Cargando…
Advanced and emerging polybenzoxazine science and technology /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam, Netherlands :
Elsevier,
2017.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Advanced and Emerging Polybenzoxazine Science and Technology ; Copyright; Dedication; Contents; Contributors; Preface; Part I: Synthesis and Properties of Benzoxazine Resins; Chapter 1: Various Synthetic Methods of Benzoxazine Monomers; 1. Introduction; 2. Various Synthetic Methods Used for Benzoxazine Synthesis; 2.1. Mannich-Condensation Based Benzoxazine Synthesis; 2.1.1. One-pot Benzoxazine Synthesis; 2.1.2. Benzoxazine Synthesis via Ortho-Hydroxybenzylamine Structure; 2.1.3. Polycyclic Benzoxazine Synthesis via N, O-Acetal Forming Reaction.
- 2.2. Benzoxazine Synthesis via Cycloaddition 2.3. Other Reactions for Benzoxazine Synthesis; 2.4. Benzoxazine Synthesis With Alternative Energy Sources; 2.5. Synthesis of Naphthoxazine, Benzoxazine Analogue; 3. Conclusion; References; Chapter 2: Catalytic Accelerated Polymerization of Benzoxazines and Their Mechanistic Considerations; 1. Introduction; 2. Benzoxazine Polymerization Mechanism Consideration; 3. Catalysts for Accelerated Benzoxazine Polymerization; 3.1. Acidic Catalysts; 3.2. Basic Catalysts; 4. Catalyst Effects on Polymerization Mechanism and Network Structures.
- 4.1. Pure Benzoxazines4.2. Benzoxazine-Epoxy Blends; 5. Conclusion; References; Chapter 3: Molecular Designs of Benzoxazines With Enhanced Reactivity Based on Utilization of Neighboring-Group Participa ... ; 1. Introduction; 2. Benzoxazines Activated by Neighboring-Group Participation; 2.1. Neighboring-Group Participation of Polar Substituents; 2.1.1. Neighboring-Group Participation of a Hydroxyl Group; 2.1.2. Neighboring-Group Participation of a Carboxylate Group; 2.2. Neighboring-Group Participation of an Allyl Group; 3. Benzoxazines Activated by a Thioether Group; 4. Conclusion.
- 5. Experimental5.1. Materials; 5.2. Analyses; 5.3. Synthesis of Benzoxazines; 5.3.1. C-he (Benzoxazine Bearing a Hydroxyl Group); 5.3.2. C-tbagl (Benzoxazine Bearing a Carboxylate Group); 5.3.3. DHPDS-a (Bifunctional Benzoxazine Bearing a Disulfide Linkage); 5.3.4. PHPTP-a; 5.3.5. ECE-SP-a; References; Chapter 4: Development of New Generation Benzoxazine Thermosets Based on Smart Ortho-Benzoxazine Chemistry; 1. Introduction; 2. Anomalous Isomeric Effects on the Properties of Bisphenol F-Based Benzoxazines; 3. Benzoxazole Resin: A Novel Class of Thermoset via Smart Ortho-Benzoxazine Chemistry.
- 3.1. Benzoxazole Resin via Ortho-Amide Functional Benzoxazine3.2. Benzoxazole Resin via Ortho-Imide Functional Benzoxazine; 3.3. Benzoxazole Resin via Ortho-(Amide-Imide) Functional Benzoxazine; 4. An Ultrahigh Performance Crosslinked PBO via Thermal Conversion From Main-Chain Type Poly(Benzoxazine Amic Acid); 5. Thermally Stable Polybenzoxazine via Ortho-Norbornene Functional Benzoxazine Monomers; 6. Molecular Understanding of the Unexpected Properties of Ortho-Functional Benzoxazine Resins; 6.1. Benzoxazine Chemistry at the Molecular Level; 6.2. Model Compounds.