorination with noble gas fluorides and halogen fluorides
- 4.4.1.3. Reaction with metal fluorides
- 4.4.2. Chlorination
- 4.4.3. Bromination
- 4.4.4. Reaction with iodine
- 4.4.5. Halogenation of higher fullerenes
- 4.5. Reactions with electrophiles and oxidation
- 4.5.1. Oxygenation reactions
- 4.5.2. Osmylation reactions
- 4.5.3. Reactions with strong acids and oxidizing agents
- 4.5.4. Reactions with Lewis acids