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New materials for catalytic applications /

New Materials for Catalytic Applications proposes the use of both new and existing materials for catalytic applications, such as zeolites, metal oxides, microporous and mesoporous materials, and monocrystals. In addition, metal-oxides are discussed from a new perspective, i.e. nano- and photocatalyt...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: P�arvulescu, V. I. (Vasile I.) (Editor ), Kemnitz, Erhard (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Elsevier, [2016]
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover; Title Page; Copyright Page; Contents; List of Contributors; Chapter 1
  • Double Metal Cyanides as Heterogeneous Catalysts for Organic Reactions; 1
  • Introduction; 2
  • Epoxide Ring-Opening Reactions; 2.1
  • Ring-Opening Polymerization of Epoxides; 2.2
  • Copolymerization of CO2 and Epoxides; 2.3
  • Cycloaddition of CO2 to Epoxides; 2.4
  • Ring-Opening of Epoxides with Amines; 3
  • Esterification, Transesterification, and Hydrolysis Reactions; 3.1
  • Transesterification Reactions; 3.2
  • Esterification Reactions; 3.3
  • Hydrolysis Reactions; 3.4
  • Polyester Synthesis.
  • 4
  • Addition and Coupling Reactions4.1
  • Hydroamination Reactions; 4.2
  • Aldol Condensation; 4.3
  • Prins Condensation; 5
  • Oxidation Reactions; 6
  • Conclusions; References; Chapter 2
  • Metal Organic Frameworks as Catalysts for Organic Reactions; 1
  • Introduction; 2
  • Stability Issues; 3
  • Zeolites Versus MOFs as Heterogeneous Catalysts; 4
  • Active Sites in MOFs; 5
  • MOFs for Oxidation Reactions; 6
  • C-C Coupling Reactions; 7
  • Hydrogenation Reactions; 8
  • Concluding Remarks; References; Chapter 3
  • On the Use of Organometallic Chemistry Concepts for the Synthesis of Nanocatalysts.
  • 1
  • Introduction2
  • Methods for the Synthesis of Metal Nanoparticles and their Characterization; 2.1
  • Synthesis Tools to Produce Metal Nanoparticles; Organometallic complexes as the source of metal atoms; Ligands as stabilizers of metal nanoparticles; 2.2
  • Tools for the Characterization of Metal Nanoparticles; Quantification of hydrides at metal nanoparticle surface; Coordination of CO to probe the surface properties of metal nanoparticles; Catalysis to probe the surface state of metal nanoparticles; 3
  • Selected Examples of Metal Nanoparticle Synthesis and their Application in Catalysis.
  • 3.1
  • In Organic MediaRhenium nanoparticles; Bimetallic nanoparticles; Phosphine and secondary phosphine oxide-stabilized Ru NPs for hydrogenation reactions; Carbene-stabilized nanoparticles for hydrogenation reactions; 3.2
  • Water-Soluble Nanoparticles for Hydrogenation Reactions in Aqueous Phase; 3.3
  • Supported Nanoparticles; Silica-supported nanoparticles for hydrogenation reactions; Carbon-supported nanoparticles for oxidation, C-C coupling, or hydrogenation reactions; 4
  • Conclusions and Outlook; Acknowledgments; References.
  • Chapter 4
  • Catalysts on Metallic Surfaces: Monoliths and Microreactors1
  • Overview; 2
  • The Metal Choice; 3
  • Catalyst Coating; 3.1
  • Metallic Substrate Pretreatment; 3.2
  • Catalyst Coating Methods; Coating methods in liquid phase; Washcoating; In situ growth/direct synthesis; Electrophoretic deposition; Electrochemical deposition; Electroless plating; Spray Coating; Coating methods in vapor phase; 4
  • Catalytic Layer: Influence of the Metallic Substrate and Deposition Procedure; 4.1
  • Influence of the Deposition Method; 4.2
  • Influence of the Metallic Substrate and the Reaction Conditions.
  • 5
  • Transport Phenomena in Structured Catalysts.