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180524s2018 enka ob 001 0 eng d |
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|a 9780128116524
|q (electronic bk.)
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|a 0128116528
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|z 9780128116517
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|z 012811651X
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|a (OCoLC)1037272358
|z (OCoLC)1037808063
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|z (OCoLC)1105189577
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|a SCI
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|a 547.59
|2 23
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|a Advances in Transition-Metal Mediated Heterocyclic Synthesis /
|c edited by Daniel Sol�e, Israel Fern�andez.
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|a London :
|b Academic Press, An imprint of Elsevier,
|c [2018]
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|a 1 online resource :
|b illustrations
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a Includes bibliographical references and index.
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|a Online resource; title from PDF title page (EBSCO, viewed May 25, 2018).
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|a Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals�i�A�to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals.
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|6 880-01
|a Front Cover; Advances in Transition-Metal Mediated Heterocyclic Synthesis; Copyright Page; Contents; List of Contributors; Foreword; 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols; 1.1 Introduction; 1.2 Silver-Catalyzed Reactions; 1.3 Gold-Catalyzed Reactions; 1.4 Platinum-Catalyzed Reactions; 1.5 Palladium-Catalyzed Reactions; 1.6 Lanthanum-Catalyzed Reactions; 1.7 Gallium-Catalyzed Reactions; 1.8 Conclusion; References; 2 Intramolecular Diamination of Alkenes; 2.1 Introduction.
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|a 2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes2.2.1 Palladium Catalysis; 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants; 2.2.3 Copper Catalysis; 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes; 2.3.1 Palladium Catalysis; 2.3.2 Copper Catalysis; 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes; 2.5 Summary and Outlook; References.
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|a 3.2.2.2 With Halides Together With Nucleophilic Partners3.2.2.3 With Halides Together With Electrophilic Partners; 3.2.2.4 With Halides Together With Alkenes and Imines; 3.2.2.5 With Halides Together With Alkynes and Arynes; 3.2.2.6 With Other Substrates; 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle; 3.3.1 Under Oxidative Conditions; 3.3.1.1 Through Carbonylative Carbocyclization; 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation; 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling.
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|a 3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition3.3.2 Under Nonoxidative Conditions; 3.3.2.1 With Halides; 3.3.2.2 With Imine Derivatives; 3.3.2.3 With Functionalized Alkynes; 3.4 Conclusions and Perspectives; References; 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions; 4.1 Introduction; 4.2 Cyclization Prior to Metal Carbene Formation; 4.3 Cyclization Through Other Carbene Precursors; 4.4 Cyclization Through Reductive Elimination; 4.5 Cyclization Through Nucleophilic Displacement.
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|a Heterocyclic compounds.
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|a Transition metals.
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|a Transition metal catalysts.
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|a Heterocyclic Compounds
|0 (DNLM)D006571
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650 |
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|a Compos�es h�et�erocycliques.
|0 (CaQQLa)201-0006824
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650 |
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|a M�etaux de transition.
|0 (CaQQLa)201-0011368
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650 |
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|a Catalyseurs �a base de m�etaux de transition.
|0 (CaQQLa)201-0064129
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|a SCIENCE
|x Chemistry
|x Organic.
|2 bisacsh
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|a Heterocyclic compounds
|2 fast
|0 (OCoLC)fst00955736
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650 |
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7 |
|a Transition metal catalysts
|2 fast
|0 (OCoLC)fst01154758
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650 |
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7 |
|a Transition metals
|2 fast
|0 (OCoLC)fst01154781
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700 |
1 |
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|a Sol�e, Daniel,
|e editor.
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700 |
1 |
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|a Fern�andez, Israel,
|e editor.
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776 |
0 |
8 |
|i Print version:
|t Advances in Transition-Metal Mediated Heterocyclic Synthesis.
|d London : Academic Press, An imprint of Elsevier, [2018]
|z 012811651X
|z 9780128116517
|w (OCoLC)1011519523
|
856 |
4 |
0 |
|u https://sciencedirect.uam.elogim.com/science/book/9780128116517
|z Texto completo
|
880 |
8 |
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|6 505-01/(S
|a 3 Synthesis of Heterocycles by Palladium-Catalyzed Carbonylative Reactions3.1 Introduction; 3.2 Palladium-Catalyzed Cyclocarbonylations Leading to Heterocycles; 3.2.1 Under Oxidative Conditions; 3.2.1.1 With Alkyne and Alkene Derivatives (Without Direct C-H Activation); 3.2.1.2 With Acetylenic C-H Activation; 3.2.1.3 With Alkenylic C-H Activation; 3.2.1.4 With Aromatic C-H Activation; 3.2.1.5 With Aliphatic C-H Activation; 3.2.1.6 With Diols, β-Amino Alcohols, Diamines, and Related Compounds; 3.2.2 Under Nonoxidative Conditions; 3.2.2.1 With Functionalized Halides.
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