Molecularly imprinted catalysts : principles, syntheses, and applications /

Molecularly Imprinted Catalysts: Principle, Synthesis, and Applications is the first book of its kind to provide an in-depth overview of molecularly imprinted catalysts and selective catalysis, including technical details, principles of selective catalysis, preparation processes, the catalytically a...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Li, Songjun (Editor ), Cao, Shunsheng (Editor ), Piletsky, Sergey (Editor ), Turner, Anthony P. F. (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam, Netherlands : Elsevier, [2016]
Temas:
Imprinted polymers.
Molecular imprinting.
Catalysts.
Polym�eres �a empreintes mol�eculaires.
Empreintes mol�eculaires.
Catalyseurs.
catalyst.
SCIENCE / Chemistry / Analytic
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Molecularly Imprinted Catalysts; Copyright; Contents; Contributors; Editors' Biographies; Foreword; Preface; 1
  • Molecularly Imprinted Polymers for Enzyme-like Catalysis: Principle, Design, and Applications; 1. Introduction; 2. Generic Profile of Molecular Imprinting; 3. Rationally Optimized Interactions within Imprinted Polymers; 4. Some Basic Issues in Imprinted Polymer Catalysts for Selective Catalysis; 5. Molecular Imprinting with Transition State Analogues as the Template; 6. Molecular Imprinting with Substrate as the Template
  • 7. Molecular Imprinting with Product as the Template8. Future Outlook of Molecular Imprinting in Catalysis; 9. Concluding Remarks; Acknowledgments; References; 2
  • Catalytically Active MIP Architectures; 1. Introduction; 2. Transition State Analogues as Templates in Abzyme Mimics; 3. Metal Complexes and Prosthetic Groups in Enzyme Mimics; 4. MIP-Enzyme Architectures; 5. Protein-Based MIPs; 6. Summary and Outlook; References; 3
  • Molecularly Imprinted Catalysts: Synthesis and Applications; 1. Introduction; 2. Design of MIPs for Catalytic Action
  • 3. Different Designs of MIPs for the Biomimetic Catalyst3.1 MIPs as Mimics of Hydrolytic Enzyme; 3.1.1 Ester Hydrolysis; 3.1.2 Stereoselective Hydrolysis; 3.1.3 Charged Hydrogen Bonding and Ester Hydrolysis; 3.1.4 Carbonate and Carbamate Hydrolysis; 3.1.5 Cellulose Hydrolysis; 3.2 MIP with Cholesterol Esterase Activity; 3.3 MIP Catalyst-Enhanced Elimination Reaction; 3.4 Diels-Alder Catalysis; 3.5 Metalloenzyme-Based MIP Catalysts; 3.6 MIP Catalyst for Isomerization Reactions; 4. Recent Progress Made in MIPs to Enhance Their Biomimetic Catalyst Property
  • 4.1 Intrinsic Factors for Enhancement of Biomimetic Catalyst Property4.1.1 High Enzyme Substrate Binding Affinities; 4.1.2 High Synergy between Recognition and Catalysis; 4.1.3 High Catalytic Turnover; 4.1.4 Substantial Rate Accelerations; 4.2 Extrinsic Factors for Enhancement of Biomimetic Catalyst Property; 4.2.1 Development of Computational Methodology Affiliated with MIPs as Biomimetic Catalyst; 5. Conclusion; References; 4
  • Advances and Challenges in the Design and Synthesis of Molecularly Imprinted Microspheres; 1. Introduction
  • 2. Progress in Design and Synthesis of Molecularly Imprinted Microspheres2.1 Methods of Initiation; 2.1.1 Controlled Radical Polymerization; 2.1.2 Iniferters; 2.1.3 Nitroxide-Mediated Polymerization; 2.1.4 Reversible Addition Fragmentation Polymerization; 2.1.5 Atom Transfer Radical Polymerization; 2.1.6 Porogens; 2.2 Cross-linkers and Functional Monomers; 2.3 Other Strategies; 3. Challenges in the Design and Synthesis of Molecularly Imprinted Microspheres; 4. Future Outlook: Processable Star MIPs; 5. Conclusion; References
  • 5
  • Molecularly Imprinted Polymers: Principle, Design, and Enzyme-Like Catalysis

Ejemplares similares