Organic nanoreactors : from molecular to supramolecular organic compounds /
Organic Nanoreactors: From Molecular to Supramolecular Organic Compounds provides a unique overview of synthetic, porous organic compounds containing a cavity which can encapsulate one or more guest(s). Confined space within a nanoreactor can isolate the guest(s) from the bulk and effectively influe...
Clasificación: | Libro Electrónico |
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Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
London :
Academic Press, an imprint of Elsevier,
[2016]
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover
- Title Page
- Copyright Page
- Contents
- List of Contributors
- Chapter 1
- Introduction to Nanoreactors
- 1
- Approaches to artificial enzymes
- 2
- Nanoreactors
- 2.1
- Nanoreactor Definition
- 2.2
- Encapsulation Effects
- 2.3
- Reaction Kinetics Inside Nanoreactors
- 2.4
- Product Inhibition
- 2.5
- Nanoreactor Classification
- 2.5.1
- Natural or Synthetic Nanoreactors
- 2.5.2
- Biological Nanoreactors
- 2.5.3
- Self-Assembled Nanoreactors
- 3
- Nanoreactor potential applications
- 3.1
- Catalysis
- 3.2
- Protection and Stabilization.
- 3.3
- Templating and Stabilizing of Nanomaterials
- 3.4
- Polymer Science
- 3.5
- Development of Nanomedicines
- 3.6
- Sensors
- 4
- Conclusions
- References
- Chapter 2
- Cyclodextrins as Porous Material for Catalysis
- 1
- Cyclodextrins: a brief overview
- 1.1
- Structure and Supramolecular Properties
- 1.2
- CD-Based Polymers
- 1.2.1
- Cross-Linked CD-Based Polymers
- 1.2.2
- Linear CD-Based Polymers
- 1.3
- Applications of CDs
- 2
- CD-based polymers as mass-transfer promoters
- 2.1
- Ester Hydrolysis
- 2.2
- Nucleophilic Substitution
- 2.3
- Oxidation.
- 2.4
- Aldol Condensation
- 2.5
- Organometallic Catalysis
- 3
- Imprinted CD-based polymers for catalysis
- 3.1
- Wacker Oxidation
- 3.2
- Oxidative Coupling
- 3.2.1
- Naphthol Derivatives Homocoupling
- 4
- CD-based nanosponges
- 5
- Conclusions
- References
- Chapter 3
- The Use of Cucurbit[n]urils as Organic Nanoreactors
- 1
- Introduction
- 2
- Physical properties of cucurbit[n]urils
- 3
- Host properties of cucurbit[n]urils
- 3.1
- Cationic Guests
- 3.2
- Neutral Guests
- 3.3
- Other Guests
- 4
- Effects of cucurbit[n]uril hosts on guest physical and structural properties.
- 4.1
- Effects of CB[n] Hosts on Guest Solubility
- 4.2
- Effects of CB[n] Hosts on Guest Spectroscopic Properties
- 4.3
- Effects of CB[n] Hosts on Guest Structure and Isomerization
- 4.4
- Effects of CB[n] Hosts on Guest Aggregation
- 5
- Effects of Cucurbit[n]urils on guest reactivity and chemical properties
- 5.1
- CB[n] Nanoreactor Control of Guest Acidity
- 5.2
- CB[n] Nanoreactor Control of Guest Electrochemical Properties
- 5.3
- CB[n] Nanoreactors for Enhanced Reactant Solubility and Stability
- 5.4
- CB[n] Nanoreactors for Reactant Geometry and Stereochemistry Control.
- 5.5
- CB[n] Nanoreactors for Reaction Templating
- 5.6
- CB[n] Nanoreactors for Reaction Catalysis
- 6
- Conclusions
- References
- Chapter 4
- Systems Based on Calixarenes as the Basis for the Creation of Catalysts and Nanocontainers
- 1
- Introduction
- 2
- Synthesis and structure of calixarenes
- 2.1
- Calixarenes and Thiacalixarenes
- 2.2
- Calix[4]resorcinarenes and Pyrogallolarenes
- 3
- Macromolecular catalysts based on macrocyclic receptors
- 4
- Supramolecular catalysis by calixarenes
- 5
- Supramolecular catalysis by metal complexes based on calixarenes.
- 6
- Supramolecular systems for controlled binding/isolation of organic molecules and biosubstrates.