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Advances in physical organic chemistry. Volume 49 /
Advances in Physical Organic Chemistry series of volumes is the definitive resource for authoritative reviews of work in physical organic chemistry. It aims to provide a valuable source of information not only for physical organic chemists applying their expertise to both novel and traditional probl...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
[Place of publication not identified] :
Academic Press,
[2015]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; ADVISORY BOARD; Advances in Physical Organic Chemistry; Copyright; CONTENTS; CONTRIBUTORS; PREFACE; One
- Metal Ion-Promoted Leaving Group Assistance in the Light Alcohols; 1. INTRODUCTION; 1.1 Problems with Water as a Solvent for Metal Ion-Promoted Solvolyses are Ameliorated in Alcohols; 2. METAL ION-PROMOTED LGA; 2.1 Brief Description of LGA and Modes of Involvement of the Metal Ion; 2.2 Early Examples with Acetyl Imidazole and Its (NH3)5CoIII-Complex where the Metal Ions Act as Lewis Activators and Provide L ...
- 2.3 Early Examples with Esters Having Complex Mechanisms for Methanolysis Promoted by Lanthanides and a Triazacyclododecane:ZnI ...2.4 DFT Computational Study of the Methanolysis of Carboxylate Esters Promoted by ZnII-Complexed Methoxide (18); 3. METAL ION-PROMOTED ALCOHOLYSIS OF PHOSPHATES; 3.1 Proof of Concept: LGA Provided by a CuII:Phenanthroline in the Solvolysis of Closely Positioned tri-, di-, and Monophosphates; 3.2 Bimolecular Catalytic Phosphate Cleavage Reactions where Metal Ion-Promoted LGA is Apparent; 3.3 DFT Computational Study of the 23-Promoted Methanolytic Cleavage of 24f
- 5. CONCLUSIONS AND SPECULATIONSACKNOWLEDGMENTS; REFERENCES; Two
- Medium Effects in Biologically Related Catalysis; 1. INTRODUCTION; 2. PHOSPHORYL TRANSFER REACTIONS; 2.1 Overview of Phosphoryl Transfer in Aqueous Solution; 2.2 Solvent Effects in Phosphoryl Transfer Reactions; 2.3 Surfactants Effects on Phosphoryl Transfer Reactions; 3. SOLVENT EFFECTS IN SULFURYL TRANSFER REACTIONS; 4. SOLVENT EFFECTS IN SN2 REACTIONS OF S-ADENOSYLMETHIONINE; 5. DECARBOXYLATION REACTIONS; 5.1 Decarboxylation of Orotic Acid Derivatives; 5.2 Decarboxylation of 3-Carboxybenzisoxazoles (Kemp Decarboxylation)
- 6. KEMP ELIMINATION7. CONCLUSIONS AND IMPLICATIONS FOR BIOINSPIRED CATALYSIS; ACKNOWLEDGMENTS; REFERENCES; Three
- Combustion Pathways of Biofuel Model Compounds: A Review of Recent Research and Current Challenges Pertaini ...; 1. INTRODUCTION; 1.1 Kinetic Mechanisms; 1.2 Experimental Techniques; 1.3 Computational Techniques; 1.4 Simplifying Detailed Mechanisms; 1.5 High- and Low-Temperature Oxidation Pathways; 1.6 Atmospheric Chemistry; 2. OVERVIEW OF FIRST-GENERATION BIOFUELS AND THEIR MODEL COMPOUNDS; 2.1 Combustion Pathways of Ethanol; 2.1.1 Unimolecular Decomposition of Ethanol