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170623s2017 enka ob 001 0 eng d |
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|a 991645425
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|a (OCoLC)990802679
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|z (OCoLC)1118403108
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|a SCI
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|a 572.6
|2 23
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|a Inorganic Reaction Mechanisms /
|c edited by Rudi van Eldik, Colin D. Hubbard.
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|a First edition.
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|a London :
|b Academic Press, an imprint of Elsevier,
|c 2017.
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|a 1 online resource (xiv, 436 pages :
|b illustrations (some color))
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
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|a Advances in inorganic chemistry ;
|v volume 70
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|a Text in English.
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|a Includes bibliographical references and index.
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|a Online resource; title from PDF title page (EBSCO, viewed June 26, 2017).
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|a Inorganic Reaction Mechanisms, Volume 70, is the latest volume from the Advances in Inorganic Chemistry series, which presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced.
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|a Title page; Table of Contents; Copyright; Dedication; Ralph G. Wilkins; Contributors; Preface; Chapter One: The Kinetics and Mechanism of Complex Redox Reactions in Aqueous Solution: The Tools of the Trade; Abstract; 1 Introduction; 2 General Considerations; 3 Selected Reactions of Oxychlorine Species; 4 Kinetics of the Oxidation Reactions of Peroxo Compounds; 5 The Photon as a Reactant; 6 Selected Kinetic Studies on Heterogeneous Systems; 7 Concluding remarks; Acknowledgments; Chapter Two: O-O Bond Activation in Cu- and Fe-Based Coordination Complexes: Breaking It Makes the Difference
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|a Chapter Four: The Role of Nonheme Transition Metal-Oxo, -Peroxo, and -Superoxo Intermediates in Enzyme Catalysis and Reactions of Bioinspired ComplexesAbstract; 1 Introduction; 2 Metal-(Di)oxygen Intermediates; 3 Conclusions; Acknowledgments; Chapter Five: Diarylplatinum(II) Scaffolds for Kinetic and Mechanistic Studies on the Formation of Platinacycles via an Oxidative Addition/Reductive Elimination/Oxidative Addition Sequence; Abstract; 1 Introduction; 2 Compounds; 3 Kinetic Studies; 4 Synergy With DFT Calculations; 5 Concluding Remarks; Acknowledgments
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|a 3 Thionitrous Acid HSNO and Thionitrite SNO<U+0012>, Elusive Aqueous Intermediates4 Polysulfides and Sulfur Sols; 5 Perthionitrite, S2NO<U+0012>. Identification of Iyellow; 6 Coordination Chemistry of Nitrosothiols, Thionitrous Acid, Thionitrite, and Perthionitrite; 7 Conclusions; Acknowledgments; Chapter Eight: Computational Insights Into the Reactivity at the Sulfur Atoms of M3S4 (M=Mo, W) Clusters: The Mechanism of [3+2] Cycloaddition With Alkynes; Abstract; 1 Introduction: The Reactivity of M3S4 (M=Mo, W) Clusters; 2 Experimental and Computational Methods
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|a Legal Deposit;
|c Only available on premises controlled by the deposit library and to one user at any one time;
|e The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
|5 WlAbNL
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540 |
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|a Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.
|5 WlAbNL
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650 |
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|a Chemistry, Inorganic.
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650 |
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2 |
|a Chemistry, Inorganic
|0 (DNLM)D015392
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650 |
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|a Chimie inorganique.
|0 (CaQQLa)201-0031942
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650 |
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|a inorganic chemistry.
|2 aat
|0 (CStmoGRI)aat300054540
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|a SCIENCE
|x Life Sciences
|x Biochemistry.
|2 bisacsh
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650 |
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|a Chemistry, Inorganic
|2 fast
|0 (OCoLC)fst00853488
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700 |
1 |
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|a Eldik, Rudi van,
|e editor.
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700 |
1 |
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|a Hubbard, Colin D.,
|e editor.
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773 |
0 |
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|t Advances in inorganic chemistry.
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773 |
0 |
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|t Elsevier.
|
776 |
0 |
8 |
|i Print version:
|t Inorganic Reaction Mechanisms.
|b First edition.
|d London : Academic Press, an imprint of Elsevier, 2017
|z 0128128348
|z 9780128128343
|w (OCoLC)966556125
|
830 |
|
0 |
|a Advances in inorganic chemistry ;
|v v. 70.
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856 |
4 |
0 |
|u https://sciencedirect.uam.elogim.com/science/bookseries/08988838/70
|z Texto completo
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880 |
8 |
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|6 505-00/(S
|a Chapter Six: Controlling the Lability of Square-Planar Pt(II) Complexes Through Electronic and π-Conjugation: Correlation Between Kinetics and Theoretical ParametersAbstract; 1 Introduction; 2 Pull-and-Push Effects of Pt(II) Complexes With Coordinated N�C/N�N/C π-Acceptor Nonleaving Ligands; 3 Conclusions; Acknowledgments; Chapter Seven: Thionitrous Acid/Thionitrite and Perthionitrite Intermediates in the "Crosstalk" of NO and H2S; Abstract; 1 Introduction; 2 S-Nitrosothiols, RSNOs, a Brief Overview on Structure and Reactivity
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|6 505-00/(S
|a Abstract1 Introduction; 2 Modeling Tyrosinase: O-O Cleavage in Dinuclear Copper Systems; 3 O-O Cleavage in Iron-Oxygen Species; 4 Summary; Chapter Three: μ-Nitrido Diiron Phthalocyanine and Porphyrin Complexes: Unusual Structures With Interesting Catalytic Properties; Abstract; 1 Introduction; 2 Preparation and Spectroscopic Characterization of μ-Nitrido Diiron Macrocyclic Complexes; 3 High-Valent Diiron-Oxo Species and Their Spectroscopic Characterization; 4 Catalytic Properties; 5 Conclusion and Outlook; Acknowledgments
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