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Carboranes /
Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Academic Press,
[2016]
|
| Edición: | Third edition. |
| Colección: | Organometallic chemistry.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Carboranes; Copyright; Dedication; Contents; Preface to the Third Edition; Preface to the Second Edition; Chapter 1: Introduction and History; References; Chapter 2: Structure and Bonding; 2.1. General perspective; 2.2. Nomenclature and numbering; 2.3. The localized-bond approach; 2.4. Structural patterns in boron clusters; 2.5. Extensions of the electron-counting rules; 2.6. Electron-counting in classically bonded clusters; 2.7. Isomer stability and cage rearrangement; 2.8. Cluster aromaticity; 2.9. ``Electron Deficiency�� in Polyhedral Boron Clusters; References.
- Chapter 3: Synthesis and Reactivity: An Overview3.1. General preparative routes to carboranes; 3.1.1. Borane-Alkyne Gas Phase Reactions; 3.1.2. Borane-Alkyne Reactions in Solution; 3.1.3. Carborane-Alkyne Reactions; 3.1.4. Carbon Insertion Via Cyano- and Isocyanoboranes; 3.1.5. Carboranes from Organoboranes; 3.2. Interconversion reactions; 3.2.1. Polyhedral Rearrangement; 3.2.2. Metal-Promoted Cage Fusion; 3.2.3. Polyhedral Expansion and Contraction; 3.3. Substitution at cage carbon and boron atoms; 3.4. Carboranes as substituents and ligands.
- Chapter 4: Small Carboranes: Four- to Six-Vertex Clusters4.1. Overview; 4.2. 4-Vertex open clusters; 4.2.1. CB3Hx and C2B2Hx; 4.3. 5-Vertex open clusters; 4.3.1. Nido- and Arachno-CB4 Systems; 4.3.2. Nido-1,2-C2B3H7; 4.3.3. Other Open-Cage C2B3 Clusters; 4.3.4. Nido-C3B2 Clusters; 4.4. 5-Vertex closo clusters; 4.4.1. CB4Hx; 4.4.2. 1,5-C2B3H5; 4.4.2.1. Synthesis; 4.4.2.2. Structure and Bonding; 4.4.2.3. Physical Properties and Reactivity; 4.4.3. Closo-C3B2H5+; 4.5. 6-Vertex open clusters; 4.5.1. Nido-2-CB5H9; 4.5.1.1. Synthesis; 4.5.1.2. Structure and Properties; 4.5.2. Hypho-CB5H13.
- 4.5.3. Nido-2,3-C2B4H84.5.3.1. Synthesis; 4.5.3.2. Structure and Properties; 4.5.4. Nido-2,4-C2B4H8; 4.5.4.1. Synthesis; 4.5.4.2. Structure and Properties; 4.5.5. Arachno- and Hypho-C2B4Hx Clusters; 4.5.6. Nido-2,3,4-C3B3H7; 4.5.6.1. Synthesis; 4.5.6.2. Structure and Properties; 4.5.7. Nido-2,3,5-C3B3H7; 4.5.7.1. Synthesis; 4.5.7.2. Structure and Properties; 4.5.8. Nido-2,3,4,5-C4B2H6; 4.5.8.1. Synthesis; 4.5.8.2. Structure and Properties; 4.5.9. Nido-2,3,4,5,6-C5BH6+; 4.5.9.1. Synthesis; 4.5.9.2. Structure and Properties; 4.6. 6-Vertex closo clusters; 4.6.1. 1-CB5H7 and 1-CB5H6-
- 4.6.1.1. Synthesis4.6.1.2. Structure and Properties; 4.6.2. 1,2- and 1,6-C2B4H6; 4.6.2.1. Synthesis; 4.6.2.2. Structure and Physical Properties; 4.6.2.3. Reactions of Closo-1,2-C2B4 Clusters; 4.6.2.4. Reactions of Closo-1,6-C2B4 Clusters: Hydrolysis, Methanolysis, and Oxidation; 4.6.2.5. Polyhedral Expansion; 4.6.2.6. Cage Linkage; 4.6.2.7. Introduction of Substituents; References; Chapter 5: Intermediate Carboranes: Seven- to Nine-Vertex Clusters; 5.1. Overview; 5.2. 7-Vertex open clusters; 5.2.1. Nido-C2B5H8-; 5.3. 7-Vertex closo clusters; 5.3.1. 2-CB6H7-; 5.3.2. 2,3-C2B5H7.