Polymer science and nanotechnology : fundamentals and applications /

Polymer Science and Nanotechnology: Fundamentals and Applications brings together the latest advances in polymer science and nanoscience. Sections explain the fundamentals of polymer science, including key aspects and methods in terms of molecular structure, synthesis, characterization, microstructu...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Narain, Ravin
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Elsevier, 2020.
Temas:
Polymers.
Nanotechnology.
Polymers
Polym�eres.
polymers.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Polymer Science and Nanotechnology: Fundamentals and Applications
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Part I: Polymer science
  • Chapter 1: Brief overview of polymer science
  • 1.1. Basic concepts
  • 1.2. Classification of polymers
  • 1.2.1. Polymer structure
  • 1.2.2. Polymerization techniques
  • 1.2.3. Intermolecular forces
  • 1.3. Natural vs synthetic polymers
  • References
  • Chapter 2: Nature and molecular structure of polymers
  • 2.1. Natural vs synthetic polymers
  • 2.2. Structure of polymers
  • 2.2.1. Amorphous vs crystalline polymers
  • 2.2.2. Primary structure
  • 2.2.2.1. Monomer polarity
  • 2.2.3. Secondary structure
  • 2.2.3.1. Polymer chain configuration
  • 2.2.4. Tertiary structure
  • 2.3. Molecular weight
  • References
  • Chapter 3: Polymer synthesis
  • 3.1. Step-growth polymerization
  • 3.1.1. General characteristics
  • 3.1.2. Polymerization of tri- and higher-order functional monomers
  • 3.1.3. Polymer types and structure
  • 3.2. Chain-growth polymerization
  • 3.2.1. General characteristics
  • 3.2.2. Polymerizability (thermodynamics)
  • 3.2.2.1. Equilibrium
  • 3.2.3. Stereochemistry of chain-growth polymerization
  • 3.2.4. ``Living�� versus ``controlled�� polymerization
  • 3.2.5. Free-radical polymerization
  • 3.2.5.1. Conventional free-radical polymerization
  • Initiators
  • Initiation
  • Propagation
  • Termination
  • Inhibitors
  • Chain transfer
  • Chain transfer agents
  • 3.2.6. Kinetics of chain-growth polymerization
  • 3.2.6.1. Initiation
  • 3.2.6.2. Propagation
  • 3.2.6.3. Termination
  • 3.2.6.4. Chain transfer
  • 3.2.6.5. Rate of polymerization
  • 3.2.6.6. Trommsdorff-Norrish effect or auto-acceleration or gel effect
  • 3.2.7. Controlled/living radical polymerization
  • 3.2.7.1. Nitroxide-mediated polymerization
  • 3.2.7.2. Atom transfer radical polymerization
  • Monomer
  • Initiator
  • Catalysts complex
  • Solvent
  • Temperature
  • 3.2.7.3. Reversible addition-fragmentation chain transfer (RAFT) polymerization
  • RAFT procedure
  • RAFT mechanism
  • 3.2.8. Ionic polymerization
  • 3.2.8.1. Anionic polymerization
  • Overview
  • Solvent
  • Initiation
  • Electron transfer
  • Nucleophilic addition to the monomer double bond
  • Propagation
  • Termination
  • 3.2.8.2. Cationic polymerization
  • Initiation
  • Bronsted acid
  • Lewis acid
  • Propagation
  • Termination
  • 3.2.8.3. Group transfer polymerization
  • 3.2.8.4. Ring-opening polymerization
  • Thermodynamics
  • Kinetics
  • 3.2.8.5. Coordination polymerization
  • Ziegler-Natta catalysts
  • Termination
  • Metallocenes
  • 3.2.8.6. Ring-opening metathesis polymerization
  • Catalysts
  • 3.3. Solution polymerization
  • 3.4. Suspension polymerization
  • 3.4.1. Process description
  • 3.4.2. Size control
  • 3.4.3. Quality and morphology
  • 3.5. Emulsion polymerization
  • 3.5.1. Conventional emulsion polymerization
  • 3.5.1.1. Miniemulsion
  • 3.5.1.2. Microemulsion
  • Process description
  • Size control

Ejemplares similares