Reactivity of P-H group of phosphorus based compounds /

Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Troev, Kolio D. (Kolio Dimov), 1944- (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: London, United Kingdom : Academic Press, [2018]
Temas:
Phosphorus compounds.
Phosphorus Compounds
Phosphore > Compos�es.
SCIENCE > Chemistry > Inorganic.
Phosphorus compounds
Acceso en línea:Texto completo

MARC

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100 1 |a Troev, Kolio D.  |q (Kolio Dimov),  |d 1944-  |e author. 
245 1 0 |a Reactivity of P-H group of phosphorus based compounds /  |c Kolio D. Troev. 
264 1 |a London, United Kingdom :  |b Academic Press,  |c [2018] 
300 |a 1 online resource (xii, 451 pages) 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
588 0 |a Vendor-supplied metadata. 
504 |a Includes bibliographical references and index. 
505 0 |a Front Cover; Reactivity of P-H Group of Phosphorus Based Compounds; Copyright Page; Contents; About the Author; Preface; 1 Acidity and Tautomerization of P-H Group; 1.1 Acidity; 1.2 Tautomerization; 1.2.1 Tautomerization of Phosphine Oxides; 1.2.2 Tautomerization of Hypophosphorous Acid; 1.2.3 Tautomerization of H-Phosphinic Acid; 1.2.4 Tautomerization of H-Phosphonic Acid; References; 2 Reactivity of P-H Group of Phosphines; 2.1 Phosphine; 2.1.1 Methods for Preparation; 2.1.2 Reactivity of P-H Group; 2.1.2.1 Reaction with Metals; 2.1.2.2 Addition Reactions 
505 8 |a 2.1.2.2.1 Addition to Carbon-Carbon Multiple BondsRadical Addition; Nucleophilic Addition; Catalyzed Hydrophosphination; 2.1.2.2.2 Addition to Carbonyl Group; 2.1.2.3 Nucleophilic Substitution Reactions; 2.2 Primary Phosphines (RPH2); 2.2.1 Methods for Preparation; 2.2.2 Reactivity of P-H Group; 2.2.2.1 Addition Reactions; 2.2.2.1.1 Addition to Carbon-Carbon Multiple Bonds; 2.2.2.1.2 Addition to Carbonyl Group; 2.2.2.2 Cross-Coupling Reactions; 2.2.2.3 Cross-Dehydrogenative Coupling; 2.3 Primary Diphosphines; 2.3.1 Methods for Preparation; 2.3.2 Reactivity of P-H Group; 2.3.2.1 Metalation 
505 8 |a 2.3.2.2 Cross-Dehydrogenative Coupling2.3.2.3 Addition Reactions; 2.3.2.3.1 Addition to Carbonyl Group; 2.3.2.3.2 Addition to Carbon-Carbon Multiple Bonds; 2.4 Secondary Phosphines R2PH; 2.4.1 Methods for Preparation; 2.4.2 Reactivity of P-H Group; 2.4.2.1 Oxidation; 2.4.2.2 Addition Reactions; 2.4.2.2.1 Addition to Carbon-Carbon Multiple Bonds; Radical Activation; Pincer Complexes; 2.4.2.2.2 Addition to Carbonyl Group; 2.4.2.3 Substitution Reactions; 2.4.2.4 Cross-Coupling Reactions; 2.4.2.5 Cross-Dehydrogenative Coupling; 2.5 Secondary Diphosphines-RPH-R2-PRH; 2.5.1 Methods for Preparation 
505 8 |a 2.5.2 Reactivity of P-H Group2.5.2.1 Condensation Reactions; 2.5.2.2 Cross-Coupling Reactions; 2.5.2.2.1 Diphenyldiphosphine PhHP-PHPh; 2.5.2.2.2 Tetraphenyldiphosphane; 2.6 Phosphine-Borane Complexes; 2.6.1 Phosphine-Borane; 2.6.1.1 Methods for Preparation; 2.6.2 Primary Phosphine-Boranes; 2.6.2.1 Methods for Preparation; 2.6.2.2 Reactivity of P-H Group; 2.6.2.2.1 Hydrophosphination; 2.6.2.2.2 Oxidative Addition; 2.6.2.2.3 Cross-Dehydrogenative Coupling; 2.6.2.2.4 Alkylation; 2.6.3 Secondary Phosphine-Boranes; 2.6.3.1 Methods for Preparation; 2.6.3.2 Reactivity of P-H Group 
505 8 |a 2.6.3.2.1 Alkylation2.6.3.2.2 Hydrophosphination; 2.6.3.2.3 Nucleophilic Substitutions; 2.6.3.2.4 Cross-Coupling Reactions; 2.6.3.2.5 Cross-Dehydrogenative Coupling; Poly(phosphinoborane)s; 2.7 Conclusion; References; 3 Reactivity of P-H Group of Phosphine Oxides; 3.1 Phosphine Oxide; 3.1.1 Methods for Preparation; 3.1.2 Reactivity of P-H Group; 3.2 Primary Phosphine Oxides; 3.2.1 Methods for Preparation; 3.2.2 Reactivity of P-H Group; 3.2.2.1 Dehydration; 3.2.2.2 Addition Reactions; 3.2.2.2.1 Addition to Carbon-Carbon Multiple Bonds; 3.3 Secondary Phosphine Oxides 
520 |a Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. 
650 0 |a Phosphorus compounds. 
650 2 |a Phosphorus Compounds  |0 (DNLM)D017553 
650 6 |a Phosphore  |x Compos�es.  |0 (CaQQLa)201-0011216 
650 7 |a SCIENCE  |x Chemistry  |x Inorganic.  |2 bisacsh 
650 7 |a Phosphorus compounds  |2 fast  |0 (OCoLC)fst01061466 
856 4 0 |u https://sciencedirect.uam.elogim.com/science/book/9780128138342  |z Texto completo 

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