Advances in heterocyclic chemistry. Volume 132 /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Scriven, Eric F. V., Ramsden, Christopher A., 1946-
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge, MA : Academic Press, 2020.
Colección:Issn Ser.
Temas:
Heterocyclic chemistry.
Chimie des compos�es h�et�erocycliques.
Heterocyclic chemistry
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover
  • Advances in Heterocyclic Chemistry
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Chapter One: Application of electrochemical oxidative methods in the C(sp)H functionalization of heterocyclic compounds
  • 1. Introduction
  • 2. CC bond formation
  • 2.1. Alkylation
  • 2.2. Arylation
  • 2.3. Cyanation
  • 3. CN bond formation
  • 4. CO bond formation
  • 5. CP, CS bonds formation
  • 6. CHalide bond formation
  • 7. Conclusion
  • Acknowledgments
  • References
  • Chapter Two: Recent developments in the chemistry of sydnones and sydnone imines
  • 1. Sydnones
  • 1.1. Introduction
  • 1.2. Preparation of sydnones
  • 1.3. Reactions with retention of the oxadiazole ring
  • 1.3.1. Electrophilic substitution
  • 1.3.1.1. Halogenation
  • 1.3.1.2. Chlorosulfonylation
  • 1.3.1.3. Acylation
  • 1.3.1.4. Miscellaneous electrophilic substitution reactions at C(4)
  • 1.3.2. Direct arylation, alkenylation, and alkynylation of sydnones
  • 1.3.3. Reactions of 4-halogeno-substituted sydnones
  • 1.3.4. Reactions of 4-formylsydnones
  • 1.3.4.1. Synthesis of imines
  • 1.3.4.2. 3-Arylsydnone-4-carbohydroximic acid chlorides
  • 1.3.4.3. Knoevenagel condensation
  • 1.3.5. Reactions of 4-acetylsydnones
  • 1.3.6. Organometallic derivatives
  • 1.3.6.1. Lithio derivatives
  • 1.3.6.2. Transition metal complexes
  • 1.3.7. Side-chain reactions
  • 1.4. Sydnone reactions associated with oxadiazole ring opening
  • 1.4.1. Cycloaddition reactions
  • 1.4.1.1. Introduction
  • 1.4.1.2. [3+2]-Cycloaddition of sydnones with alkynes
  • 1.4.1.3. Strain-promoted sydnone cycloadditions
  • 1.4.1.4. Copper-catalyzed sydnone-alkyne cycloaddition reactions
  • 1.4.1.5. [3+2]-Cycloaddition of sydnones with arynes
  • 1.4.1.6. [3+2]-Cycloaddition of sydnones with alkenes
  • 1.4.1.7. Miscellaneous cycloadditions
  • 1.4.1.8. Syntheses of 1,3,4-oxadiazolin-2-ones
  • 1.4.2. Masked hydrazines and other reaction
  • 1.5. Biological activity of sydnone derivatives
  • 1.6. Sydnones in polymer chemistry
  • 1.7. Liquid crystal, optical, and electrochemical properties of sydnones
  • 2. Sydnone imines
  • 2.1. Preparation of sydnone imines
  • 2.2. Reactions of sydnone imines
  • 2.2.1. Reactions at the exocyclic N6 atom of sydnone imines
  • 2.2.2. Reactions at C(4)-position
  • 2.2.2.1. 4-Halogen-substituted derivatives
  • 2.2.2.2. 4-Lithium derivatives
  • 2.2.3. Transition metal derivatives of sydnone imines
  • 2.2.4. Side-chain reactions
  • 2.3. Bicyclic sydnone imines
  • 2.4. Cycloaddition of sydnone imines
  • 2.5. Biologically activity of sydnone imines
  • Acknowledgments
  • References
  • Chapter Three: The chemistry of thieno[b]pyrrolones, dihydrothieno[b]pyrrolones, and their fused derivatives
  • 1. Introduction
  • 2. Thieno[2,3-b]pyrrolones
  • 2.1. Thieno[2,3-b]pyrrol-2-ones
  • 2.1.1. Properties
  • 2.1.1.1. Nuclear magnetic resonance spectroscopy
  • 2.1.1.2. Infrared spectroscopy
  • 2.1.2. Reactivity
  • 2.1.2.1. Reaction with nucleophiles

Ejemplares similares