C-furanosides : synthesis and stereochemistry /

Carbon analogs of carbohydrates, dubbed C-glycosides, have remained an important and interesting class of mimetics, be it in natural product synthesis, for pharmacological applications, as conformational probes, or for biological studies. C-Furanosides: Synthesis and Stereochemistry provides a much-...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores principales: Goekjian, Peter (Autor), Hauchy, Arnaud (Autor), Menhour, Boudjema (Autor), Coiffier, Claire (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: London, United Kingdom : Academic Press, an imprint of Elsevier, [2018]
Temas:
Diastereoisomers.
Diast�er�eo-isom�eres.
SCIENCE > Chemistry > Organic.
Diastereoisomers
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Machine generated contents note:
  • pt. A C-Glycosides of Lyxose and Ribose: galacto-, altro- and alio- Configurations
  • A. Introduction
  • References
  • A.1. galacto-C-Furanosides (I, �I²-C-Lyxose)
  • Disconnections
  • Natural Occurrence
  • A.1.1. Disconnection A
  • A.1.2. Disconnection B
  • A.1.3. Disconnection C
  • A.1.4. Disconnection D
  • A.1.5. Miscellaneous
  • A.1.6. Conclusion
  • References
  • A.2. D- and L-altro-C-furanosides (II/ent-II, �I�-C-Lyxose, �I�-C-Ribose)
  • Disconnections
  • Natural Occurrence
  • A.2.1. Disconnection A
  • A.2.2. Disconnection B
  • A.2.3. Disconnection C
  • A.2.4. Disconnection D
  • A.2.5. Disconnection E
  • A.2.6. Miscellaneous
  • A.2.7. Conclusion
  • References
  • A.3. allo-C-Furanosides (VI, �I²-C-Ribose) Disconnections
  • Natural Occurrence
  • A.3.1. Disconnection A
  • A.3.2. Disconnection B
  • A.3.3. Disconnection C
  • A.3.4. Disconnection D
  • A.3.5. Disconnection E
  • A.3.6. Miscellaneous
  • A.3.7. Conclusion
  • References
  • A.4. Lyxose and Ribose C-Glycosides: Other Results and Further Insight Into Stereochemistry
  • A.4.1. Disconnection A
  • A.4.2. Disconnection B
  • A.4.3. Disconnection C
  • A.4.4. Disconnection D
  • A.4.5. Miscellaneous
  • A.4.6. Conclusion
  • References
  • pt. B. C-Glycosides of Arabinose and Xylose: gluco-, ido- and manno- Configurations
  • B. Introduction
  • References
  • B.1. Gluco-C-Furanosides (III/ent-III, �I²-C-Arabinose, �I²-C-Xylose) Disconnections
  • Natural Occurrence
  • B.1.1. Disconnection A
  • B.1.2. Disconnection B
  • B.1.3. Disconnection C
  • B.1.4. Disconnection D
  • B.1.5. Miscellaneous
  • B.1.6. Conclusion
  • References
  • B.2. ido-C-Furanosides (V/ent-V, �I�-C-Xylose) Disconnections
  • Natural Occurrences
  • B.2.1. Disconnection A
  • B.2.2. Disconnection B
  • B.2.3. Disconnection C
  • B.2.4. Disconnection D
  • B.2.5. Miscellaneous
  • B.2.6. Conclusion
  • References
  • B.3. manno-C-Furanosides (VII/ent-VII, �I�-C-Arabinose) Disconnections
  • Natural Occurrence
  • B.3.1. Disconnection A
  • B.3.2. Disconnection B
  • B.3.3. Disconnection C
  • B.3.4. Disconnection D
  • B.3.5. Conclusion
  • References
  • B.4. Arabinose and Xylose C-Furanosides: Other Results and Further Insight Into Stereochemistry Disconnections
  • B.4.1. Disconnection A
  • B.4.2. Disconnection B
  • B.4.3. Disconnection C
  • B.4.4. Equilibration Processes
  • B.4.5. Miscellaneous
  • B.4.6. Conclusion
  • References
  • pt. C. Applications of C-Furanosides Introduction
  • C.1. Preparation of C-Furanosides
  • C.2. Agro-Industry and Farming
  • C.3. Ligands for Asymmetric Catalysis
  • C.4. Perfumes, Aromas, and Cosmetics
  • C.5. Imaging and Diagnostics
  • C.6. Pharmaceutical Industry
  • C.7. Polymers
  • References
  • pt. D. 1H NMR Vicinal Coupling Constants of C-Furanosides
  • Introduction
  • D.1. 1H NMR Data in galacto-C-Furanosides (I, �I²-C-Lyxose), Corresponding to Chapter A.1
  • D.2. 1H NMR Data in D- and L-altro-C-Furanosides (II/ent-II, �I�-C-Lyxose, �I�-C-Ribose), Corresponding to Chapter A.2
  • D.3. Comparison Between 1H NMR Data in galacto-C- Furanosides (I, �I²-C-Lyxose), Corresponding to Chapter A.1, and in D- and L-altro-C-Furanosides (II/ent-II, �I�-C-Lyxose, �I�-C-Ribose), Corresponding to Chapter A.2
  • D.4. 1H NMR Data in allo-C-Furanosides (VI, �I²-C-Ribose), Corresponding to Chapter A.3
  • D.5. Comparison Between 1H NMR Data in D- and L-altro- C-Furanosides (II/ent-II, �I�-C-Lyxose, �I�-C-Ribose), Corresponding to Chapter A.2, and in allo-C-Furanosides (VI, �I²-C-Ribose), Corresponding to Chapter A.3
  • D.6. 1H NMR Data in D- and L-gluco-C-Furanosides (III/ent-III, �I²-C-Arabinose, �I²-C-Xylose), Corresponding to Chapter B.1
  • D.7. 1H NMR Data in D- and L-ido-C-Furanosides (V/ent-V, �I�-C-D-Xylose, �I�-C-L-Xylose), Corresponding to Chapter B.2
  • D.8. Comparison Between 1H NMR Data in D- and L-gluco- C-Furanosides (III/ent-III, �I²-C-Arabinose, �I²-C-Xylose), Corresponding to Chapter B.1, and in D- and L-ido-C-Furanosides (V/ent-V, �I�-C-D-Xylose, �I�-C-L-Xylose), Corresponding to Chapter B.2
  • D.9. 1H NMR Data in D- and L-manno-C-Furanosides (VII/ent-VII, �I�-C-Arabinose), Corresponding to Chapter B.3
  • D.10. Comparison Between 1H NMR Data in galacto-C- Furanosides (I, �I²-C-Lyxose), Corresponding to Chapter A.1, and in D- and L-gluco-C-Furanosides (III/ent-III, �I²-C-Arabinose, �I²-C-Xylose), Corresponding to Chapter B.1
  • D.11. Comparison Between 1H NMR Data in D- and L-altro- C-Furanosides (II/ent-II, �I�-C-Lyxose, �I�-C-Ribose), Corresponding to Chapter A.2, and in D- and L-ido- C-Furanosides (V/ent-V, �I�-C-D-Xylose, �I�-C-L-Xylose), Corresponding to Chapter B.2
  • D.12. Conclusion and Summary of Expected Coupling Constants
  • References.

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