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Progress in heterocyclic chemistry. Volume 30 /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam, Netherlands :
Elsevier,
[2018]
|
| Colección: | Progress in Heterocyclic Chemistry ;
Volume 30 |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover
- PROGRESS IN HETEROCYCLIC CHEMISTRY
- PROGRESS IN HETEROCYCLIC CHEMISTRY
- Copyright
- CONTENTS
- CONTRIBUTORS
- FOREWORD
- EDITORIAL ADVISORY BOARD MEMBERS PROGRESS IN HETEROCYCLIC CHEMISTRY
- 1
- Nitrogen-Philic Cyclization of Acyl Radicals Enables the Synthesis of Lactams
- 1.1 INTRODUCTION
- 1.1.1 Exo Cyclization of Acyl Radicals Onto Imine N-C Double Bond
- 1.1.2 Endo Cyclization of Acyl Radicals Onto Imine CN Double Bond
- 1.2 ACYL RADICAL CYCLIZATION ONTO AMINE NITROGEN
- 1.3 ACYL RADICAL CYCLIZATION ONTO AZIDE NITROGEN
- 1.4 SYNTHESIS OF LACTAMS VIA [2+2+1] CYCLOADDITION
- 1.5 AMINOCARBONYLATION LEADING TO LACTAMS
- 1.6 CONCLUSIONS
- REFERENCES
- 2
- The Silyl-Prins Reaction as an Emerging Method for the Synthesis of Heterocycles
- 2.1 INTRODUCTION
- 2.2 SYNTHESIS OF OXACYCLES BY SILYL-PRINS CYCLIZATIONS WITH ALLYLSILANES
- 2.2.1 Synthesis of Five-Membered Oxacycles
- 2.2.2 Synthesis of Six-Membered Oxacycles
- 2.2.2.1 Synthesis of Dihydropyrans and Tetrahydropyrans
- 2.2.2.2 Synthesis of Methylenetetrahydropyrans
- 2.3 SYNTHESIS OF SEVEN- TO TEN-MEMBERED OXACYCLES
- 2.3.1 Oxepanes
- 2.3.2 Oxocanes
- 2.3.3 Macrocyclic Systems
- 2.3.4 Synthesis of Bicycles
- 2.4 SYNTHESIS OF OXACYCLES BY SILYL-PRINS CYCLIZATIONS WITH VINYLSILANES
- 2.4.1 Synthesis of Five-Membered Oxacycles
- 2.4.2 Synthesis of Six-Membered Oxacycles
- 2.4.3 Synthesis of Seven-Membered Oxacycles
- 2.4.4 Synthesis of Bicycles
- 2.5 SYNTHESIS OF AZACYCLES BY SILYL-AZA-PRINS CYCLIZATIONS
- 2.5.1 Allyl Silanes
- 2.5.1.1 Five-Membered Azacycles
- 2.5.1.2 Six-Membered Azacycles
- 2.5.1.3 Seven-Membered Azacycles
- 2.5.1.4 Bicyclic Systems
- 2.5.2 Vinyl Silanes
- 2.5.2.1 Six-Membered Azacycles
- 2.5.2.2 Bicyclic Systems
- 2.6 OTHER SILANES
- 2.7 SUMMARY
- REFERENCES
- 3
- Three-Membered Ring Systems
- 3.1 INTRODUCTION.
- 5.2.4.1.3 Intramolecular Type c
- 5.2.4.1.4 Intramolecular Type e
- 5.2.4.2 Intermolecular Approaches to Indoles
- 5.2.4.2.1 Intermolecular Type ab
- 5.2.4.2.2 Intermolecular Type ac
- 5.2.4.2.3 Intermolecular Type bc
- 5.2.4.2.4 Intermolecular Type ce
- 5.2.4.2.5 Other Intermolecular Syntheses of Indole
- 5.2.5 REACTIONS OF INDOLES
- 5.2.5.1 Substitution at C2/C3
- 5.2.5.1.1 C2 Substitution
- 5.2.5.1.1.1 Directed C-H Functionalization
- 5.2.5.1.1.2 Innate C-H Functionalization
- 5.2.5.1.2 C2 Substitution, Ring-Forming
- 5.2.5.1.3 C2-C3 Annulation/Functionalization
- 5.2.5.1.4 C3 Substitution
- 5.2.5.1.5 C3 Substitution, Ring-Forming
- 5.2.5.2 Substitution at Nitrogen
- 5.2.5.3 Functionalization of the Benzene Ring
- 5.2.5.3.1 C-H Functionalization
- 5.2.5.3.2 From Prefunctionalized Indoles (e.g., Halides, Triflates, etc.)
