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Zeolites and zeolite-like materials /
Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam :
Elsevier,
�2016.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Zeolites and Zeolite-like Materials; Copyright; Contents; Contributors; Preface; Chapter 1: Toward Greener and Designed Synthesis of Zeolite Materials; 1 Introduction; 2 Green Synthesis; 2.1 Synthesis for Reduced Cost and Environmental Impact; 2.1.1 Organic-template-free synthesis; 2.1.1.1 Metal-cation-directed synthesis; 2.1.1.2 Seed-assisted synthesis; 2.1.2 Solvent-free synthesis; 2.1.3 Cheap or low-toxic organic-template-directed synthesis; 2.2 Synthesis for Waste Reused; 2.2.1 Organic-template-reused synthesis; 2.2.2 Mother-liquor-reused synthesis.
- 2.3 Synthesis for Energy Efficiency: Microwave-Assisted Synthesis2.4 Synthesis for Process Safety: Ionothermal Synthesis; 3 Designed Synthesis; 3.1 Designing Novel SDAs; 3.1.1 SDA design for novel zeolite structures; 3.1.2 SDA design for hierarchical zeolites; 3.2 Charge Density Mismatch; 3.3 Heteroatom Substitution; 3.3.1 Heteroatom substitution with trivalent and divalent metal ions; 3.3.2 Heteroatom substitution with Ge atom to direct D4R; 3.4 Topotactic Conversion of Framework; 3.4.1 Topotactic condensation of layered structures (2D-3D); 3.4.2 Topotactic conversion of a 3D framework.
- 4 ConclusionReferences; Chapter 2: Metal-Organic Frameworks and Related Materials: Miles to Go; 1 Introduction; 1.1 Synthesis of Carboxylate MOFs; 2 MOFs as Selective Heterogeneous Catalysts; 3 The Nature of Catalitically Active Sites in MOFs; 3.1 Catalysis on Open Catalytically Active Sites; 3.2 Catalysis on Formally Saturated Catalytically Active Sites; 3.3 Catalysis on Framework Defects; 4 Design of Catalysts Based on MOFs; 4.1 MOF as a Support for Heterogeneous Catalysts; 4.2 Bridging Ligand as an Active Site; 4.2.1 Metal-containing ligands; 4.2.2 Catalysis by metal-free organic ligands.
- 4.3 Inorganic Node as an Active Site4.4 Introduction of Guest Molecules Containing Catalytically Active Sites; 4.5 Active Sites Introduced by the Postsynthetic Modification of the Framework; 5 Catalysis in the Presence of Chiral MOFs; 6 Other Types of Catalytic Processes on MOFs; 7 Adsorption on MOFs; 7.1 Hydrogen Storage; 7.1.1 Physical sorption of hydrogen; 7.1.2 H2 storage in zeolites; 7.1.3 H2 storage in MOFs; 7.1.4 Specific surface area; 7.1.5 Pore shape and size; 7.1.6 MOFs with catenane structures; 7.1.7 Chemistry of organic linkers; 7.1.8 Flexibility of organic linkers.
- 7.1.9 Presence of coordinatively unsaturated (open) metal centers7.1.10 Hydrogen spillover; 7.1.11 Adsorption and storage of other molecules; 8 MOFs as Sensor Materials; 9 Other Potential Applications; 10 Conclusions; Acknowledgment; References; Chapter 3: Computational Chemistry of Zeolite Catalysis; 1 Introduction; 2 Methodology; 2.1 The Concept of the Potential Energy Surface; 2.2 The Many-Body Problem and Born-Oppenheimer Approximation; 2.3 Ab Initio Methods; 2.4 Density Functional Theory; 2.5 Basis Sets; 2.6 Models; 3 Reactions in Confined Space: The Role of Dispersion Interactions.