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Copper(I) chemistry of phosphines, functionalized phosphines and phosphorus heterocycles /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam, Netherlands :
Elsevier,
2019.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Copper(I) Chemistry of Phosphines, Functionalized Phosphines, and Phosphorus Heterocycles; Copyright Page; Dedication; Contents; List of contributors; Preface; 1 Copper(I) complexes of low-coordinate phosphorus(III) compounds; 1.1 Introduction; 1.1.1 Electronic properties of low-coordinate phosphorus compounds; 1.2 Phosphaalkenes as ligands; 1.3 Phosphorus heterocycles as ligands; 1.3.1 Four-membered heterocycles with two phosphorus atoms; 1.3.2 Five-membered heterocylces with one phosphorus atom; 1.3.3 Five-membered heterocycles with two phosphorus atoms
- 1.3.4 Five-membered heterocycles with three phosphorus atoms1.3.5 Five-membered heterocycles with five phosphorus atoms; 1.3.6 Formally cationic five-membered phosphorus heterocycles; 1.3.7 Six-membered heterocycles: phosphinines; 1.4 Reactions of phosphinines with Cu(I); 1.5 Reactions of phosphaalkynes with Cu(I); References; 2 Polymetallic Cu(I) complexes based on bridging phosphine ligands; 2.1 Introduction; 2.2 The representation of the bridging coordination mode in phosphane complexes; 2.3 The first descriptions of symmetrically bridging phosphine ligands
- 2.3.1 Tertiary phosphanes as bridging ligands in Rh(I) organometallic bimetallic complexes2.3.2 Bridging phosphane ligands in Pd(I) bimetallic coordination complexes based on N, P, N chelates bearing a phosphole ring; 2.3.3 Toward an extension of the bridging phosphane coordination mode to other polymetallic systems?; 2.4 Coordination chemistry of bridging phosphane ligands bearing a phosphole ring with the Cu(I) metal center; 2.4.1 Bimetallic Cu(I) complexes bearing a bridging phosphane ligand based on the 2,5-bis(2-pyridyl)phosphole ligand 1
- 2.5.4 Formation of one-dimensional coordination polymers based on Cu(I) supramolecular nodes bearing bridging phosphane ligand2.5.5 Cu(I) compact supramolecular assemblies bearing a bridging phosphane ligand and ditopic inorganic linkers: "sterical ... ; 2.6 Conclusion; References; 3 Phosphine-copper(I) complexes as anticancer agents: design, synthesis, and physicochemical characterization. Part I; Abbreviations; 3.1 Why copper, why copper(I) complexes, and why hydrophilic phosphine-copper(I) complexes as potential metal-based antitum ...