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Advances in heterocyclic chemistry. Volume 116 /
Advances in Heterocyclic Chemistry is the definitive series in this area-one of great importance to organic chemists, polymer chemists, and many biological scientists. As the disciplines of biology and organic chemistry increasingly intersect, the nomenclature of organic chemistry is increasingly us...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Waltham, MA :
Academic Press,
2015.
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| Edición: | First edition |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover; Advances in Heterocyclic Chemistry; Editorial Advisory Board; Copyright; Contents; Contributors; Preface; The Larock Reaction in the Synthesis of Heterocyclic Compounds; 1. Introduction; 2. Mechanism of Larock Heteroannulation; 2.1 Homogeneous Catalyst; 2.2 Heterogeneous Catalyst; 2.3 Phosphine-Free Pseudothiourea Palladium(II); 2.4 Stabilized Palladium Colloid; 2.5 Silicon-Based Cross-Coupling Reactions; 2.6 N-Heterocyclic Carbene-Pd Complexes; 3. Larock Reactions in the Solid Phase; 3.1 Synthesis of Trisubstituted Indoles on a Solid Phase
- 5.6 Synthesis of Ibogaine5.7 Synthesis of Dictyodendrins; 5.8 Synthesis of Natural Products Containing the Tryptamine-HPI Bond; 5.9 Larock Reactions in Drug Discovery; 6. Heteroannulation with Substrates Other than Alkynes; 6.1 Heteroannulation of 1,3-Dienes; 6.2 Heteroannulation of Allenes; 7. Conclusions; Acknowledgments; References; Helical Phosphorus Derivatives: Synthesis and Applications; 1. Introduction: Helical Structures; 2. Primary Helical Molecules; 2.1 Phosphorus Containing Helicenes; 2.1.1 Helicene-Based Phosphine Ligands; 2.1.2 Helicene-Based Phosphite Ligands
- 2.1.3 Helicene-Based Phosphine Oxide Ligands2.1.4 Helicene-Based Phosphole Ligands; 2.2 Other Phosphorus Helical Derivatives; 2.2.1 Ortho-Substituted Triarylphosphines; 2.2.2 Polycyclic Propellers; 2.2.3 Spirocyclic Phosphorus Derivatives; 2.2.4 Highly Fused and Distorted Phosphorus Heterocycles; 3. Secondary Helical Phosphorus Assemblies; 3.1 Helical Organic Frameworks Embedding Phosphorus Atoms; 3.1.1 Helical H-Bond-Structured Organic Frameworks; 3.1.2 Helical Metal Organic Frameworks; 3.2 Helical Polymers Embedding Phosphorus Atoms; 3.2.1 Phosphazene Polymers
- 3.2.2 Phosphino-Quinoxaline-Based Polymers4. Conclusion; List of Abbreviations ; References; Recent Advances in the Chemistry of 1,2,4-OxadiazolesaaDedicated to Professor Nicol�o Vivona on the occasion of his 75th bir ...; 1. Introduction; 1.1 Historical Remarks; 1.2 Classical 1,2,4-Oxadiazole Synthesis; 1.3 Reactive Sites in the 1,2,4-Oxadiazole Ring; 2. Modern 1,2,4-Oxadiazole Synthesis; 3. 1,2,4-Oxadiazoles as Reagents; 3.1 Ground State Rearrangements of 1,2,4-Oxadiazoles; 3.2 Excited-State Rearrangements of 1,2,4-Oxadiazoles; 4. 1,2,4-Oxadiazoles in Materials Chemistry; 4.1 Liquid Crystals