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Handbook of greener synthesis of nanomaterials and compounds. Volume 1, Fundamental principles and methods /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Kharisov, Boris I. (Editor ), Kharissova, Oxana Vasilievna (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Elsevier, 2021.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front cover
  • Half title
  • Full title
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Part I
  • Fundamentals of greener synthesis
  • 1
  • The Fundamental perspectives of greener synthesis
  • 1.1 Introduction
  • 1.2 General synthetic methods in green chemistry
  • 1.2.1 Ultrasound-assisted nanoparticle synthesis
  • 1.2.2 Microwave-assisted nanoparticles synthesis
  • 1.2.3 Reactor technology in NP synthesis
  • 1.3 Green solvents in synthetic methods
  • 1.3.1 Applications of ionic liquids in NPs synthesis
  • 1.3.2 Applications of scCO 2 in NPs synthesis
  • 1.4 Conclusions
  • Acknowledgments
  • References
  • 2
  • The importance of green chemistry metrics
  • 2.1 Introduction
  • 2.2 Green metrics parameters
  • 2.2.1 Organic chemistry metrics
  • 2.2.1.1 Atom economy (AE), atom efficiency (AEf) and atom utilization (AU)
  • 2.2.1.2 Environmental assessment tool for organic syntheses (EATOS)
  • 2.2.1.3 E-Factor
  • 2.2.1.4 Carbon efficiency
  • 2.2.1.5 Effective mass yield (EMY)
  • 2.2.1.6 Reaction mass efficiency (RME)
  • 2.2.1.7 Mass intensity (MI) or product mass intensity (PMI)
  • 2.2.1.8 Stoichiometric factor
  • 2.2.1.9 Solvent and catalyst environmental impact parameter
  • 2.2.2 Analytical chemistry metrics
  • 2.2.2.1 National environmental methods index (NEMI)
  • 2.2.2.2 Analytical eco-scale
  • 2.2.2.3 Green certificate
  • 2.2.2.4 Green analytical procedure index (GAPI)
  • 2.2.2.5 Analytical method volume intensity (AMVI)
  • 2.2.3 Industry metrics
  • 2.2.3.1 Life cycle assessment (LCA)
  • 2.2.3.2 Carbon footprint
  • 2.2.3.3 Green aspiration level (GAL)
  • 2.3 Final remarks
  • References
  • 3
  • Greener synthesis at different scales
  • 3.1 Introduction
  • 3.1.1 Motivation and goal of the present chapter
  • 3.2 Synthesis at macroscale
  • 3.2.1 Organic compounds
  • 3.2.2 Polymers
  • 3.2.3 Metal oxides and other systems
  • 3.2.4 Organometallic complexes and MOFs
  • 3.2.5 Biomaterials
  • 3.2.6 Pharmaceuticals
  • 3.3 Greener synthesis at nanoscale
  • 3.3.1 Different strategies for the greener synthesis of nanomaterials
  • 3.3.2 Bacteria in NP synthesis
  • 3.3.3 Actinomycetes in NP synthesis
  • 3.3.4 Fungi in NP synthesis
  • 3.3.5 Algae in NP synthesis
  • 3.3.6 Virus-based NP synthesis
  • 3.3.7 Synthesis of NPs using plant extracts
  • 3.3.8 Factors affecting the synthesis of NPs
  • 3.3.9 Mechanism: NPs synthesis using microorganisms
  • 3.3.10 Nonbiogenic greener approaches
  • 3.3.11 Different NPs synthesized using green processes
  • 3.3.12 Nanomaterials, nanocomposites, and hybrids
  • 3.4 Possibilities of the synthesis at industrial scale
  • 3.4.1 A few scaled up greener syntheses
  • 3.5 Summary and final remarks
  • References
  • 4
  • Role of greener syntheses at the nanoscale
  • 4.1 Introduction
  • 4.2 Green syntheses
  • 4.3 Role of green synthesis
  • 4.3.1 Metal NPs
  • 4.3.2 Nonmetal NPs
  • 4.3.3 Noble-metal NPs.