Opportunities for fluoropolymers : synthesis, characterization, processing, simulation and recycling /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Am�eduri, B., Fomin, Sergey
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Elsevier, 2020.
Colección:Progress in fluorine science series.
Temas:
Fluoropolymers.
Fluoropolymers
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title
  • Copyright
  • Contents
  • Contributors
  • About the editors
  • Preface
  • Chapter 1
  • Semi-fluorinated aromatic ether polymers via step-growth polymerization of fluoroalkenes
  • 1
  • Introduction
  • 2
  • Synthesis of perfluorocyclobutyl (pfcb) aromatic ether polymers from trifluorovinyl ether-bearing monomers
  • 2.1
  • Synthesis of trifluorovinyl aromatic ethers (TFVE)
  • 2.2
  • Synthesis of multifunctional trifluorovinyl ether (TFVE)-bearing monomers
  • 2.3
  • PFCB containing monomers for classical polymerization
  • 2.4
  • Postpolymerization modification on PFCB aryl ether polymers
  • 2.5
  • Characterization of TFVE monomers and PFCB aromatic ether polymers
  • 2.5.1
  • Infrared and Raman spectroscopy of TFVE monomers and PFCB aromatic ether polymers
  • 2.5.2
  • Carbon nuclear magnetic resonance (NMR) spectroscopy
  • 2.5.3
  • Fluorine NMR spectroscopy
  • 2.5.4
  • Differential scanning calorimetry (DSC)
  • 3
  • Synthesis and characterization of perfluorocycloalkenyl (PFCA) aromatic ether polymers
  • 3.1
  • Select perfluorocycloalkenyl monomers used for synthesizing PFCA aromatic ether polymers
  • 3.1.1
  • Direct step-growth polycondensation of perfluorocycloalkenes with bisphenols
  • 3.1.2
  • Step-growth polycondensation of PFCA-end capped monomers bis(AA)-type with bisphenols
  • 3.1.3
  • AB-type difunctional monomers in PFCA synthesis
  • 3.1.4
  • PFCA as building block toward PFCA-enchained polymer synthesis
  • 4
  • Synthesis and characterization of semi-fluorinated arylene vinylene ether (FAVE) polymers
  • 4.1
  • Synthesis of FAVE polymers from the step-growth polycondensation of TFVE monomers and bisphenols
  • 4.1.1
  • Direct step-growth polycondensation of TFVE and bisphenols
  • 4.1.2
  • Step-growth polycondensation of TFVE- and hydroxyl-group containing oligomers
  • 4.1.3
  • Postpolymerization modification of FAVE polymers
  • 4.1.4
  • Enchainment of chromophoric units in FAVE polymers
  • 5
  • Conclusion
  • Abbreviations
  • References
  • CHAPTER 2
  • Iodine transfer emulsion polymerizations of vinylidene fluoride
  • 1
  • Introduction
  • 2
  • Results and discussion
  • 2.1
  • Experimental considerations
  • 2.2
  • Pressure impact on VDF ITP in emulsion
  • 2.3
  • Impact of CTA structure and concentration on particle size distributions
  • 3
  • Conclusions
  • References
  • Chapter 3
  • Fluorinated initiators, mediators, and solvents in controlled radical polymerization
  • 1
  • Introduction: general aspects of controlled radical polymerization
  • 2
  • Fluorinated agents in CRP
  • 2.1
  • Fluorinated iniferters and chain transfer agents (for RAFT)
  • 2.2
  • Fluorinated alkoxyamines and nitroxides for nitroxide mediated polymerization
  • 2.3
  • Fluorinated alkyl halides and ligands for ATRP
  • 3
  • Fluorine-containing macroinitiators
  • 4
  • Fluorinated solvents
  • 5
  • Conclusion and outlooks
  • 6
  • Acknowledgments
  • References
  • Chapter 4
  • Specifics of the Mn2(CO)10 photomediated synthesis of PVDF block copolymers

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