- 5.2.6 ISATINS, OXINDOLES, INDOXYLS, AND SPIROOXINDOLES
- 5.2.7 CARBAZOLES
- 5.2.8 AZAINDOLES
- 5.2.9 ISOINDOLES
- REFERENCES
- 5.3
- Five-Membered Ring Systems: Furans and Benzofurans
- 5.3.1 INTRODUCTION
- 5.3.2 REACTIONS
- 5.3.2.1 Furans
- 5.3.3 SYNTHESIS
- 5.3.3.1 Furans
- 5.3.3.2 Benzo[b]furans and Related Compounds
- ACKNOWLEDGMENTS
- REFERENCES
- 5.4
- Five-Membered Ring Systems: With More Than One N Atom
- 5.4.1 INTRODUCTION
- 5.4.2 PYRAZOLES AND RING-FUSED DERIVATIVES
- 5.4.3 IMIDAZOLES AND RING-FUSED DERIVATIVES
- 5.4.4 1,2,3-TRIAZOLES AND RING-FUSED DERIVATIVES
- 5.4.5 1,2,4-TRIAZOLES AND RING-FUSED DERIVATIVES
- 5.4.6 TETRAZOLES AND RING-FUSED DERIVATIVES
- REFERENCES
- 5.5
- Five-Membered Ring Systems: With N and S Atoms
- 5.5.1 INTRODUCTION
- 5.5.2 THIAZOLES
- 5.5.2.1 Synthesis of Thiazoles
- 5.5.2.2 Synthesis of Thiazolines
- 5.5.2.3 Synthesis of Benzothiazoles
- 5.5.2.4 Reactions of Thiazoles and Fused Derivatives
- 5.5.2.5 New Thiazole-Containing Natural Products.
- 5.5.2.6 Biologically Active Thiazoles and Isothiazoles
- 5.5.3 ISOTHIAZOLES
- 5.5.4 THIADIAZOLES
- REFERENCES
- 5.6
- Five-Membered Ring Systems: With O and S (Se, Te) Atoms
- 5.6.1 1,3-DIOXOLES AND DIOXOLANES
- 5.6.2 1,3-DITHIOLES AND DITHIOLANES
- 5.6.3 1,3-OXATHIOLES AND OXATHIOLANES
- 5.6.4 1,2-DITHIOLES AND DITHIOLANES
- 5.6.5 THREE HETEROATOMS
- REFERENCES
- 5.7
- Five-Membered Ring Systems: With O and N Atoms
- 5.7.1 ISOXAZOLES
- 5.7.2 ISOXAZOLINES
- 5.7.3 ISOXAZOLIDINES
- 5.7.4 OXAZOLES
- 5.7.5 OXAZOLINES
- 5.7.6 OXAZOLIDINES
- 5.7.7 OXADIAZOLES
- REFERENCES
- 6.1
- Six-Membered Ring Systems: Pyridine and Benzo Derivatives
- 6.1.1 INTRODUCTION
- 6.1.2 PYRIDINES
- 6.1.2.1 Preparation of Pyridines
- 6.1.2.2 Reactions of Pyridines
- 6.1.3 QUINOLINES
- 6.1.3.1 Preparation of Quinolines
- 6.1.3.2 Reactions of Quinolines
- 6.1.4 ISOQUINOLINES
- 6.1.4.1 Preparation of Isoquinolines
- 6.1.4.2 Reactions of Isoquinolines
- REFERENCES
- 6.2
- Six-Membered Ring Systems: Diazines and Benzo Derivatives
- 6.2.1 Introduction
- 6.2.2 Pyridazines and Benzo Derivatives
- 6.2.2.1 Syntheses
- 6.2.2.2 Reactions
- 6.2.2.3 Applications
- 6.2.3 Pyrimidines and Benzo Derivatives
- 6.2.3.1 Syntheses
- 6.2.3.2 Reactions
- 6.2.3.3 Applications
- 6.2.4 Pyrazines and Benzo Derivatives
- 6.2.4.1 Syntheses
- 6.2.4.2 Reactions
- 6.2.4.3 Applications
- References
- 6.3
- Triazines, Tetrazines, and Fused Ring Polyaza Systems
- 6.3.1 INTRODUCTION
- 6.3.2 TRIAZINES
- 6.3.2.1 1,2,3-Triazines or v-Triazines and 1,2,4-Triazines or a-Triazines
- 6.3.2.2 1,3,5-Triazines (s-Triazines)
- 6.3.2.2.1 Chemistry
- 6.3.2.2.2 Triazines for Material Chemistry
- 6.3.2.2.3 Triazines for Biomedical and Related Applications
- 6.3.2.2.4 Triazines for Fluorescence and Optics-Related Applications
- 6.3.2.2.5 Miscellaneous
- 6.3.3 TETRAZINES.
