Annual Reports on NMR Spectroscopy. Volume 100.

Annual Reports on NMR Spectroscopy, Volume 100, is a premier resource for both specialists and non-specialists who are looking to become familiar with new techniques and applications in NMR spectroscopy. Chapters in this new release cover In Operando NMR Studies, Recent Developments in Automotive Di...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Academic Press, 2020.
Temas:
Nuclear magnetic resonance spectroscopy.
Spectrum analysis.
Magnetic Resonance Spectroscopy
Spectroscopie de la r�esonance magn�etique nucl�eaire.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Annual Reports on NMR spectroscopy
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Chapter One: Solid-state NMR of small molecule adsorption in metal-organic frameworks (MOFs)
  • 1. Introduction
  • 2. Solid-state NMR of adsorbed molecules in MOFs
  • 3. Remarks on MOF materials
  • 4. Adsorbed molecules
  • 4.1. Xenon, Xe
  • 4.2. Water, H2O
  • 4.3. Carbon dioxide, CO2
  • 4.3.1. Effect of CO2 adsorption on host structure
  • 4.3.2. CO2 dynamics
  • 4.3.3. PFG NMR
  • 4.4. Hydrogen, H2
  • 4.5. Carbon monoxide, CO
  • 4.6. Nitric oxide, NO
  • 4.7. Hydrocarbons
  • 4.7.1. Methane, CH4
  • 4.7.2. Ethene/ethane, C2H4/C2H6
  • 4.7.3. Aromatics
  • 4.7.4. Methanol, CH3OH
  • 4.7.5. Other organic compounds
  • 4.8. Molecules with metal atoms
  • 4.9. Other systems
  • 5. The importance of calculations
  • 6. Selected techniques-highlights
  • 7. Conclusions and outlook
  • References
  • Chapter Two: Acidity characterization of solid acid catalysts by solid-state 31P NMR of adsorbed phosphorus-containing prob ...
  • 1. Introduction
  • 2. Acidity characterization by 31P solid-state NMR spectroscopy
  • 2.1. 31P-TMP approach
  • 2.2. 31P-R3PO approach
  • 2.3. Other 31P SSNMR approaches using phosphorus-containing probes
  • 3. Applications of 31P SSNMR for acidity characterization
  • 3.1. Discernment of acid types
  • 3.2. Characterization of acidic strength
  • 3.2.1. Microporous zeolites and mesoporous molecular sieves
  • 3.2.2. Metal oxides and mixed metal oxides
  • 3.2.3. Heteropolyacids
  • 3.2.4. other functionalized solid acid materials
  • 3.2.5. Commercial catalysts
  • 3.3. Location, distribution and spatial proximity of acid sites
  • 3.4. Reaction mechanism
  • 4. Summary
  • Acknowledgements
  • References
  • Chapter Three: 15N NMR coordination shifts in transition metal complexes and organometallics with heterocycles containing n ...
  • 1. Transition metal complexes and organometallics with azines
  • 1.1. 15N NMR coordination shifts in square-planar (d8) Pd(II)- and Pt(II)-azine complexes or organometallics
  • 1.2. 15N NMR coordination shifts in square-planar (d8) Rh(I)- and Ir(I)-azine complexes or organometallics
  • 1.3. 15N NMR coordination shifts in octahedral (d6) Co(III)-, Rh(III)-, and Ir(III)-azine complexes or organometallics
  • 1.4. 15N NMR coordination shifts in octahedral (d6) Fe(II)-, Ru(II)-, and Os(II)-azine complexes or organometallics
  • 1.5. 15N NMR coordination shifts in (d10) Cu(I)- and Ag(I)-azine complexes or organometallics
  • 1.6. 15N NMR coordination shifts in square-planar (d8) Au(III)-azine complexes or organometallics
  • 1.7. 15N NMR coordination shifts in (d10) Zn(II)- and Cd(II)-azine complexes
  • 2. Transition metal complexes and organometallics with azoles
  • 2.1. 15N NMR coordination shifts in square-planar (d8) Pd(II)- and Pt(II)-azole complexes or organometallics

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