Cargando…

Advances in Transition-Metal Mediated Heterocyclic Synthesis /

Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals�i�A�to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Sol�e, Daniel (Editor ), Fern�andez, Israel (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: London : Academic Press, An imprint of Elsevier, [2018]
Temas:
Acceso en línea:Texto completo

MARC

LEADER 00000cam a2200000 i 4500
001 SCIDIR_on1037272358
003 OCoLC
005 20231120010256.0
006 m o d
007 cr cnu|||unuuu
008 180524s2018 enka ob 001 0 eng d
040 |a N$T  |b eng  |e rda  |e pn  |c N$T  |d N$T  |d OPELS  |d YDX  |d EBLCP  |d OCLCF  |d STF  |d MERER  |d OCLCQ  |d CNCGM  |d OTZ  |d NLE  |d INT  |d AU@  |d UKMGB  |d OCLCQ  |d U3W  |d LVT  |d OCLCQ  |d D6H  |d SNK  |d LQU  |d ABC  |d OCLCQ  |d S2H  |d OCLCO  |d OCLCQ  |d OCLCO  |d K6U  |d OCLCQ  |d SFB  |d OCLCQ  |d OCLCO 
066 |c (S 
016 7 |a 018880091  |2 Uk 
019 |a 1037808063  |a 1039404455  |a 1105189577  |a 1105573803  |a 1229491629 
020 |a 9780128116524  |q (electronic bk.) 
020 |a 0128116528  |q (electronic bk.) 
020 |z 9780128116517 
020 |z 012811651X 
035 |a (OCoLC)1037272358  |z (OCoLC)1037808063  |z (OCoLC)1039404455  |z (OCoLC)1105189577  |z (OCoLC)1105573803  |z (OCoLC)1229491629 
050 4 |a QD400.5.S95 
072 7 |a SCI  |x 013040  |2 bisacsh 
082 0 4 |a 547.59  |2 23 
245 0 0 |a Advances in Transition-Metal Mediated Heterocyclic Synthesis /  |c edited by Daniel Sol�e, Israel Fern�andez. 
264 1 |a London :  |b Academic Press, An imprint of Elsevier,  |c [2018] 
300 |a 1 online resource :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
504 |a Includes bibliographical references and index. 
588 0 |a Online resource; title from PDF title page (EBSCO, viewed May 25, 2018). 
520 |a Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals�i�A�to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. 
505 0 |6 880-01  |a Front Cover; Advances in Transition-Metal Mediated Heterocyclic Synthesis; Copyright Page; Contents; List of Contributors; Foreword; 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols; 1.1 Introduction; 1.2 Silver-Catalyzed Reactions; 1.3 Gold-Catalyzed Reactions; 1.4 Platinum-Catalyzed Reactions; 1.5 Palladium-Catalyzed Reactions; 1.6 Lanthanum-Catalyzed Reactions; 1.7 Gallium-Catalyzed Reactions; 1.8 Conclusion; References; 2 Intramolecular Diamination of Alkenes; 2.1 Introduction. 
505 8 |a 2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes2.2.1 Palladium Catalysis; 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants; 2.2.3 Copper Catalysis; 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes; 2.3.1 Palladium Catalysis; 2.3.2 Copper Catalysis; 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes; 2.5 Summary and Outlook; References. 
505 8 |a 3.2.2.2 With Halides Together With Nucleophilic Partners3.2.2.3 With Halides Together With Electrophilic Partners; 3.2.2.4 With Halides Together With Alkenes and Imines; 3.2.2.5 With Halides Together With Alkynes and Arynes; 3.2.2.6 With Other Substrates; 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle; 3.3.1 Under Oxidative Conditions; 3.3.1.1 Through Carbonylative Carbocyclization; 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation; 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling. 
505 8 |a 3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition3.3.2 Under Nonoxidative Conditions; 3.3.2.1 With Halides; 3.3.2.2 With Imine Derivatives; 3.3.2.3 With Functionalized Alkynes; 3.4 Conclusions and Perspectives; References; 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions; 4.1 Introduction; 4.2 Cyclization Prior to Metal Carbene Formation; 4.3 Cyclization Through Other Carbene Precursors; 4.4 Cyclization Through Reductive Elimination; 4.5 Cyclization Through Nucleophilic Displacement. 
650 0 |a Heterocyclic compounds. 
650 0 |a Transition metals. 
650 0 |a Transition metal catalysts. 
650 2 |a Heterocyclic Compounds  |0 (DNLM)D006571 
650 6 |a Compos�es h�et�erocycliques.  |0 (CaQQLa)201-0006824 
650 6 |a M�etaux de transition.  |0 (CaQQLa)201-0011368 
650 6 |a Catalyseurs �a base de m�etaux de transition.  |0 (CaQQLa)201-0064129 
650 7 |a SCIENCE  |x Chemistry  |x Organic.  |2 bisacsh 
650 7 |a Heterocyclic compounds  |2 fast  |0 (OCoLC)fst00955736 
650 7 |a Transition metal catalysts  |2 fast  |0 (OCoLC)fst01154758 
650 7 |a Transition metals  |2 fast  |0 (OCoLC)fst01154781 
700 1 |a Sol�e, Daniel,  |e editor. 
700 1 |a Fern�andez, Israel,  |e editor. 
776 0 8 |i Print version:  |t Advances in Transition-Metal Mediated Heterocyclic Synthesis.  |d London : Academic Press, An imprint of Elsevier, [2018]  |z 012811651X  |z 9780128116517  |w (OCoLC)1011519523 
856 4 0 |u https://sciencedirect.uam.elogim.com/science/book/9780128116517  |z Texto completo 
880 8 |6 505-01/(S  |a 3 Synthesis of Heterocycles by Palladium-Catalyzed Carbonylative Reactions3.1 Introduction; 3.2 Palladium-Catalyzed Cyclocarbonylations Leading to Heterocycles; 3.2.1 Under Oxidative Conditions; 3.2.1.1 With Alkyne and Alkene Derivatives (Without Direct C-H Activation); 3.2.1.2 With Acetylenic C-H Activation; 3.2.1.3 With Alkenylic C-H Activation; 3.2.1.4 With Aromatic C-H Activation; 3.2.1.5 With Aliphatic C-H Activation; 3.2.1.6 With Diols, β-Amino Alcohols, Diamines, and Related Compounds; 3.2.2 Under Nonoxidative Conditions; 3.2.2.1 With Functionalized Halides.