- 6.3.3.1 Synthetic Chemistry
- 6.3.3.2 Tetrazines for Click Chemistry and Related Applications
- 6.3.3.3 Applications for Optics: New Dyes
- 6.3.3.4 Miscellaneous
- 6.3.4 FUSED HIGHER POLYAZAAROMATICS
- 6.3.4.1 [6+5] Fused Systems: Purines and Related Heterocycles
- 6.3.4.1.1 Purines and Related Heterocycles
- 6.3.4.2 [6+6] Fused Systems: Pteridines and Related Heterocycles
- 6.3.4.3 New Polyazafused Rings and Heptazines
- REFERENCES
- 6.4
- Six-Membered Ring Systems: With O and/or S Atoms
- 6.4.1 INTRODUCTION
- 6.4.2 HETEROCYCLES CONTAINING ONE OXYGEN ATOM
- 6.4.2.1 Pyrans
- 6.4.2.2 [1]Benzopyrans and Dihydro[1]benzopyrans
- 6.4.2.2.1 Chromenes and Chromans
- 6.4.2.3 [2]Benzopyrans and Dihydro[2]benzopyrans
- 6.4.2.3.1 Isochromenes and Isochromans
- 6.4.2.4 Pyranones
- 6.4.2.5 Coumarins
- 6.4.2.6 Chromones and Chromanones
- 6.4.2.7 Xanthenes and Xanthones
- 6.4.3 HETEROCYCLES CONTAINING ONE OR TWO SULFUR ATOMS
- 6.4.3.1 Thiopyrans and Analogs
- 6.4.3.2 Dithiin Analogs
- 6.4.4 HETEROCYCLES CONTAINING TWO OR MORE OXYGEN ATOMS
- 6.4.4.1 Dioxanes
- 6.4.5 HETEROCYCLES CONTAINING BOTH OXYGEN AND SULFUR IN THE SAME RING
- 6.4.5.1 Oxathianes
- REFERENCES
- 7
- Seven-Membered Rings
- 7.1 INTRODUCTION
- 7.2 SEVEN-MEMBERED SYSTEMS CONTAINING ONE HETEROATOM
- 7.2.1 Azepanes and Derivatives
- 7.2.2 Benzazepines and Derivatives
- 7.2.3 Fused Azepanes and Derivatives
- 7.2.4 Oxepanes and Fused Derivatives
- 7.2.5 Thiepines and Fused Derivatives
- 7.3 SEVEN-MEMBERED SYSTEMS CONTAINING TWO HETEROATOMS
- 7.3.1 Diazepines and Fused Diazepines
- 7.3.1.1 Benzodiazepines and Derivatives
- 7.3.2 Oxazepanes and Fused Derivatives
- 7.3.3 Thiazepines and Derivatives
- 7.3.4 Dioxepines, Dithiepines, Oxathiepines, and Derivatives
- 7.4 SEVEN-MEMBERED SYSTEMS CONTAINING THREE OR MORE HETEROATOMS.