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Binary Polar Liquids : Structural and Dynamic Characterization Using Spectroscopic Methods.
Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods provides liquid state physical chemists and physicists with practical theoretical models based on a wealth of robust data that describe the dielectric properties of dipolar materials in a systematic manner. In...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
San Diego :
Elsevier Science,
2017.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Binary Polar Liquids; Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods; Copyright; Contents; Preface; 1
- Theoretical and Experimental Aspects of Time Domain Permittivity Spectroscopy; 1.1 INTRODUCTION; 1.1.1 Polar; 1.1.2 Nonpolar; 1.1.3 Dipole Moment; 1.2 POLARIZATION; 1.2.1 Polarization Mechanisms; 1.2.2 Electronic Polarization; 1.2.3 Atomic Polarization; 1.2.4 Orientation Polarization; 1.2.5 Interfacial Polarization; 1.3 DIELECTRIC THEORIES; 1.3.1 Theories of Static Permittivity; 1.3.2 The Debye Theory of Static Permittivity.
- 1.3.3 The Onsager Dielectric Theory1.3.4 The Kirkwood Theory; 1.3.5 The Frohlich Theory; 1.4 DYNAMICAL THEORY OF DIELECTRICS; 1.4.1 The Debye Model; 1.4.2 The Cole-Cole Model; 1.4.3 The Cole-Davidson Model; 1.4.4 The Havriliak-Negami Model; 1.4.5 The Double-Debye (Two-Debye) Model; 1.5 DIELECTRIC MODELS RELATED TO MOLECULAR BEHAVIOR; 1.5.1 Kirkwood Correlation Factor; 1.5.2 Kirkwood Correlation Factor in Binary Mixture; 1.5.3 Excess Dielectric Constant; 1.5.4 The Modified Bruggeman Model; 1.5.5 The Redlich-Kister Model23; 1.6 THERMODYNAMIC PARAMETERS; 1.7 EXPERIMENTAL TECHNIQUE.
- 1.7.1 Dielectric Relaxation Spectroscopy1.7.2 Basic Principle of TDR; 1.7.3 Sampling Oscilloscope; 1.7.4 Sample Cell; 1.7.5 Choice of Time Window; 1.8 DATA ANALYSIS; 1.8.1 Bilinear Calibration Method; 1.8.2 An Example: Determination of Relaxation Time and Distribution Parameters; 1.9 CONCLUSION; References; 2
- Dielectric Relaxation in Binary Polar Liquids Containing Alcohols and Molecules With -OH Group; 2.1 INTRODUCTION; 2.2 WATER-METHANOL BINARY SYSTEM; 2.3 THE WATER-ETHANOL SYSTEM; 2.4 THE WATER-PROPANOL SYSTEM; 2.5 THE WATER-ETHYLENE GLYCOL SYSTEM.
- 2.6 THE WATER-TERTIARY BUTYL ALCOHOL SYSTEM2.7 THE ETHANOL-ETHYLENE GLYCOL SYSTEM; 2.8 OTHER SIMILAR SYSTEM; 2.9 CONCLUSION; References; 3
- Spectroscopic Characterization of Binary Polar Liquid Mixtures Containing Amino or Sulfoxide Group and Hydroxyl ... ; 3.1 INTRODUCTION; 3.2 N, N-DIMETHYLAMINOETHANOL-FORMAMIDE BINARY SYSTEM; 3.3 WATER-FORMAMIDE BINARY SYSTEM; 3.4 WATER-N-METHYLFORMAMIDE BINARY SYSTEM; 3.5 WATER-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM; 3.6 2-ETHOXYETHANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM; 3.7 ETHANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM.
- 3.8 PROPANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM3.9 ETHANOLAMINE-N, N-DIMETHYLACETAMIDE BINARY SYSTEM; 3.10 WATER-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.11 ETHANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.12 PROPANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.13 2-ETHOXYETHANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.14 ANILINE-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.15 ANILINE-METHANOL BINARY SYSTEM; 3.16 ANILINE-ETHANOL BINARY SYSTEM; 3.17 ANILINE-PROPANOL BINARY SYSTEM; 3.18 ANILINE-BUTANOL BINARY SYSTEM; 3.19 ANILINE-HEXANOL BINARY SYSTEM; 3.20 ANILINE-HEPTANOL BINARY SYSTEM.