Cargando…
Advances in Transition-Metal Mediated Heterocyclic Synthesis /
Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals�i�A�to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London :
Academic Press, An imprint of Elsevier,
[2018]
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Advances in Transition-Metal Mediated Heterocyclic Synthesis; Copyright Page; Contents; List of Contributors; Foreword; 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols; 1.1 Introduction; 1.2 Silver-Catalyzed Reactions; 1.3 Gold-Catalyzed Reactions; 1.4 Platinum-Catalyzed Reactions; 1.5 Palladium-Catalyzed Reactions; 1.6 Lanthanum-Catalyzed Reactions; 1.7 Gallium-Catalyzed Reactions; 1.8 Conclusion; References; 2 Intramolecular Diamination of Alkenes; 2.1 Introduction.
- 2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes2.2.1 Palladium Catalysis; 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants; 2.2.3 Copper Catalysis; 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes; 2.3.1 Palladium Catalysis; 2.3.2 Copper Catalysis; 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes; 2.5 Summary and Outlook; References.
- 3.2.2.2 With Halides Together With Nucleophilic Partners3.2.2.3 With Halides Together With Electrophilic Partners; 3.2.2.4 With Halides Together With Alkenes and Imines; 3.2.2.5 With Halides Together With Alkynes and Arynes; 3.2.2.6 With Other Substrates; 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle; 3.3.1 Under Oxidative Conditions; 3.3.1.1 Through Carbonylative Carbocyclization; 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation; 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling.
- 3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition3.3.2 Under Nonoxidative Conditions; 3.3.2.1 With Halides; 3.3.2.2 With Imine Derivatives; 3.3.2.3 With Functionalized Alkynes; 3.4 Conclusions and Perspectives; References; 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions; 4.1 Introduction; 4.2 Cyclization Prior to Metal Carbene Formation; 4.3 Cyclization Through Other Carbene Precursors; 4.4 Cyclization Through Reductive Elimination; 4.5 Cyclization Through Nucleophilic Displacement.