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Pincer compounds : chemistry and applications /
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research-from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant met...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam, Netherlands :
Elsevier,
[2018]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Intro; Title page; Table of Contents; Copyright; Dedication; List of Contributors; Preface; Chapter 1. Chiral Pincer Complexes for Asymmetric Reactions; Abstract; 1.1 Introduction; 1.2 Reduction Reactions; 1.3 Borylation Reactions; 1.4 Alkynylation Reactions; 1.5 Reactions with Carbenoids; 1.6 Electrophilic Substitution Reactions; 1.7 Allylation and Propargylation of Carbonyl Compounds; 1.8 Aldol and Mannich Reactions; 1.9 Hydrophosphination and Hydroamination; 1.10 Miscellaneous Reactions; 1.11 Summary; References; Chapter 2. Well-defined Iron and Manganese Pincer Catalysts; Abstract.
- 2.1 Introduction2.2 Hydrido Carbonyl Fe(II) PNP Pincer Complexes; 2.3 Hydrido Carbonyl Mn(I) PNP Pincer Complexes; 2.4 Conclusions and Perspectives; References; Chapter 3. The Pincer Complexes of Group 13-15 Elements: Recent Developments; Abstract; Acknowledgments; 3.1 Introduction; 3.2 Group 13 Complexes; 3.3 Group 14 Complexes; References; Chapter 4. Reduction of CO2 Mediated or Catalyzed by Pincer Complexes; Abstract; Acknowledgment; 4.1 Introduction; 4.2 Third-Row Transition Metal Systems; 4.3 Second-Row Transition Metal Systems; 4.4 First-Row Transition Metal Systems.
- 4.5 Summary and OutlookReferences; Chapter 5. Mechanistic Insights and Computational Prediction of Base Metal Pincer Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions; Abstract; 5.1 Introduction; 5.2 Metal Complexes With Aromatic Pincer Ligands; 5.3 Metal Complexes With Aliphatic Pincer Ligands; 5.4 Bio-Inspired Design of Base Metal Pincer Complexes; 5.5 Conclusions; References; Chapter 6. Hydrogenation and Dehydrogenation Reactions Catalyzed by Iron Pincer Compounds; Abstract; 6.1 Introduction; 6.2 Reversible Catalytic Hydrogenations of Carbonyl Functionalities.
- Chapter 8. Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and ApplicationsAbstract; Acknowledgments; 8.1 Introduction; 8.2 Structural Diversity; 8.3 Preparation of Common Pro-ligands; 8.4 Complexation of CEC Ligands; 8.5 Applications; References; Chapter 9. Transition Metal Pincer Complexes With Chiral Imidazoline Donor(s): Synthesis and Asymmetric Catalysis; Abstract; Acknowledgments; 9.1 Introduction; 9.2 Synthesis of Transition Metal Pincer Complexes With Chiral (Imidazoline) Donor(s); 9.3 Applications to Asymmetric Catalytic Reactions; 9.4 Conclusion; References.