Strategies for palladium-catalyzed non-directed and directed C-H bond functionalization /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Kapdi, Anant R., Maiti, Debabrata
Formato: Electrónico eBook
Idioma:Inglés
Publicado: [Place of publication not identified] : Elsevier, 2017.
Colección:Latest trends in palladium chemistry.
Temas:
Organometallic chemistry.
Chemical bonds.
Catalysis.
Activation (Chemistry)
Carbon.
Hydrogen.
Catalysis
Carbon
Hydrogen
Chimie organom�etallique.
Catalyse.
Activation (Chimie)
Carbone.
Hydrog�ene.
SCIENCE / Chemistry / Organic.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Machine generated contents note: 1. Introduction / Debabrata Maiti
  • 2. Directed C
  • H Bond Functionalization Strategies for Synthesis / Anant R. Kapdi
  • 2.1. Introduction
  • 2.2. Ortho-Palladated C
  • H Bond Functionalization via Directing Group Effect
  • 2.3. Conclusion
  • References
  • 3. Nondirected C
  • H Bond Functionalizations of (Hetero)arenes / Fuk-Yee Kwong
  • 3.1. Introduction
  • 3.2. Reactions With Halides
  • 3.3. Reactions With Pseudohalides
  • 3.4. Conclusion
  • References
  • 4. Palladium-Catalyzed Directed Arylation of Unactivated C(sp3)
  • H Bonds / Bing-Feng Shi
  • 4.1. Introduction
  • 4.2. Palladium-Catalyzed C(sp3)
  • H Arylation Directed by Monodentate DGs
  • 4.3. Palladium-Catalyzed C(sp3)
  • H Arylation Directed by Bidentate DGs
  • 4.4. Palladium-Catalyzed C(sp3)
  • H Arylation Using Transient DGs
  • 4.5. Palladium-Catalyzed Asymmetric C(sp3)
  • H Arylation
  • 4.6. Conclusions and Outlook
  • References
  • 5. C
  • H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3) / Martin Oestreich
  • 5.1. Palladium-Catalyzed C
  • H Bond Functionalization of Indole
  • 5.2. Palladium-Catalyzed C
  • H Bond Functionalization of Indolines
  • 5.3. Conclusions
  • List of Abbreviations
  • References
  • 6. Palladium-Catalyzed Carbonylative and Carboxylative C
  • H Functionalization Reactions: Importance and Role of Regioselectivity / Bhalchandra M. Bhanage
  • 6.1. Introduction
  • 6.2. Carbonylative C
  • H Functionalization of Arenes in the Presence of Directing Group
  • 6.3. Carbonylative C(sp2)
  • H Functionalization of Heteroarenes
  • 6.4. Carboxylative C
  • H Bond Functionalization
  • 6.5. Conclusion and Future Outlook
  • References
  • 7. Flow Chemistry Perspective for C
  • H Bond Functionalization / Timothy Noel
  • 7.1. Introduction
  • 7.2. Advantages of Using Continuous-Flow Microreactor Technology for C
  • H Activation
  • 7.3. Cross-Dehydrogenative Coupling in Continuous Flow
  • 7.4. Rh-Catalyzed C
  • H Activation Reactions in Continuous Flow
  • 7.5. Palladium-Catalyzed C(sp3)
  • H Activation Reactions in Continuous Flow
  • 7.6. Ru-Catalyzed C
  • H Activation Reactions in Continuous Flow
  • 7.7. Intramolecular C
  • H Activation Reactions in Continuous Flow
  • 7.8. Ortho-Directed Hydrogen/Deuterium Isotope Exchange via Iridium-Catalyzed C
  • H Activation
  • 7.9. Conclusion
  • References
  • 8. Directed Meta-Selective C
  • H Bond Functionalizations / Gang Li
  • 8.1. Introduction
  • 8.2. Directing Group Assisted Meta-C
  • H Functionalization
  • 8.3. Ortho-Directing Group-Assisted and Norbornene-Mediated Meta-C
  • H Functionalization
  • 8.4. Formal Meta-C
  • H Functionalization Using a Traceless Directing Group
  • 8.5. Conclusion
  • Abbreviations
  • References
  • 9. Recent Advances in Distal Aliphatic sp3 C
  • H Functionalization / Debabrata Maiti
  • 9.1. Introduction
  • 9.2. Scope of Functionalization
  • 9.4. Conclusion
  • References
  • 10. Palladacycles for Directed and Nondirected C
  • H Bond Functionalization of (Hetero)arenes / Benudhar Punji
  • 10.1. Introduction
  • 10.2. Palladacycle PreCatalyst in C
  • H Functionalization
  • 10.3. Palladacycle Intermediate in C
  • H Functionalization
  • 10.4. Conclusion
  • Abbreviations
  • References
  • 11. Mechanistic/Organometallic Aspects of Palladium-Catalyzed C
  • H Bond Functionalization / Anant R. Kapdi
  • 11.1. Introduction
  • 11.2. Early Findings
  • 11.3. Palladium-Catalyzed C
  • H Activation Pathways
  • 11.4. Conclusion
  • Acknowledgments
  • List of Abbreviations
  • References
  • 12. Recent Developments in Palladium-Catalyzed Natural Product Synthesis via C
  • H Activation / Chandra M.R. Volla
  • 12.1. Introduction
  • 12.2. Total Synthesis of Aspidospermidine
  • 12.3. Total Synthesis of (+) -Lithospermic Acid
  • 12.4. Total Synthesis of Pipercyclobutanamide A
  • 12.5. Total Synthesis of Piperarborenine B and D
  • 12.6. Total Synthesis of Podophyllatoxin
  • 12.7. Total Synthesis of Clavicipitic Acid
  • 12.8. Total Synthesis of Hibispeptin A
  • 12.9. Divergent Synthesis of Aeruginosins (sp3 C
  • H Alkenylation and Arylation)
  • 12.10. Total Synthesis of (+) Linoxepin
  • 12.11. Rapid Total Synthesis of Rhazinal
  • 12.12. Total Synthesis of Gamendazole
  • 12.13. Total Synthesis of (+/- ) Rhazinilam
  • 12.14. Conclusion
  • References.

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