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Palladacycles : catalysis and beyond /
Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles hav...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam :
Elsevier,
2019.
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| Edición: | First edition. |
| Colección: | Latest trends in palladium chemistry.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Palladacycles: Catalysis And Beyond; Copyright; Contents; Contributors; Chapter 1: Palladacycles as Efficient Precatalysts for Suzuki-Miyaura Cross-Coupling Reactions; 1. Introduction; 2. Imine and Amine Palladacycles; 3. Oxime Palladacycles; 4. Ferrocene Palladacycles; 5. Pincer Palladacycles; 6. Phosphorus Donor Atom Palladacycles; 7. Carbene Palladacycles; 8. Alternative Palladacycles; 9. Conclusions; References; Chapter 2: Palladacycles as Precatalysts for Heck and Sonogashira Cross-Coupling Reactions; 1. Introduction; 2. Phosphine-Based Palladacycles
- 2.1. Heck Cross-Coupling Reaction2.1.1. Herrmann-Beller-Type Palladacycles; 2.1.2. Other Dimeric and Monomeric Phosphapalladacycles; 2.1.3. Diphosphine-Palladacycles; 2.2. Sonogashira Cross-Coupling Reaction; 3. Ferrocene-Based Palladacycles; 3.1. Heck Cross-Coupling Reaction; 3.1.1. Ferrocene-Based Palladacycles With N(sp3) Atom; 3.1.2. Ferrocene-Based Palladacycles With N(sp2) Atom; 3.1.2.1. Imine-Derived Ferrocenyl Palladacycles; 2.1.2.2. Oxime-Derived Ferrocenyl Palladacycles; 3.1.3. Other Ferrocenyl Palladacycles; 3.2. Sonogashira Cross-Coupling Reaction
- 4. Amine/Imine/Oxime-Based Palladacycles4.1. Heck Cross-Coupling Reaction; 4.1.1. Amine-Based Palladacycles; 4.1.2. Imine-Based Palladacycles; 4.1.3. Oxime-Based Palladayclces; 4.1.4. N-Heterocycles C, N or C, N, N-Donor Palladacycles; 4.1.5. Other Nitrogen-Containing Palladacycles; 4.2. Sonogashira Cross-Coupling Reaction; 5. N-Heterocyclic Carbene-Based Palladacycles; 5.1. Heck Cross-Coupling Reaction; 5.1.1. Imidazol-2-ylidene NHC-Based Palladacycles; 5.1.2. Functionalized Imidazol-2-ylidene NHC-Based Palladacycles; 5.1.2.1. Pyridyl-Imidazol-2-ylidene NHC-Based Palladacycles
- 5.1.2.2. Other Imidazol-2-ylidene NHC-based palladacycles5.1.3. Benzimidazol-2-ylidene NHC-Based Palladacycles; 5.1.4. Other NHC-Based Palladacycles; 5.2. Sonogashira Cross-Coupling Reaction; 6. Pincer-Based Palladacycles; 6.1. Heck Cross-coupling Reaction; 6.1.1. PCP- and PNP-Pincer Palladacycles; 6.1.2. NCN- and CNC Pincer Palladacycles; 6.1.3. SCS-, SNS-, SeCSe- and SeNSe-Pincer Palladacycles; 6.1.4. CNN-Pincer Palladacycles; 6.1.5. LCL- and LNL-Pincer Palladacycles (L=C, N, or O; L=C, N, O, S, Se, P); 6.2. Sonogashira Cross-Coupling Reaction; 7. Other Palladacycles
- 7.1. Heck Cross-Coupling Reaction7.2. Sonogashira Cross-Coupling Reaction; 8. Conclusions and Prospects; References; Chapter 3: Palladacycles as Efficient Precatalysts for Negishi and Buchwald-Hartwig Amination Reactions; 1. Introduction; 1.1. Buchwald-Hartwig Amination: A Brief Historic Perspective; 1.2. General Features; 1.2.1. Mechanism; 1.2.2. Role of Ancillary Ligands; 1.2.3. Palladium Source; 2. Types of Palladacycles Used in Buchwald-Hartwig CN Bond Forming Reactions; 2.1. Group 1: Herrmann-Beller Palladacycle and Others Incorporating a CP Backbone